Formation and structural characterization of Ni nanoparticles embedded in SiO₂

Face-centered cubic Ni nanoparticles were formed in SiO₂ by ion implantation and thermal annealing. Small-angle x-ray scattering in conjunction with transmission electron microscopy was used to determine the nanoparticle size as a function of annealing temperature, whereas the local atomic structure was measured with x-ray absorption spectroscopy. The influence of finite-size effects on the nanoparticle structural properties was readily apparent and included a decrease in coordination number and bond length and an increase in structural disorder for decreasing nanoparticle size. Such results are consistent with the non-negligible surface-to-volume ratio characteristic of nanoparticles. In addition, temperature-dependent x-ray absorption spectroscopy measurements showed the mean vibrational frequency (as obtained from the Einstein temperature) decreased with decreasing nanoparticle size. This reduction was attributed to the greater influence of the loosely bound, under-coordinated surface atoms prevailing over the effects of capillary pressure, the former enhancing the low frequency modes of the vibrational density of statesThis work was financially supported by the Australian Synchrotron and the Australian Research Council with access to equipment provided by the Australian Nanofabrication Facility

Quality of life and well-being of carers of people with dementia: are there differences between working and nonworking carers? Results from the IDEAL program

The aim of this study was to identify the differences in quality of life (QoL) and well-being between working and nonworking dementia carers and the relative contribution of psychological characteristics, caregiving experience, and social support. Multiple regressions modeled the contribution of working status, caregiver experiences, and psychological and social resources to carer QoL (EQ-5D) and well-being (WHO-5). After controlling for age, gender, carer–dyad relationship, and severity of dementia, working status contributed significant variance to EQ-5D (2%) but not to WHO-5 scores. Independent of working status, higher self-esteem and reduced stress contributed to variance in both models. Self-efficacy, social support, and positive perceptions of caregiving additionally contributed to higher WHO-5 scores. Working status associated with higher EQ-5D QoL; this may reflect the sustained sense of independence associated with supported work opportunities for carers. Outside of working status, the findings support the importance of psychological and social factors as targets to improved mental health for dementia carers

Observations of internal waves generated by an anticyclonic eddy: a case study in the ice edge region of the Greenland Sea

Internal waves in the ocean play an important role in turbulence generation due to wave-breaking processes and mixing of the ocean. Airborne radar images of internal waves and ocean eddies north of Svalbard suggested that ocean eddies could generate internal waves. Here, we test this hypothesis using data from a dedicated internal wave experiment in the Greenland Sea. Internal waves with dominant frequencies of 1–3 cycles per hour and amplitudes up to 15 m were observed using three thermistor chains suspended from a drifting array conveniently placed on the ice in a triangle with sides of several km. Analysis shows that internal waves propagated westwards with a speed of about 0.2 m/s and wavelength of 0.4–1.0 km, away from an anticyclonic ocean eddy located just east of the array. This was consistent with the remote-sensing observations of internal waves whose surface signature was imaged by an airborne radar in the western part of this eddy, and with theories that eddies and vortexes can directly generate internal waves. This case study supports our hypothesis that ocean eddies can be the direct sources of internal waves reported here for the first time and not only enhancing the local internal wave field by draining energy from the eddies, as studied previously. The present challenge is to explore the role of eddies as a new source in generating internal waves in the global ocean

Saline Aquifer CO2 Storage (SACS2). Final report, geological characterisation of the Utsira Sand reservoir and caprocks (Work Area 1)

