273 research outputs found
The New and Old Originalism: A Discussion
These five essays, which were originally published on the Library of Law and Liberty website, explore several themes involving the new and
The New and Old Originalism: A Discussion
These five essays, which were originally published on the Library of Law and Liberty website, explore several themes involving the new and
Inverse melting of the vortex lattice
Inverse melting, in which a crystal reversibly transforms into a liquid or
amorphous phase upon decreasing the temperature, is considered to be very rare
in nature. The search for such an unusual equilibrium phenomenon is often
hampered by the formation of nonequilibrium states which conceal the
thermodynamic phase transition, or by intermediate phases, as was recently
shown in a polymeric system. Here we report a first-order inverse melting of
the magnetic flux line lattice in Bi2Sr2CaCu2O8 superconductor. At low
temperatures, the material disorder causes significant pinning of the vortices,
which prevents observation of their equilibrium properties. Using a newly
introduced 'vortex dithering' technique we were able to equilibrate the vortex
lattice. As a result, direct thermodynamic evidence of inverse melting
transition is found, at which a disordered vortex phase transforms into an
ordered lattice with increasing temperature. Paradoxically, the structurally
ordered lattice has larger entropy than the disordered phase. This finding
shows that the destruction of the ordered vortex lattice occurs along a unified
first-order transition line that gradually changes its character from
thermally-induced melting at high temperatures to a disorder-induced transition
at low temperatures.Comment: 13 pages, 4 figures, Nature, In pres
Exploring autoionization and photo-induced proton-coupled electron transfer pathways of phenol in aqueous solution
The excited state dynamics of phenol
in water have been investigated
using transient absorption spectroscopy. Solvated electrons and vibrationally
cold phenoxyl radicals are observed upon 200 and 267 nm excitation,
but with formation time scales that differ by more than 4 orders of
magnitude. The impact of these findings is assessed in terms of the
relative importance of autoionization versus proton-coupled electron
transfer mechanisms in this computationally tractable model system
Can Vertical Profiles of Tropospheric Methane on Titan Be Derived from Radio-Occultation Soundings?
The intensity of the received signal at Earth in the radio occultations of Titan is attenuated both by refractive defocusing and pressure-induced absorption from N2-N2 and CH4-N2 pairs. Because the absorption strength is different for the two sets of pairs, matching the retrieved absorptivity profile can in principle yield the vertical variation in gaseous methane in the troposphere. There are two factors that make this difficult. The first is the propagation of noise in the phase and amplitude of the received signal in the absorption retrieval. The phase data is first inverted to retrieve vertical profiles of refractivity, from which the refractive defocusing is calculated. This is then subtracted from the observed. intensity attenuation of the received signal to generate a profile of atmospheric absorption. The second problem is the uncertainty in the pressure-induced absorption coefficients. Laboratory data at radio wavelengths is only available near room temperature (see, e.g., [1] for N2-N2), and the extrapolation to the low temperatures in Titan's troposphere is not well established. Ab initio calculations by Borysow et al. [2, 3] provide absorption coefficients at low temperatures and long wavelengths, but their accuracy has come into question. We present examples from Cassini radio occultations of Titan to illustrate the difficulties. For methane mole fractions in the lower troposphere comparable to that inferred from the Huygens probe (approximately 0.05), it will be difficult to separate the contributions of N2-N2 collisions from those of N2-CH4, collisions to the retrieved absorption. However, higher concentrations of CH4 and/or a higher signal-to-noise ratio from a future uplink experiment could result in a successful separation of the two components. However, key to this are highly accurate estimates of the absorption from a combination of laboratory measurements at love temperatures and long wavelengths, and possibly improved theoretical calculations
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