693 research outputs found
The box diagram in Yukawa theory
We present a light-front calculation of the box diagram in Yukawa theory. The
covariant box diagram is finite for the case of spin-1/2 constituents
exchanging spin-0 particles. In light-front dynamics, however, individual
time-ordered diagrams are divergent. We analyze the corresponding light-front
singularities and show the equivalence between the light-front and covariant
results by taming the singularities.Comment: 21 pages, 17 figures. submittes to Phys. Rev.
Tracking the Orbital and Super-orbital Periods of SMC X-1
The High Mass X-ray Binary (HMXB) SMC X-1 demonstrates an orbital variation
of 3.89 days and a super-orbital variation with an average length of 55 days.
As we show here, however, the length of the super-orbital cycle varies by
almost a factor of two, even across adjacent cycles. To study both the orbital
and super-orbital variation we utilize lightcurves from the Rossi X-ray Timing
Explorer All Sky Monitor (RXTE-ASM). We employ the orbital ephemeris from
Wojdowski et al. (1998) to obtain the average orbital profile, and we show that
this profile exhibits complex modulation during non-eclipse phases.
Additionally, a very interesting ``bounceback'' in X-ray count rate is seen
during mid-orbital eclipse phases, with a softening of the emission during
these periods. This bounceback has not been previously identified in pointed
observations. We then define a super-orbital ephemeris (the phase of the
super-orbital cycle as a function of date) based on the ASM lightcurve and
analyze the trend and distribution of super-orbital cycle lengths. SMC X-1
exhibits a bimodal distribution of these lengths, similar to what has been
observed in other systems (e.g., Her X-1), but with more dramatic changes in
cycle length. There is some hint, but not conclusive evidence, for a dependence
of the super-orbital cycle length upon the underlying orbital period, as has
been observed previously for Her X-1 and Cyg X-2. Using our super-orbital
ephemeris we are also able to create an average super-orbital profile over the
71 observed cycles, for which we witness overall hardening of the spectrum
during low count rate times. We combine the orbital and super-orbital
ephemerides to study the correlation between the orbital and super-orbital
variations in the system.Comment: 10 pages, using emulateapj style. To be published in the
Astrophysical Journa
Selective Analysis of Redox Processes at the Electrode Interface with Time-Resolved Raman Spectroscopy
Electrochemistry and electrochemical reactions are increasingly important in the transition to a sustainable chemical industry. The electron transfer that drives such reactions takes place within nanometers of the electrode surface, and follow-up chemical reactions take place within the diffusion layer. Hence, understanding electrochemical reactions requires time-, potential-, and spatially resolved analysis. The confocal nature of Raman spectroscopy provides high spatial resolution, in addition to detailed information on molecular structure. The intrinsic weakness of nonresonant Raman scattering, however, is not sensitive enough for relatively minor changes to the solution resulting from reactions at the electrode interface. Indeed, the limit of detection is typically well above the concentrations used in electrochemical studies. Here, we show that surface-enhanced Raman scattering (SERS) and resonance Raman (rR) spectroscopy allow for spatially and time-resolved analysis of solution composition at (<1-2 nm) and near (within 5 μm) the electrode surface, respectively, in a selective manner for species present at low (<1 mM) concentrations. We show changes in concentration of species at the electrode surface, without the need for labels, specific adsorption, or resonance enhancement, using a SERS-active gold electrode prepared readily by electrochemical surface roughening. A combination of smooth and roughened gold electrodes is used to distinguish between surface and resonance enhancement using the well-known redox couples ferrocene and 2,2’-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS). We discuss the impact of specific adsorption on the spectral analysis with the ruthenium(II) polypyridyl complex, [Ru(bpy)3]2+. The dual function of the electrode (surface enhancement and electron transfer) in the analysis of solution processes is demonstrated with the reversible oxidation of TMA (4,N,N-trimethylaniline), where transient soluble species are identified in real time, with rapid spectral acquisition, making use of localized enhancement. We anticipate that this approach will find use in elucidating electro(catalytic) reactions at electrode interfaces.</p
Low Luminosity States of the Black Hole Candidate GX~339--4. II. Timing Analysis
Here we present timing analysis of a set of eight Rossi X-ray Timing Explorer
(RXTE) observations of the black hole candidate GX 339-4 that were taken during
its hard/low state. On long time scales, the RXTE All Sky Monitor data reveal
evidence of a 240 day periodicity, comparable to timescales expected from
warped, precessing accretion disks. On short timescales all observations save
one show evidence of a persistent f approximately equal to 0.3 Hz QPO. The