This report summarises the results and highlights the main findings of SACS Work Area 1, the geological and reservoir characterisation of the Utsira Sand and its caprock. For more detailed technical information on each topic, the reader is directed to the relevant SACS Technical Reports and, in particular, two earlier Work Area 1 interim reports, Holloway et al. (1999) and Chadwick et al. (2000). The Utsira Sand comprises a basinally-restricted deposit of Mio-Pliocene age forming a clearly defined seismic unit, pinching out to east and west, and seismically distinct from overlying and underlying strata.The reservoir is highly elongated, extending for more than 400 km from north to south and between 50 and 100 km from east to west, with an area of some 26100 km2. Its eastern and western limits are defined by stratigraphical lap-out, to the southwest it passes laterally into shaly sediments, and to the north it occupies a narrow channel deepening towards the More Basin. Locally, particularly in the north, depositional patterns are quite complex with some isolated depocentres, and lesser areas of non-deposition within the main depocentre. The top Utsira Sand surface generally varies relatively smoothly, mainly in the range 550 to 1500 m, but mostly from 700 to 1000 m. The base of the sand is more irregular, disturbed by diapirism of the underlying shales. Isopachs of the reservoir sand show two main depocentres. One is in the south, around Sleipner, where thicknesses range up to more than 300 m. The second depocentre lies some 200 km to the north of Sleipner. Here the Utsira Sand is locally 200 m thick, with an underlying sandy unit adding further to the total reservoir thickness. Macroscopic and microscopic analysis of core and cuttings samples of the Utsira Sand show that it consists of a largely uncemented fine-grained sand, with medium and occasional coarse grains. The grains are predominantly angular to sub-angular and consist primarily of quartz with some feldspar and shell fragments. Sheet silicates are present in small amounts (a few percent). The sand is interpreted as being deposited by mass flows in a marine environment in water depths of 100 m or more. The porosity of the Utsira Sand core ranges generally from 27% to 31%, but reaches values as high as 42% Regional log porosities are quite uniform, in the range 35 to 40% over much of the reservoir. Geophysical logs show a number of peaks on the -ray, sonic and neutron density logs, and also on some induction and resistivity logs. These are interpreted as mostly marking thin (~1m thick) intrareservoir shale layers. The shale layers constitute important permeability barriers within the reservoir sand, and have proved to have a significant effect on CO2 migration through, and entrapment within, the reservoir. The proportion of clean sand in the total reservoir thickness varies generally from about 0.7 to nearly 1.0. The caprock succession overlying the Utsira reservoir is rather variable, and can be divided into three main units. The Lower Seal forms a shaly basin-restricted unit, some 50 to 100 m thick. The Middle Seal mostly comprises prograding sediment wedges of Pliocene age, dominantly shaly in the basin centre, but coarsening into a sandier facies both upwards and towards the basin margins. The Upper Seal comprises Quaternary strata, mostly glacio-marine clays and glacial tills. The Lower Seal extends well beyond the area currently occupied by the CO2 injected at Sleipner and seems to be providing an effective seal at the present time. Cuttings samples comprise dominantly grey clay silts or silty clays. Most are massive although some show a weak sedimentary lamination. XRD analysis typically reveal quartz (30%), undifferentiated mica (30%), kaolinite (14%), K-feldspar (5%), calcite (4%), smectite (4%), albite (2%), chlorite (1%), pyrite (1%) and gypsum (1%) together with traces of drilling mud contamination. The clay fraction is generally dominated by illite with minor kaolinite and traces of chlorite and smectite. The cuttings samples are classified as non-organic mudshales and mudstones. Although the presence of small quantities of smectite may invalidate its predictions, XRD-determined quartz contents suggest displacement pore throat diameters in the range 14 to 40 nm. Such displacement pore throat diameters are consistent with capillary entry pressures of between about 2 and 5.5 MPa capable of trapping a CO2 column several hundred metres high. In addition, the predominant clay fabric with limited grain support resembles caprocks which are stated in the literature to be capable of supporting a column of 35 API oil greater than 150 m in height. Empirically, therefore, the caprock samples suggest the presence of an effective seal at Sleipner, with capillary leakage of CO2 unlikely to occur. Around and east of the injection point, a layer of sand, 0 - 50 m thick, lies close to the base of the Lower Seal and is termed the Sand-wedge. The geometry of this unit is likely to prove important in determining the long-term migration behaviour of the CO2. Fluid flow in the Utsira Sand, based on limited pressure measurements and basin-modelling, is likely to be low, in the range 0.3 – 4 metres per year, depending on assumed permeabilities. The total pore-space within the Utsira Sand is estimated at 6.05 x 1011 m3. However not all of this can necessarily be utilised for CO2 storage. The simplest assumption is that long-term storage of CO2 can only be accomplished in structural traps at the top of the reservoir. A detailed study around Sleipner indicates that 0.3% of the reservoir porosity is actually situated within structural closures such as this. In practical terms moreover, with a small number of injection wells, it is unlikely that all of the small traps could be utilised in any case. Around Sleipner the most realistic estimate of the pore-space situated within accessible closed structures is just 0.11% of the total pore-volume. On the other hand, trapping of CO2 beneath the intra-reservoir shales could significantly increase realisable storage volumes, particularly if it encouraged dissolution of CO2 into the groundwater. Similarly trapping of CO2 in the Sand-wedge, as well as beneath the top of the Utsira Sand, will increase the overall storage capacity significantly. In conclusion, the theoretical storage capacity of the Utsira Sand is very high, but how much of this can be utilised in reality is uncertain, and a function of several complex parameters. Migration models have been constructed with 30 x 106 m3 of CO2, injected into the Utsira Sand (approximating to the expected final injected mass of 20 million tonnes). They show that if the CO2 is trapped at the top of the Utsira Sand it will migrate generally northwestward, reaching a maximum distance from the injection site of about 12 km. However, if the CO2 is trapped within the Sand-wedge, migration is less well constrained, being northwards then northeastwards. Data limitations to the east of the injection point preclude quantitative estimates of the maximum migration distance in this case

