Addition of phenylisocyanate to 3,5-diphenyl-1,2-dithiolium-4-olate gives a thioketone

The Type B mesoionic heterocycle, 3,5-diphenyl-1,2-dithiolium-4-olate, reacts with phenylisocyanate producing a thioketone derivative rather than a pseudo-semi-conjugated heterocyclic mesomeric betaine. The structure of the thioketone product was confirmed by an X-ray crystallographic investigation

Unification and classification of two-dimensional crystalline patterns using orbifolds

The concept of an orbifold is particularly suited to classification and enumeration of crystalline groups in the euclidean (flat) plane and its elliptic and hyperbolic counterparts. Using Conway's orbifold naming scheme, this article explicates conventional point, frieze and plane groups, and describes the advantages of the orbifold approach, which relies on simple rules for calculating the orbifold topology. The article proposes a simple taxonomy of orbifolds into seven classes, distinguished by their underlying topological connectedness, boundedness and orientability. Simpler 'crystallographic hyperbolic groups' are listed, namely groups that result from hyperbolic sponge-like sections through three-dimensional euclidean space related to all known genus-three triply periodic minimal surfaces (i.e. the P, D, Gyroid, CLP and H surfaces) as well as the genus-four I-WP surface

Integrating economic and environmental impact analysis: the case of rice-based farming in northern Thailand

Crop production is associated with a range of potential environmental impacts, including field 9 emissions of greenhouse gases, loss of nitrogen and phosphorous nutrients to water and toxicity 10 effects on humans and natural ecosystems. Farmers can mitigate these environmental impacts 11 by changing their farming systems; however these changes have implications for production 12 and profitability. To address these trade-offs, a farm-level model was constructed to capture 13 the elements of a rice-based production system in northern Thailand. Life Cycle Assessment 14 (LCA) was used to generate environmental impacts, across a range of indicators, for all crops 15 and associated production processes in the model. A baseline, profit maximising combination 16 of crops and resource use was generated and compared with a greenhouse gas minimising 17 scenario and an alternative inputs (fertilisers and insecticides) scenario. Greenhouse gas 18 minimisation showed a reduction in global warming potential of 13%; other impact indicators 19 also decreased. Associated profit foregone was 10% as measured by total gross margin. With 20 the alternative farm inputs (ammonium sulphate, organic fertiliser and fipronil insecticide), 21 results indicated that acidification, eutrophication, freshwater and terrestrial ecotoxicity 22 impacts were reduced by 43, 37, 47 and 91% respectively with relatively small effects on profit

Prospects for dedicated energy crop production and attitudes towards agricultural straw use: the case of livestock farmers

Second generation biofuels utilising agricultural by-products (e.g. straw), or dedicated energy crops (DECs) produced on ‘marginal’ land, have been called for. A structured telephone survey of 263 livestock farmers, predominantly located in the west or ‘marginal’ upland areas of England captured data on attitudes towards straw use and DECs. Combined with farm physical and business data, the survey results show that 7.2% and 6.3% of farmers would respectively consider growing SRC and miscanthus, producing respective maximum potential English crop areas of 54,603 ha and 43,859 ha. If higher market prices for straw occurred, most livestock farmers would continue to buy straw. Reasons for not being willing to consider growing DECs include concerns over land quality, committing land for a long time period, lack of appropriate machinery, profitability, and time to financial return; a range of moral, land quality, production conflict and lack of crop knowledge factors were also cited. Results demonstrate limited potential for the production of DECs on livestock farms in England. Changes in policy support to address farmer concerns with respect to DECs will be required to incentivise farmers to increase energy crop production. Policy support for DEC production must be cognisant of farm-level economic, tenancy and personal objectives

Integrating the economic and environmental performance of agricultural systems: a demonstration using Farm Business Survey data and Farmscoper

