Improved pH buffering agent for sodium hypochlorite

Sodium citrate/citric acid was found to be an effective buffer for pH control when used with sodium hypochlorite. The mixture does not corrode aluminum. The buffer appears to form a type of conversion coating that may provide corrosion-resistant properties to aluminum in other applications

Hydrographic Study of Peirce Island Wastewater Treatment Plant Effluent in the Piscataqua River of Portsmouth, New Hampshire: Report of Findings from the December 10 – 14, 2012 Study Period

In order to assist the New Hampshire Department of Environmental Services (NHDES) evaluate the impact of treated wastewater effluent from Peirce Island Wastewater Treatment Plant (WWTP) to the Lower Piscataqua River and Portsmouth Harbor a hydrographic dye study was conducted in December 2012 in Portsmouth, NH. Eight (8) shellfish cages with American oysters (Crassostrea virginica) and blue mussels (Mytilus edulis) were deployed both upstream and downstream of the Peirce Island WWTP in the Piscataqua River, Little Harbor, and the entrance of Little Bay. Eight (8) mini CTDs that monitor conductivity/salinity, temperature, and depth, and six (6) moored fluorometers, which measure dye tagged effluent from the Peirce Island WWTP were attached to the subsurface cages. A fifty (50) gallon mixture of Rhodamine WT dye and distilled water was injected into WWTP on December 11, 2012 for a half tidal cycle (approximately 12.4 hours). Additionally, boat tracking fluorometers connected with a mobile geographic information system (GIS) were used to measure dye levels on the surface in situ and in real time. Microbiological analyses of fecal coliform (FC), male-specific coliphage (MSC), Norovirus (NoV) genogroup I (GI) and genogroup II (GII), and Adenovirus (AdV) were conducted on WWTP influent and effluent composite samples collected with automated samplers to determine the WWTP efficiency in reducing indicator bacteria and viruses. Microbiological sampling and testing of oysters and mussels from the eight (8) sentinel cages was conducted to assess the impact of WWTP effluent on shellfish growing areas and growing area classifications. Prior to conducting the study, the assumption was that the FDA’s recommended minimum dilution of 1000:1was not applicable in this situation because the recommended dilution is based on a WWTP having at least secondary treatment. The microbiological findings in shellfish samples, wastewater samples from the Peirce Island WWTP, and the results of the dye study, confirm that a minimum of 1,000:1 dilution with respect to Peirce Island WWTP is currently not applicable for this WWTP. The FDA and NHDES recommend continued MSC testing of wastewater samples from the WWTP before and after the WWTP upgrade. The FDA and NHDES recommend a future field study after the WWTP upgrade in order to delineate the 1,000:1 dilution zone

Topological Phase Transitions and Holonomies in the Dimer Model

We demonstrate that the classical dimer model defined on a toroidal hexagonal lattice acquires holonomy phases in the thermodynamic limit. When all activities are equal the lattice sizes must be considered mod 6 in which case the finite size corrections to the bulk partition function correspond to a massless Dirac Fermion in the presence of a flat connection with nontrivial holonomy. For general bond activities we find that the phase transition in this model is a topological one, where the torus degenerates and its modular parameter becomes real at the critical temperature. We argue that these features are generic to bipartite dimer models and we present a more general lattice whose continuum partition function is that of a massive Dirac Fermion.Comment: 7 pages, 4 figures. Minor corrections with additional figure

Decidability Results for Multi-objective Stochastic Games

We study stochastic two-player turn-based games in which the objective of one player is to ensure several infinite-horizon total reward objectives, while the other player attempts to spoil at least one of the objectives. The games have previously been shown not to be determined, and an approximation algorithm for computing a Pareto curve has been given. The major drawback of the existing algorithm is that it needs to compute Pareto curves for finite horizon objectives (for increasing length of the horizon), and the size of these Pareto curves can grow unboundedly, even when the infinite-horizon Pareto curve is small. By adapting existing results, we first give an algorithm that computes the Pareto curve for determined games. Then, as the main result of the paper, we show that for the natural class of stopping games and when there are two reward objectives, the problem of deciding whether a player can ensure satisfaction of the objectives with given thresholds is decidable. The result relies on intricate and novel proof which shows that the Pareto curves contain only finitely many points. As a consequence, we get that the two-objective discounted-reward problem for unrestricted class of stochastic games is decidable.Comment: 35 page

