Picosecond electron diffraction from molecules aligned by dissociation

In gas electron diffraction an averaging over statistical directions of the molecules takes place. This results in diffraction patterns in the form of isotropic rings which yield information only on the radial distribution function displaying the inter-atomic distances. We demonstrate that by dissociating molecules with linearly polarized light the pattern becomes anisotropic. In the experiments the iodide C2F4I2 is dissociated and molecular difference intensities and difference radial distribution curves are measured for directions parallel and perpendicular to the direction of polarization. With picosecond temporal resolution the curves clearly demonstrate transient anisotropy and its decay by molecular rotation. This experiment is a first step towards the determination of structure and of ultrafast structural changes by electron diffraction from aligned molecules

Proposed method for measuring the duration of electron pulses by attosecond streaking

We propose a method to measure the duration of ultrashort electron pulses. The electron pulse to be measured impinges on a solid target, causing the emission of Auger electrons through impact ionization. The energy spectrum of the Auger electrons is altered in the presence of an intense femtosecond laser field. Due to the extremely short lifetime of the Auger effect, this effect can be used to generate cross correlation between a laser and an electron pulse. The method is applicable to electron pulses ranging from hundreds of attoseconds to hundreds of femtoseconds in duration, and for a few hundreds of electron volts to relativistic energies

Time-Resolved Electron Diffraction from Selectively Aligned Molecules

We experimentally demonstrate ultrafast electron diffraction from transiently aligned molecules in the absence of external (aligning) fields. A sample of aligned molecules is generated through photodissociation with femtosecond laser pulses, and the diffraction pattern is captured by probing the sample with picosecond electron pulses shortly after dissociation—before molecular rotation causes the alignment to vanish. In our experiments the alignment decays with a time constant of 2.6 ± 1.2 ps