2,403 research outputs found
Gapped Heisenberg spin chains in a field
We consider the fully anisotropic Heisenberg spin-1/2 antiferromagnet in a
uniform magnetic field, whose ground-state is characterized by broken spin
rotation symmetry and gapped spinon excitations. We expand on a recent
mean-field approach to the problem by incorporating fluctuations in a loop
expansion. Quantitative results for the magnetization, excitation gap and
specific heat are obtained. We compare our predictions with new DMRG and exact
diagonalization data and, for zero field, with the exact solution of the
spin chain from the Bethe Ansatz.Comment: 11 pages, 14 figure
From Graphene constrictions to single carbon chains
We present an atomic-resolution observation and analysis of graphene
constrictions and ribbons with sub-nanometer width. Graphene membranes are
studied by imaging side spherical aberration-corrected transmission electron
microscopy at 80 kV. Holes are formed in the honeycomb-like structure due to
radiation damage. As the holes grow and two holes approach each other, the
hexagonal structure that lies between them narrows down. Transitions and
deviations from the hexagonal structure in this graphene ribbon occur as its
width shrinks below one nanometer. Some reconstructions, involving more
pentagons and heptagons than hexagons, turn out to be surprisingly stable.
Finally, single carbon atom chain bridges between graphene contacts are
observed. The dynamics are observed in real time at atomic resolution with
enough sensitivity to detect every carbon atom that remains stable for a
sufficient amount of time. The carbon chains appear reproducibly and in various
configurations from graphene bridges, between adsorbates, or at open edges and
seem to represent one of the most stable configurations that a few-atomic
carbon system accomodates in the presence of continuous energy input from the
electron beam.Comment: 12 pages, 4 figure
The regulating role of mindfulness in enacted workplace incivility:An experience sampling study
Incivility at work poses a problem, both for individuals who are the targets of incivility and for organizations. However, relatively little is known about what drives or hinders individuals to engage in incivility, and how they respond to their own uncivil behavior. Adopting a self-regulation perspective, we link theories explaining enacted incivility as self-regulatory failure with research about the self-regulatory benefits of mindfulness. We develop and investigate a conceptual model on the role of trait mindfulness in antecedent- and consequent-based processes of enacted workplace incivility. Data from an experience-sampling study across 5 work days provided support for the majority of our hypotheses. Individuals high in trait mindfulness not only showed generally low levels of enacted incivility, but they also displayed less variability in enacted incivility over time. Specifically, while enacted incivility was entrained to the work week and systematically decreased from Monday to Friday for individuals low in mindfulness, enacted incivility remained stable over the course of the work week for individuals high in mindfulness. Furthermore, employees high in trait mindfulness reacted in a more morally mature manner and experienced guilt when having engaged in uncivil behavior compared to their low mindful counterparts. However, increases in guilt for high mindful individuals did not translate into lower levels of enacted incivility the following work day. (PsycInfo Database Record (c) 2021 APA, all rights reserved
Optical Properties of Pentacene and Perfluoropentacene Thin Films
The optical properties of pentacene (PEN) and perfluoropentacene(PFP) thin
films on various SiO2 substrates were studied using variable angle
spectroscopic ellipsometry. Structural characterization was performed using
X-ray reflectivity and atomic force microscopy. A uniaxial model with the optic
axis normal to the sample surface was used to analyze the ellipsometry data. A
Strong optical anisotropy was observed and enabled the direction of the
transition dipole of the absorption bands to be determined. Furthermore,
comparison of the optical constants of PEN and PFP thin films with the
absorption spectra of the monomers in solution shows significant changes due to
the crystalline environment. Relative to the monomer spectrum the HOMO-LUMO
transition observed in PEN (PFP) thin film is reduced by 210 meV (280 meV).
Surprisingly, a second absorption band in the PFP thin film shows a slight
blueshift (40 meV) compared to the spectrum of the monomer with its transition
dipole perpendicular to that of the first absorption band.Comment: 6 pages, 6 figures, submitted to J. Chem. Phy
Housing situation and healthcare for patients in a psychiatric centre in Berlin, Germany: a cross-sectional patient survey
OBJECTIVE:
To determine the housing situation among people seeking psychiatric treatment in relation to morbidity and service utilisation.