broad band (10^{-3}-10^2 Hz) power appears to be dominated by two independent
processes that can be modeled as very broad Lorentzians with Q approximately
less than 1. The coherence function between soft and hard photon variability
shows that if these are truly independent processes, then they are individually
coherent, but they are incoherent with one another. This is evidenced by the
fact that the coherence function between the hard and soft variability is near
unity between 0.005-10 Hz but shows evidence of a dip at f approximately equal
to 1 Hz. This is the region of overlap between the broad Lorentzian fits to the
PSD. Similar to Cyg X-1, the coherence also drops dramatically at frequencies
approximately greater than 10 Hz. Also similar to Cyg X-1, the hard photon
variability is seen to lag the soft photon variability with the lag time
increasing with decreasing Fourier frequency. The magnitude of this time lag
appears to be positively correlated with the flux of GX 339-4. We discuss all
of these observations in light of current theoretical models of both black hole
spectra and temporal variability.Comment: To Appear in the AStrophysical Journa
pH-Induced Changes in the SERS Spectrum of Thiophenol at Gold Electrodes during Cyclic Voltammetry
Thiophenol is a model compound used in the study of self-assembly of arylthiols on gold surfaces. In particular, changes in the surface-enhanced Raman scattering (SERS) spectra of these self-assembled monolayers (SAMs) with a change of conditions have been ascribed to, for example, differences in orientation with respect to the surface, protonation state, and electrode potential. Here, we show that potential-induced changes in the SERS spectra of SAMs of thiophenol on electrochemically roughened gold surfaces can be due to local pH changes at the electrode. The changes observed during the potential step and cyclic voltammetry experiments are identical to those induced by acid–base switching experiments in a protic solvent. The data indicate that the potential-dependent spectral changes, assigned earlier to changes in molecular orientation with respect to the surface, can be ascribed to changes in the pH locally at the electrode. The pH at the electrode can change as much as several pH units during electrochemical measurements that reach positive potentials where oxidation of adventitious water can occur. Furthermore, once perturbed by applying positive potentials, the pH at the electrode takes considerable time to recover to that of the bulk solution. It is noted that the changes in pH even during cyclic voltammetry in organic solvents can be equivalent to the addition of strong acids, such as CF3SO3H, and such effects should be considered in the study of the redox chemistry of pH-sensitive redox systems and potential-dependent SERS in particular
Is the `IR Coincidence' Just That?
(Abridged) Motch (1985) suggested that in the hard state of GX 339-4 the soft
X-ray power-law extrapolated backward in energy agrees with the IR flux. Corbel
& Fender (2002) showed that the hard state radio power-law extrapolated forward
in energy meets the extrapolated X-ray power-law at an IR break, which was
explicitly observed twice in GX 339-4. This `IR coincidence' has been cited as
further evidence that a jet might make a significant contribution to the X-rays
in hard state systems. We explore this hypothesis with a series of simultaneous
radio/X-ray observations of GX 339-4, taken during its 1997, 1999, and 2002
hard states. We fit these spectra, in detector space, with a simple, but
remarkably successful, doubly broken power-law that requires an IR spectral
break. For these observations, the break position and the integrated radio/IR
flux have stronger dependences upon the X-rays than the simplest jet
predictions. If one allows for a softening of the X-ray power law with
increasing flux, then the jet model agrees with the correlation. We also find
evidence that the radio/X-ray fcorrelation previously observed in GX 339-4
shows a `parallel track' for the 2002 hard state. The slope of the 2002
correlation is consistent with prior observations; however, the radio amplitude
is reduced. We then examine the correlation in Cyg X-1 through the use of radio
data, obtained with the Ryle radio telescope, and RXTE data, from the ASM and
pointed observations. We again find evidence of `parallel tracks', and here
they are associated with `failed transitions' to the soft state. We also find
that for Cyg X-1 the radio flux is more fundamentally correlated with the hard
X-ray flux.Comment: To Appear in the July 2005 Astrophysical Journal; 9 Pages, uses
emulateapj.st
Control Predictivo MÃn-Máx de una planta piloto
Este trabajo muestra la aplicación de una estrategia de control predictivo mÃn máx basado
en modelos (Min-Max Model Predictive Control, MMMPC) a una planta piloto en la que se controla la
temperatura de un reactor. Para calcular la acción de control se utiliza una aproximación del peor caso,
que permite calcular una solución muy cercana a la del problema mÃn-máx con un coste computacional
mucho menor. Por tanto, es un algoritmo cuya complejidad hace factible una implementación en tiempo
real para valores tÃpicos de los horizontes de predicción y control. El comportamiento del proceso y del