Solution structure of Mannobioses unravelled by means of Raman optical activity

Structural analysis of carbohydrates is a complicated endeavour, due to the complexity and diversity of the samples at hand. Herein, we apply a combined computational and experimental approach, employing molecular dynamics (MD) and density functional theory (DFT) calculations together with NMR and Raman optical activity (ROA) measurements, in the structural study of three mannobiose disaccharides, consisting of two mannoses with varying glycosidic linkages. The disaccharide structures make up the scaffold of high mannose glycans and are therefore important targets for structural analysis. Based on the MD population analysis and NMR, the major conformers of each mannobiose were identified and used as input for DFT analysis. By systematically varying the solvent models used to describe water interacting with the molecules and applying overlap integral analysis to the resulting calculational ROA spectra, we found that a full quantum mechanical/molecular mechanical approach is required for an optimal calculation of the ROA parameters. Subsequent normal mode analysis of the predicted vibrational modes was attempted in order to identify possible marker bands for glycosidic linkages. However, the normal mode vibrations of the mannobioses are completely delocalised, presumably due to conformational flexibility in these compounds, rendering the identification of isolated marker bands unfeasible

Marine ecosystem community carbon and nutrient uptake stoichiometry under varying ocean acidification during the PeECE III experiment

Changes to seawater inorganic carbon and nutrient concentrations in response to the deliberate CO2 perturbation of natural plankton assemblages were studied during the 2005 Pelagic Ecosystem CO2 Enrichment (PeECE III) experiment. Inverse analysis of the temporal inorganic carbon dioxide system and nutrient variations was used to determine the net community stoichiometric uptake characteristics of a natural pelagic ecosystem perturbed over a range of pCO2 scenarios (350, 700 and 1050 μatm). Nutrient uptake showed no sensitivity to CO2 treatment. There was enhanced carbon production relative to nutrient consumption in the higher CO2 treatments which was positively correlated with the initial CO2 concentration. There was no significant calcification response to changing CO2 in Emiliania huxleyi by the peak of the bloom and all treatments exhibited low particulate inorganic carbon production (~15 μmol kg−1). With insignificant air-sea CO2 exchange across the treatments, the enhanced carbon uptake was due to increase organic carbon production. The inferred cumulative C:N:P stoichiometry of organic production increased with CO2 treatment from 1:6.3:121 to 1:7.1:144 to 1:8.25:168 at the height of the bloom. This study discusses how ocean acidification may incur modification to the stoichiometry of pelagic production and have consequences for ocean biogeochemical cycling

