Vitrification and determination of the crystallization time scales of the bulk-metallic-glass-forming liquid Zr58.5Nb2.8Cu15.6Ni12.8Al10.3

The crystallization kinetics of Zr58.5Nb2.8Cu15.6Ni12.8Al10.3 were studied in an electrostatic levitation (ESL) apparatus. The measured critical cooling rate is 1.75 K/s. Zr58.5Nb2.8Cu15.6Ni12.8Al10.3 is the first bulk-metallic-glass-forming liquid that does not contain beryllium to be vitrified by purely radiative cooling in the ESL. Furthermore, the sluggish crystallization kinetics enable the determination of the time-temperature-transformation (TTT) diagram between the liquidus and the glass transition temperatures. The shortest time to reach crystallization in an isothermal experiment; i.e., the nose of the TTT diagram is 32 s. The nose of the TTT diagram is at 900 K and positioned about 200 K below the liquidus temperature

Approximate Homomorphisms of Ternary Semigroups

A mapping $f:(G_1,[ ]_1)\to (G_2,[ ]_2)$ between ternary semigroups will be called a ternary homomorphism if $f([xyz]_1)=[f(x)f(y)f(z)]_2$. In this paper, we prove the generalized Hyers--Ulam--Rassias stability of mappings of commutative semigroups into Banach spaces. In addition, we establish the superstability of ternary homomorphisms into Banach algebras endowed with multiplicative norms.Comment: 10 page

Electrostatic Levitation for Studies of Materials for Additive and In-Space Manufacturing

The electrostatic levitation (ESL) laboratory at NASA's Marshall Space Flight Center (MSFC) is a unique facility for investigators studying high-temperature materials. Electrostatic levitation minimizes gravitational effects and allows materials to be studied without contact with a container or instrumentation

On the Orthogonal Stability of the Pexiderized Quadratic Equation

The Hyers--Ulam stability of the conditional quadratic functional equation of Pexider type f(x+y)+f(x-y)=2g(x)+2h(y), x\perp y is established where \perp is a symmetric orthogonality in the sense of Ratz and f is odd.Comment: 10 pages, Latex; Changed conten

Lightweight Damage Tolerant High-Temperature Radiators for Space Propulsion

No abstract availabl

Asymptotic stability of the Cauchy and Jensen functional equations

The aim of this note is to investigate the asymptotic stability behaviour of the Cauchy and Jensen functional equations. Our main results show that if these equations hold for large arguments with small error, then they are also valid everywhere with a new error term which is a constant multiple of the original error term. As consequences, we also obtain results of hyperstability character for these two functional equations

Reduced-Gravity Measurements of the Effect of Oxygen on Properties of Zirconium

The influence of oxygen on the thermophysical properties of zirconium is being investigated using MSL-EML (Material Science Laboratory - Electromagnetic Levitator) on ISS (International Space Station) in collaboration with NASA, ESA (European Space Agency), and DLR (German Aerospace Center). Zirconium samples with different oxygen concentrations will be put into multiple melt cycles, during which the density, viscosity, surface tension, heat capacity, and electric conductivity will be measured at various undercooled temperatures. The facility check-up of MSL-EML and the first set of melting experiments have been successfully performed in 2015. The first zirconium sample will be tested near the end of 2015. As part of ground support activities, the thermophysical properties of zirconium and ZrO were measured using a ground-based electrostatic levitator located at the NASA Marshall Space Flight Center. The influence of oxygen on the measured surface tension was evaluated. The results of this research will serve as reference data for those measured in ISS

Advances in Non-contact Measurement of Creep Properties

Our team has developed a novel approach to measuring creep at extremely high temperatures using electrostatic levitation (ESL). This method has been demonstrated on niobium up to 2300 C, while ESL has melted tungsten (3400 C). High-precision machined spheres of the sample are levitated in the NASA MSFC ESL, a national user facility, and heated with a laser. The laser is aligned off-center so that the absorbed photons transfer their momentum to the sample, causing it to rotate at up to 250,000+ RPM. The rapid rotation loads the sample through centripetal acceleration, causing it to deform. The deformation of the sample is captured on high-speed video, which is analyzed by machine-vision software from the University of Massachusetts. The deformations are compared to finite element models to determine the constitutive constants in the creep relation. Furthermore, the noncontact method exploits stress gradients within the sample to determine the stress exponent in a single test. This method was validated in collaboration with the University of Tennessee for niobium at 1985 C, with agreement within the uncertainty of the conventional measurements. A similar method is being employed on Ultra-High-Temperature ZrB2- SiC composites, which may see application in rocket nozzles and sharp leading edges for hypersonic vehicles

Materials Research in Microgravity 2012

Reducing gravitational effects such as thermal and solutal buoyancy enables investigation of a large range of different phenomena in materials science. The Symposium on Materials Research in Microgravity involved 6 sessions composed of 39 presentations and 14 posters with contributions from more than 14 countries. The sessions concentrated on four different categories of topics related to ongoing reduced-gravity research. Highlights from this symposium will be featured in the September 2012 issue of JOM. The TMS Materials Processing and Manufacturing Division, Process Technology and Modeling Committee and Solidification Committee sponsored the symposium

Lightweight, High-Temperature Radiator for Space Propulsion

For high-power nuclear-electric spacecraft, the radiator can account for 40% or more of the power system mass and a large fraction of the total vehicle mass. Improvements in the heat rejection per unit mass rely on lower-density and higher-thermal conductivity materials. Current radiators achieve near-ideal surface radiation through high-emissivity coatings, so improvements in heat rejection per unit area can be accomplished only by raising the temperature at which heat is rejected. We have been investigating materials that have the potential to deliver significant reductions in mass density and significant improvements in thermal conductivity, while expanding the feasible range of temperature for heat rejection up to 1000 K and higher. The presentation will discuss the experimental results and models of the heat transfer in matrix-free carbon fiber fins. Thermal testing of other carbon-based fin materials including carbon nanotube cloth and a carbon nanotube composite will also be presented