Culturally safe speech-language supports for First Nations children: Achieving Sustainable Development Goals 3, 4, 8 and 10

Purpose: Self-determination is foundational to health and well-being for First Nations people. Colonisation has undermined self-determination and widespread effects are observed as disparities in health and well-being. Chronic middle ear disease is more highly prevalent in First Nations children, is associated with delays in speech and language and lower levels of educational readiness. However, there is a paucity of culturally and linguistically sensitive speech-language assessments and habilitation services globally. Focussing on high-income colonial-settler countries (including United States, Canada, Australia and New Zealand), where health disparities are significant, we aim to discuss the importance of and the challenges in providing culturally safe care to First Nations children with communication disabilities. Result: To be effective, both cultural and linguistic diversity and cultural safety must be considered in all aspects of assessment and intervention. Furthermore, speech-language pathologists must be equipped to work with First Nations children with communication disorders. Conclusion: To optimally support First Nations’ children with communication disabilities, services need to be culturally safe, family-centred and strengths-based. This commentary focuses on the United Nations Sustainable Development Goals (SDGs)3, 4, 8 and 10

Effect of retardation on dynamical mass generation in two-dimensional QED at finite temperature

The effect of retardation on dynamical mass generation in is studied, in the imaginary time formalism. The photon porarization tensor is evaluated to leading order in 1/N (N is the number of flavours), and simple closed form expressions are found for the fully retarded longitudinal and transverse propagators, which have the correct limit when T goes to zero. The resulting S-D equation for the fermion mass (at order 1/N) has an infrared divergence associated with the contribution of the transverse photon propagator; only the longitudinal contribution is retained, as in earlier treatments. For solutions of constant mass, it is found that the retardation reduces the value of the parameter r (the ratio of twice the mass to the critical temperature) from about 10 to about 6. The gap equation is then solved allowing for the mass to depend on frequency. It was found that the r value remained close to 6. Possibilities for including the transverse propagator are discussed.Comment: 26 pages 8 figure

Influence of rare regions on magnetic quantum phase transitions

The effects of quenched disorder on the critical properties of itinerant quantum magnets are considered. Particular attention is paid to locally ordered rare regions that are formed in the presence of quenched disorder even when the bulk system is still in the nonmagnetic phase. It is shown that these local moments or instantons destroy the previously found critical fixed point in the case of antiferromagnets. In the case of itinerant ferromagnets, the critical behavior is unaffected by the rare regions due to an effective long-range interaction between the order parameter fluctuations.Comment: 4 pp., REVTe

An evaluation of sampling methodology for assessing settlement of temperate fish in seagrass meadows

All demersal fish with planktonic larvae settle at some point early in life, generally around the transformation from larvae to juveniles or soon after. Sampling pre-settlement or very young, settled fish is challenging due to spatial concretions within the habitat and the pulsed, rapid nature of the settlement process. There is a lack of robust methods that enable this sampling, but information on the settlement, that represents a mortality bottleneck, is crucial for the follow-up of populations for fisheries and conservation purposes. An empirical evaluation of sampling methods has not been conducted in temperate habitats. Here, we compare six different sampling methods to collect pre- and post-settlement stages of fish to determine the best combination of techniques to utilise in Posidonia oceanica, an endemic Mediterranean seagrass that provides a key nursery habitat for coastal fish. We considered three types of pelagic nets (bongo net, neuston net and ring net), two types of light-traps (Quatrefoil and Ecocean CARE®) to sample pre-settled stages and a low-impact epibenthic trawl for recent settlers. Our results show a significantly different size-spectrum for each method, with a continuous range of sizes from 2 mm to 200 mm. The smallest sizes were collected by the bongo net, followed by the ring net, the neuston net, the Quatrefoil, the Ecocean and finally the epibenthic trawl. Our results suggest that an appropriate strategy for collecting and estimating the abundance of key littoral fish species around settlement size is the combination of the Ecocean light trap and the epibenthic trawl