controlador se ilustran mediante resultados experimentalesMinisterio de Eduación y Ciencia DPI2004-07444Ministerio de Eduación y Ciencia DPI2005-0456
Advantages of continuous genotype values over genotype classes for GWAS in higher polyploids: a comparative study in hexaploid chrysanthemum
Background: Association studies are an essential part of modern plant breeding, but are limited for polyploid crops. The increased number of possible genotype classes complicates the differentiation between them. Available methods are limited with respect to the ploidy level or data producing technologies. While genotype classification is an established noise reduction step in diploids, it gains complexity with increasing ploidy levels. Eventually, the errors produced by misclassifications exceed the benefits of genotype classes. Alternatively, continuous genotype values can be used for association analysis in higher polyploids. We associated continuous genotypes to three different traits and compared the results to the output of the genotype caller SuperMASSA. Linear, Bayesian and partial least squares regression were applied, to determine if the use of continuous genotypes is limited to a specific method. A disease, a flowering and a growth trait with h(2) of 0.51, 0.78 and 0.91 were associated with a hexaploid chrysanthemum genotypes. The data set consisted of 55,825 probes and 228 samples. Results: We were able to detect associating probes using continuous genotypes for multiple traits, using different regression methods. The identified probe sets were overlapping, but not identical between the methods. Baysian regression was the most restrictive method, resulting in ten probes for one trait and none for the others. Linear and partial least squares regression led to numerous associating probes. Association based on genotype classes resulted in similar values, but missed several significant probes. A simulation study was used to successfully validate the number of associating markers. Conclusions: Association of various phenotypic traits with continuous genotypes is successful with both uni- and multivariate regression methods. Genotype calling does not improve the association and shows no advantages in this study. Instead, use of continuous genotypes simplifies the analysis, saves computational time and results more potential markers
Going with the flow: can the base of jets subsume the role of compact accretion disk coronae?
The hard state of X-ray binaries (XRBs) is characterized by a power law
spectrum in the X-ray band, and a flat/inverted radio/IR spectrum associated
with occasionally imaged compact jets. It has generally been thought that the
hard X-rays result from Compton upscattering of thermal accretion disk photons
by a hot, coronal plasma whose properties are inferred via spectral fitting.
Interestingly, these properties-especially those from certain magnetized corona
models-are very similar to the derived plasma conditions at the jet footpoints.
Here we explore the question of whether the `corona' and `jet base' are in fact
related, starting by testing the strongest premise that they are synonymous. In
such models, the radio through the soft X-rays are dominated by synchrotron
emission, while the hard X-rays are dominated by inverse Compton at the jet
base - with both disk and synchrotron photons acting as seed photons. The
conditions at the jet base fix the conditions along the rest of the jet, thus
creating a direct link between the X-ray and radio emission. We also add to
this model a simple iron line and convolve the spectrum with neutral
reflection. After forward-folding the predicted spectra through the detector
response functions, we compare the results to simultaneous radio/X-ray data
obtained from the hard states of the Galactic XRBs GX339-4 and Cygnus X-1.
Results from simple Compton corona model fits are also presented for
comparison. We demonstrate that the jet model fits are statistically as good as
the single-component corona model X-ray fits, yet are also able to address the
simultaneous radio data.Comment: Accepted to the Astrophysical Journal. 14 pages, emulateapj.st
Electrochemical Ring-Opening and -Closing of a Spiropyran
The bistability of molecular switches is an essential characteristic in their use as functional components in molecular-based devices and machines. For photoswitches, light-driven switching between two stable states proceeds via short-lived changes of the bond order in electronically excited states. Here, bistable switching of a ditertbutyl-substituted spiropyran photoswitch is instead demonstrated by oxidation and subsequent reduction in an overall four-state cycle. The spiropyran structure chosen has reduced sensitivity to the effect of secondary electrochemical processes such as H+ production and provides transient access to a decreased thermal Z-E isomerization barrier in the one electron oxidized state, akin to that achieved in the corresponding photochemical path. Thus, we show that the energy needed for switching spiropyrans to the merocyanine form on demand, typically delivered by a photon, can instead be provided electrochemically. This opens up further opportunities for the utilization of spiropyrans in electrically controlled applications and devices
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