Kvalitetsindikatorer på barns medvirkning : en studie av mulige indikatorer som kan måle kvaliteten på barns medvirkning i barneverntjenesten

Masteroppgave ledelse ORG917 - Universitetet i Agder 2016"Det heter ikke medvirkning å si sin mening, jeg har sagt masse masse masse til både Fylkesmannen og til andre om mitt institusjonsopphold, men ingenting ble forandra! Er det medvirkning?" (barnevernproff). Medvirkning er et positivt ladet ord som er inn i tiden. Innholdet i begrepet er viet stadig mer oppmerksomhet. Begrepet er tatt inn i grunnloven, barnevernloven og forskrift til barnevernloven. Det råder ingen tvil om at barn og unge skal medvirke i barnevernets arbeid med dem. Det er forsket mye på hva medvirkning innebærer. Forandringsfabrikkens barnevernproffer har også jobbet med å konkretisere hva de mener er reell medvirkning i praksis. De har fremmet gode forslag for Barneverntjenesten som har kommet langt i å implementere ny praksis. Fylkesmannen har mulighet til å føre tilsyn med om barneverntjenesten lar og har latt barn medvirke. Så er ikke dette godt nok ivaretatt? Slik vi ser det, er det ikke det. I et så stort byråkrati som barneverntjenesten i Norge, trengs det et system for å vite om barna får medvirke i barnevernets arbeid med dem. Vi mener det ikke er godt nok å anta at så og så mange prosent medvirker. Det vi i denne oppgaven leter etter, er en måte barneverntjenesten kan holde kontroll med dette på selv, et månedlig oppdatert resultat på medvirkning. Vi har prøvd å finne kvalitetsindikatorer på medvirkning som både dekker forskriftens tre punkter og samtidig tilfredsstiller kravene til gode kvalitetsindikatorer. Det har vist seg ikke å være enkelt, og mange kollegaer og informanter var skeptiske til om dette i det hele tatt var mulig. Det interessante er at vi i løpet av det siste året har funnet frem til tre indikatorer som vi mener kan kvalitetssikre rapportering på barns medvirkning

Overview of the Nordic Seas CARINA data and salinity measurements

Water column data of carbon and carbon relevant hydrographic and hydrochemical parameters from 188 previously non-publicly available cruises in the Arctic, Atlantic, and Southern Ocean have been retrieved and merged into a new database: CARINA (CARbon IN the Atlantic). The data have been subject to rigorous quality control (QC) in order to ensure highest possible quality and consistency. The data for most of the parameters included were examined in order to quantify systematic biases in the reported values, i.e. secondary quality control. Significant biases have been corrected for in the data products, i.e. the three merged files with measured, calculated and interpolated values for each of the three CARINA regions; the Arctic Mediterranean Seas (AMS), the Atlantic (ATL) and the Southern Ocean (SO). With the adjustments the CARINA database is consistent both internally as well as with GLODAP (Key et al., 2004) and is suitable for accurate assessments of, for example, oceanic carbon inventories and uptake rates and for model validation. The Arctic Mediterranean Seas include the Arctic Ocean and the Nordic Seas, and the quality control was carried out separately in these two areas. This contribution provides an overview of the CARINA data from the Nordic Seas and summarises the findings of the QC of the salinity data. One cruise had salinity data that were of questionable quality, and these have been removed from the data product. An evaluation of the consistency of the quality controlled salinity data suggests that they are consistent to at least ±0.005