There is a continued need to monitor the environmental impacts of agricultural systems while also ensuring sufficient agricultural production. However, it can be difficult to collect relevant environmental data on a large enough number of farms and studies that do so often neglect to consider the financial drivers that ultimately determine many aspects of farm management and performance. This paper outlines a methodology for generating environmental indicators from the Farm Business Survey (FBS), an extensive annual economic survey of representative farms in England and Wales. Data were extracted from the FBS for a sample of East Anglian cereal farms and south western dairy farms and converted where necessary to use as inputs in ‘Farmscoper’; farm-level estimates of nitrate, phosphorus and sediment loadings and ammonia and greenhouse gas emissions were generated using the Farmscoper model. Nitrate losses to water, ammonia and greenhouse gas emissions were positively correlated with food energy production per unit area for both farm types; phosphorus loading was also correlated with food energy on the dairy farms. Environmental efficiency indicators, as measured by either total food energy or financial output per unit of negative environmental effect, were calculated; greenhouse gas emission efficiency (using either measure of agricultural output) and nitrate loading efficiency (using financial output) were positively correlated with profitability on cereal farms. No other environmental efficiency measures were significantly associated with farm profitability and none were significant on the dairy farms. These findings suggest that an improvement in economic performance can also improve environmental efficiency, but that this depends on the farm type and negative environmental externality in question. In a wider context, the augmentation of FBS-type data to generate additional environmental indicators can provide useful insights into ongoing research and policy issues around sustainable agricultural production

Biochar-mediated reductions in greenhouse gas emissions from soil amended with anaerobic digestates

This investigation examines nitrous oxide (N2O) fluxes from soil with simultaneous amendments of anaerobic digestates and biochar. The main source of anthropogenic emissions of N2O is agriculture and in particular, manure and slurry application to fields. Anaerobic digestates are increasingly used as a fertiliser and interest is growing in their potential as sources of N2O via nitrification and denitrification. Biochar is a stable product of pyrolysis and may affect soil properties such as cation exchange capacity and water holding capacity. Whilst work has been conducted on the effects of biochar amendment on N2O emissions in soils fertilised with mineral fertilisers and raw animal manures, little work to date has focused on the effects of biochar on nitrogen transformations within soil amended with anaerobic digestates. The aim of the current investigation was to quantify the effects of biochar application on ammonification, nitrification and N2O fluxes within soil amended with three anaerobic digestates derived from different feedstocks. A factorial experiment was undertaken in which a sandy loam soil (Dunnington Heath series) was either left untreated, or amended with three different anaerobic digestates and one of three biochar treatments; 0%, 1% or 3%. Nitrous oxide emissions were greatest from soil amended with anaerobic digestate originating from a maize feedstock. Biochar amendment reduced N2O emissions from all treatments, with the greatest effect observed in treatments with maximum emissions. The degree of N2O production and efficacy of biochar amelioration of gas emissions is discussed in context of soil microbial biomass and soil available carbon

More sustainable vegetable oil: Balancing productivity with carbon storage opportunities

Intensive cultivation and post-harvest vegetable oil production stages are major sources of greenhouse gas (GHG) emissions. Variation between production systems and reporting disparity have resulted in discordance in previous emissions estimates. The aim of this study was to assess global systems-wide variation in GHG emissions resulting from palm, soybean, rapeseed and sunflower oil production. Such an analysis is critical to understand the implications of meeting increasing edible oil demand. To achieve this, we performed a unified re-analysis of life cycle input data from diverse palm, soybean, rapeseed, and sunflower oil production systems, from a saturating search of published literature. The resulting dataset reflects almost 6000 producers in 38 countries, and is representative of over 71% of global vegetable oil production. Across all oil crop systems, median GHG emissions were 3.81 kg CO2e per kg refined oil. Crop specific median emissions ranged from 2.49 kg CO2e for rapeseed oil to 4.25 kg CO2e for soybean oil per kg refined oil. Determination of the carbon cost of agricultural land occupation revealed that carbon storage potential in native compared to agricultural land cover drives variation in production GHG emissions, and indicates that expansion of production in low carbon storage potential land, whilst reforesting areas of high carbon storage potential, could reduce net GHG emissions whilst boosting productivity. Nevertheless, there remains considerable scope to improve sustainability within current production systems, including through increasing yields whilst limiting application of inputs with high carbon footprints, and in the case of palm oil through more widespread adoption of methane capture technologies in processing stages

Polycontinuous geometries for inverse lipid phases with more than two aqueous network domains

