3,227 research outputs found
Non-exclusionary input prices
This paper models a vertically-integrated provider that is a monopoly supplier of an input that is essential for downstream production. An input price that is “too high” can lead to inefficient foreclosure and one that is “too low” creates incentives for non-price discrimination. The range of non-exclusionary input prices is circumscribed by the input prices generated on the basis of upper-bound and lower-bound displacement ratios. The admissible range of the ratio of downstream to upstream price-cost margins is increasing in the degree of product differentiation and reduces to a single ratio in the limit as the products become perfectly homogeneous
Theory and it ab initio calculation of radiative lifetime of excitons in semiconducting carbon nanotubes
We present theoretical analysis and first-principles calculation of the
radiative lifetime of excitons in semiconducting carbon nanotubes. An intrinsic
lifetime of the order of 10 ps is computed for the lowest optically active
bright excitons. The intrinsic lifetime is however a rapid increasing function
of the exciton momentum. Moreover, the electronic structure of the nanotubes
dictates the existence of dark excitons nearby in energy to each bright
exciton. Both effects strongly influence measured lifetime. Assuming a thermal
occupation of bright and dark exciton bands, we find an effective lifetime of
the order of 10 ns at room temperature, in good accord with recent experiments.Comment: 12 pages, 3 figure
Excitonic Effects and Optical Spectra of Single-Walled Carbon Nanotubes
Many-electron effects often dramatically modify the properties of reduced
dimensional systems. We report calculations, based on an many-electron Green's
function approach, of electron-hole interaction effects on the optical spectra
of small-diameter single-walled carbon nanotubes. Excitonic effects
qualitatively alter the optical spectra of both semiconducting and metallic
tubes. Excitons are bound by ~ 1 eV in the semiconducting (8,0) tube and by ~
100 meV in the metallic (3,3) tube. These large many-electron effects explain
the discrepancies between previous theories and experiments.Comment: 6 pages, 3 figures, 2 table
Extended performance solar electric propulsion thrust system study. Volume 4: Thruster technology evaluation
Several thrust system design concepts were evaluated and compared using the specifications of the most advanced 30 cm engineering model thruster as the technology base. Emphasis was placed on relatively high power missions (60 to 100 kW) such as a Halley's comet rendezvous. The extensions in thruster performance required for the Halley's comet mission were defined and alternative thrust system concepts were designed in sufficient detail for comparing mass, efficiency, reliability, structure, and thermal characteristics. Confirmation testing and analysis of thruster and power processing components were performed, and the feasibility of satisfying extended performance requirements was verified. A baseline design was selected from the alternatives considered, and the design analysis and documentation were refined. The baseline thrust system design features modular construction, conventional power processing, and a concentrator solar array concept and is designed to interface with the Space Shuttle
Toward Practical Non-Contact Optical Strain Sensing Using Single-Walled Carbon Nanotubes
Progress is reported in an emerging non-contact strain sensing technology based on optical properties of single-walled carbon nanotubes (SWCNTs). In this strain-sensing smart skin (“S4”) method, nanotubes are dilutely embedded in a thin polymer film applied to a substrate of interest. Subsequent strain in the substrate is transferred to the nanotubes, causing systematic spectral shifts in their characteristic short-wave infrared fluorescence peaks. A small diode laser excites a spot on the coated surface, and the resulting emission is captured and spectrally analyzed to deduce local strain. To advance performance of the method, we prepare S4 films with structurally selected SWCNTs. These give less congested emission spectra that can be analyzed precisely. However, quenching interactions with the polymer host reduce SWCNT emission intensity by an order of magnitude. The instrumentation that captures SWCNT fluorescence has been made lighter and smaller for hand-held use or mounting onto a positioning mechanism that makes efficient automated strain scans of laboratory test specimens. Statistical analysis of large S4 data sets exposes uncertainties in measurements at single positions plus spatial variations in deduced baseline strain levels. Future refinements to S4 film formulation and processing should provide improved strain sensing performance suitable for industrial application
Ultrafast Optical Spectroscopy of Micelle-Suspended Single-Walled Carbon Nanotubes
We present results of wavelength-dependent ultrafast pump-probe experiments
on micelle-suspended single-walled carbon nanotubes. The linear absorption and
photoluminescence spectra of the samples show a number of chirality-dependent
peaks, and consequently, the pump-probe results sensitively depend on the
wavelength. In the wavelength range corresponding to the second van Hove
singularities (VHSs), we observe sub-picosecond decays, as has been seen in
previous pump-probe studies. We ascribe these ultrafast decays to intraband
carrier relaxation. On the other hand, in the wavelength range corresponding to
the first VHSs, we observe two distinct regimes in ultrafast carrier
relaxation: fast (0.3-1.2 ps) and slow (5-20 ps). The slow component, which has
not been observed previously, is resonantly enhanced whenever the pump photon
energy resonates with an interband absorption peak, and we attribute it to
radiative carrier recombination. Finally, the slow component is dependent on
the pH of the solution, which suggests an important role played by H ions
surrounding the nanotubes.Comment: 6 pages, 8 figures, changed title, revised, to be published in
Applied Physics
Nonsteroidal Antiinflammatory Drug Use and Association With Incident Hypertension in Ankylosing Spondylitis.
ObjectiveNonsteroidal antiinflammatory drugs (NSAIDs) increase blood pressure and potentially cardiovascular burden, which may limit their use in ankylosing spondylitis (AS). Our objective was to determine the association of NSAID use with incident hypertension in a longitudinal AS cohort.MethodsAdults with AS were enrolled in a prospective cohort study of patient outcomes and examined every 4-6 months. Hypertension was defined by patient-reported hypertension; antihypertensive medication use; or, on 2 consecutive visits, systolic blood pressure ≥140 mm Hg or diastolic blood pressure ≥90 mm Hg. Continuous NSAID use was dichotomized based on the validated NSAID index. We assessed the association of NSAID use as a time-varying exposure with the incidence of hypertension using Cox proportional hazards models.ResultsOf the 1,282 patients in the cohort, 628 patients without baseline hypertension had at least 1 year of follow-up and were included in the analysis. Of these, 72% were male, the mean age at baseline was 39 ± 13 years, and 200 patients used NSAIDs continuously. On follow-up, 129 developed incident hypertension. After controlling for other variables, continuous NSAID use was associated with a hazard ratio of 1.12 for incident hypertension (95% confidence interval 1.04-1.20), compared to noncontinuous or no use. The association did not differ in subgroups defined by age, body mass index, biologic use, or disease activity.ConclusionIn our prospective, longitudinal AS cohort, continuous NSAID use was associated with a 12% increased risk for the development of incident hypertension, as compared to noncontinuous or no NSAID use
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