58 research outputs found

    Modeling of Wear-Out Failures and Service Life Improvement of Sealing Units

    Get PDF
    AbstractThe article is concerned with a new method of setting up and solution of boundary value problems of reliability theory for sealing units on the basis of wear resistance criterion of sealing elements. The research group carried out theoretical study of service life for the standard “roller - shoe” friction couple on the basis of wear resistance of shoes manufactured from different sealing materials. Theoretical results were verified and the most durable sealing materials were introduced into commercial operation

    Fluorescent properties of the kindling fluorescent protein (KFP) at acidic pH values

    Get PDF
    Kindling fluorescent protein (KFP) is the photoswitchable protein which can be used in high-resolution microscopy and as a quencher in FRET-sensors. Fluorescent properties of KFP depend on pH value. In this paper we investigate the influence of pH on the spectral properties and kindling/quenching ability of KFP in the acidic pH region.Shift to the acidic region leads to the increase of fluorescence intensity of KFP over time. The excitation spectrum has a new peak near 455nm, giving two peaks - 530 and 590nm – in emission spectrum. We can assume that this maximum corresponds to the appearance of protonated form of the KFP chromophore.Analysis of fluorescence decay curves of KFP in H2O and D2O showed the presence of the kinetic isotope effect, which can be caused by the proton transfer from solvent molecules to the KFP chromophore, confirming the hypothesis that in the acidic pH region protonated form of KFP chromophore appears.At acidic pH irradiation of KFP with green light doesn’t lead to fluorescence increase, while blue light doesn’t quench the fluorescence. It means that KFP is also in the bright form, and there is no conformational states of protein which can be quenched by blue light

    Nanostructured Lead Compounds in Electrode Materials of a Lead-Acid Battery

    Get PDF
    The nanostructure and phase composition of the electrode material of lead-acid batteries, formed by chemical transformations with involvement of sulfuric acid solutions of various concentrations, water and carbon dioxide have been studied

    Physical research of microgravity influence on physical phenomenon in cryogenic liquids and general-purpose onboard cryogenic facility for realization of this researchaboard International Space Station

    No full text
    The united research plan named "Boiling" is created on the basis of several cryogenic research projects developed by experts in Russia and Ukraine for International Space Station. The "Boiling" plan includes 8 first experiments aimed at investigating the influence of microgravity on boiling processes, heat transfer and hydrodynamics in liquid helium being either under normal or superfluid conditions. The experiments are supposed to be carried out with individual cells collected inside a single cryogenic onboard experimental facility. The international research program experiments are characterized by the following features: utilization of several artificially simulated microgravity levels, owing to rotation of the experimental helium cryostat; visualization of the processes that occur in liquid helium; research of boiling and hydrodynamics both in a large volume of stationary liquid, and in a liquid flow running through a channel. Upon completion of the "Boiling" research plan, the cryogenic onboard facility created for International Space Station would be able to find its application in further scientific and experimental researches with helium

    The Physics of Cluster Mergers

    Get PDF
    Clusters of galaxies generally form by the gravitational merger of smaller clusters and groups. Major cluster mergers are the most energetic events in the Universe since the Big Bang. Some of the basic physical properties of mergers will be discussed, with an emphasis on simple analytic arguments rather than numerical simulations. Semi-analytic estimates of merger rates are reviewed, and a simple treatment of the kinematics of binary mergers is given. Mergers drive shocks into the intracluster medium, and these shocks heat the gas and should also accelerate nonthermal relativistic particles. X-ray observations of shocks can be used to determine the geometry and kinematics of the merger. Many clusters contain cooling flow cores; the hydrodynamical interactions of these cores with the hotter, less dense gas during mergers are discussed. As a result of particle acceleration in shocks, clusters of galaxies should contain very large populations of relativistic electrons and ions. Electrons with Lorentz factors gamma~300 (energies E = gamma m_e c^2 ~ 150 MeV) are expected to be particularly common. Observations and models for the radio, extreme ultraviolet, hard X-ray, and gamma-ray emission from nonthermal particles accelerated in these mergers are described.Comment: 38 pages with 9 embedded Postscript figures. To appear in Merging Processes in Clusters of Galaxies, edited by L. Feretti, I. M. Gioia, and G. Giovannini (Dordrecht: Kluwer), in press (2001

    Nanostructured Lead Compounds in Electrode Materials of a Lead-Acid Battery

    Get PDF
    The nanostructure and phase composition of the electrode material of lead-acid batteries, formed by chemical transformations with involvement of sulfuric acid solutions of various concentrations, water and carbon dioxide have been studied

    Polyfunctional imidazoles: II. Synthesis and reactions with nucleophilic reagents of 1-substituted 2,4-dichloro-1H-imidazole-5-carbaldehydes

    No full text
    1-Alkyl(aryl)imidazolidine-2,4-diones reacted with Vilsmeier-Haack reagent affording 1-alkyl(aryl)-2,4-dichloro-1H-imidazole-5-carbaldehydes whose reactions with sodium azide, sodium alkoholates, with phenols, thiols, and secondary cycloalkylamines led to the substitution of chlorine in the position 2 of the imidazole ring. The reaction with primary amines resulted in the condensation products at the aldehyde group

    Reentrant superconducting behavior of the Josephson SFS junction. Evidence for the π-phase state

    Get PDF
    Critical supercurrents, Ic in Nb_Cu1−xNix_Nb Josephson SFS junctions with F-layers prepared from ferromagnetic Cu1−xNix alloys have been studied. For value x=0.52 and particular F-layer thickness we have observed Ic(T) oscillations with Ic vanishing for some values of T. We associate this reentrant superconducting behavior with a crossover of the SFS junction from ‘0’- to ‘π’-state that is related to temperature dependence of spatial oscillation period of induced superconducting order parameter in the weak ferromagnet. We argue this is the first experimental evidence of the π-behavior of a Josephson junction, that is the special feature of superconducting pair flow through a ferromagnet predicted for SFS junctions by Bulaevskii, Buzdin et al [1]
    corecore