Inverse bicontinuous cubic phases with two aqueous network domains separated by a smooth bilayer are firmly established as equilibrium phases in lipid/water systems. The purpose of this article is to highlight the generalisations of these bicontinuous geometries to polycontinuous geometries, which could be realised as lipid mesophases with three or more network-like aqueous domains separated by a branched bilayer. An analysis of structural homogeneity in terms of bilayer width variations reveals that ordered polycontinuous geometries are likely candidates for lipid mesophase structures, with similar chain packing characteristics to the inverse micellar phases (that once were believed not to exist due to high packing frustration). The average molecular shape required by global geometry to form these multi-network phases is quantified by the surfactant shape parameter, v/(al); we find that it adopts values close to those of the known lipid phases. We specifically analyse the 3etc(187 193) structure of hexagonal symmetry P63 /mcm with three aqueous domains, the 3dia(24 220) structure of cubic symmetry I 3d composed of three distorted diamond networks, the cubic chiral 4srs(24 208) with cubic symmetry P4232 and the achiral 4srs(5 133) structure of symmetry P42/nbc, each consisting of four intergrown undistorted copies of the srs net (the same net as in the QGII gyroid phase). Structural homogeneity is analysed by a medial surface approach assuming that the head-group interfaces are constant mean curvature surfaces. To facilitate future experimental identification, we provide simulated SAXS scattering patterns that, for the 4srs(24 208) and 3dia(24 220) structures, bear remarkable similarity to those of bicontinuous QGII-gyroid and QDII-diamond phases, with comparable lattice parameters and only a single peak that cannot be indexed to the well-established structures. While polycontinuous lipid phases have, to date, not been reported, the likelihood of their formation is further indicated by the reported observation of a solid tricontinuous mesoporous silicate structure, termed IBN-9, which formed in the presence of surfactants [Han et al., Nat. Chem., 2009, 1, 123]

Mathematical modelling of antimicrobial resistance in agricultural waste highlights importance of gene transfer rate

Antimicrobial resistance is of global concern. Most antimicrobial use is in agriculture; manures and slurry are especially important because they contain a mix of bacteria, including potential pathogens, antimicrobial resistance genes and antimicrobials. In many countries, manures and slurry are stored, especially over winter, before spreading onto fields as organic fertilizer. Thus these are a potential location for gene exchange and selection for resistance. We develop and analyze a mathematical model to quantify the spread of antimicrobial resistance in stored agricultural waste. We use parameters from a slurry tank on a UK dairy farm as an exemplar. We show that the spread of resistance depends in a subtle way on the rates of gene transfer and antibiotic inflow. If the gene transfer rate is high, then its reduction controls resistance, while cutting antibiotic inflow has little impact. If the gene transfer rate is low, then reducing antibiotic inflow controls resistance. Reducing length of storage can also control spread of resistance. Bacterial growth rate, fitness costs of carrying antimicrobial resistance and proportion of resistant bacteria in animal faeces have little impact on spread of resistance. Therefore effective treatment strategies depend critically on knowledge of gene transfer rates

Analysing reduced tillage practices within a bio-economic modelling framework

Sustainable Intensification of agricultural production systems will require changes in farm practice. Within arable cropping systems, reducing the intensity of tillage practices (e.g. reduced tillage) potentially offers one such sustainable intensification approach. Previous researchers have tended to examine the impact of reduced tillage on specific factors such as yield or weed burden, while, by definition, sustainable intensification necessitates a system-based analysis approach. Drawing upon a bio-economic optimisation model, ‘MEETA’, we quantify trade-off implications between potential yield reductions, reduced cultivation costs and increased crop protection costs. We extend the MEETA model to quantify farm-level net margin, in addition to quantifying farm-level gross margin, net energy, and greenhouse gas emissions. For the lowest intensity tillage system, zero tillage, results demonstrate financial benefits over a conventional tillage system even when the zero tillage system includes yield penalties of 0-14.2% (across all crops). Average yield reductions from zero tillage literature range from 0-8.5%, demonstrating that reduced tillage offers a realistic and attainable sustainable intensification intervention, given the financial and environmental benefits, albeit that yield reductions will require more land to compensate for loss of calories produced, negating environmental benefits observed at farm-level. However, increasing uptake of reduced tillage from current levels will probably require policy intervention; an extension of the recent changes to the CAP (‘Greening’) provides an opportunity to do this