DESIGN:
Cross-sectional patient survey.
SETTING:
Psychiatric centre with a defined catchment area in Berlin, Germany, March-September 2016.
PARTICIPANTS:
540 psychiatric inpatients including day clinics (43.2% of all admitted patients in the study period (n=1251)).
MAIN OUTCOME MEASURES:
Housing status 30 days prior the interview as well as influencing variables including service use, psychiatric morbidity and sociodemographic variables.
RESULTS:
In our survey, 327 participants (68.7%) currently rented or owned an own apartment; 62 (13.0%) reported to be homeless (living on the street or in shelters for homeless or refugees); 87 (18.3%) were accommodated in sociotherapeutic facilities. Participants without an own apartment were more likely to be male and younger and to have a lower level of education. Homeless participants were diagnosed with a substance use disorder significantly more often (74.2%). Psychotic disorders were the highest among homeless participants (29.0%). Concerning service use, we did neither find a lower utilisation of ambulatory services nor a higher utilisation of hospital-based care among homeless participants.
CONCLUSIONS:
Our findings underline the need for effective housing for people with mental illness. Despite many sociotherapeutic facilities, a concerning number of people with mental illness is living in homelessness. Especially early interventions addressing substance use might prevent future homelessness
Biplots for compositional data derived from generalized joint diagonalization methods
Biplots constructed from principal components of a compositional data set are an established means to explore its features. Principal Component Analysis (PCA) is also used to transform a set of spatial variables into spatially decorrelated factors. However, because no spatial structures are accounted for in the transformation the application of PCA is limited. In geostatistics and blind source separation a variety of different matrix diagonalization methods have been developed with the aim to provide spatially or temporally decorrelated factors. Just as PCA, many of these transformations are linear and so lend themselves to the construction of biplots. In this contribution we consider such biplots for a number of methods (MAF, UWEDGE and RJD transformations) and discuss how and if they can contribute to our understanding of relationships between the components of regionalized compositions. A comparison of the biplots with the PCA biplot commonly used in compositional data analysis for the case of data from the Northern Irish geochemical survey shows that the biplots from MAF and UWEDGE are comparable as are those from PCA and RJD. The biplots emphasize different aspects of the regionalized composition: for MAF and UWEDGE the focus is the spatial continuity, while for PCA and RJD it is variance explained. The results indicate that PCA and MAF combined provide adequate and complementary means for exploratory statistical analysis
Targeted micro-heterogeneity in bioinks allows for 3D printing of complex constructs with improved resolution and cell viability
Three-dimensional bioprinting is an evolving versatile technique for biomedical applications. Ideal bioinks have complex micro-environment that mimic human tissue, allow for good printing quality and provide high cell viability after printing. Here we present two strategies for enhancing gelatin-based bioinks heterogeneity on a 1–100 µm length scale resulting in superior printing quality and high cell viability. A thorough spatial and micro-mechanical characterization of swollen hydrogel heterogeneity was done using multiple particle tracking microrheology. When poly(vinyl alcohol) is added to homogeneous gelatin gels, viscous inclusions are formed due to micro-phase separation. This phenomenon leads to pronounced slip and superior printing quality of complex 3D constructs as well as high human hepatocellular carcinoma (HepG2) and normal human dermal fibroblast (NHDF) cell viability due to reduced shear damage during extrusion. Similar printability and cell viability results are obtained with gelatin/nanoclay composites. The formation of polymer/nanoclay clusters reduces the critical stress of gel fracture, which facilitates extrusion, thus enhancing printing quality and cell viability. Targeted introduction of micro-heterogeneities in bioinks through micro-phase separation is an effective technique for high resolution 3D printing of complex constructs with high cell viability. The size of the heterogeneities, however, has to be substantially smaller than the desired feature size in order to achieve good printing quality
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