Performance des lieux d'enfouissement sanitaire de Laterrière et de Ste-Sophie, Québec, Canada

Ce travail décrit les caractéristiques hydrogéologiques et chimiques de deux lieux d'enfouissement de déchets municipaux localisés au Québec. Le site de Laterrière est en opération depuis 1971 dans une ancienne sablière. Sous les dépôts meubles, la topographie du sotte rocheux est marquée par une vallée qui forme une limite imperméable à l'aquifère de sable et impose un écoulement convergent de l'eau souterraine vers la rivière Chicoutimi. Le site de Ste-Sophie, en opération depuis 1976, repose sur une couche de 3,5 mètres de sables fins saturés recouvrant un lit d'argile marine. La surélévation de la nappe dans les déchets favorise un écoulement divergent vers le périmètre de la zone d'enfouissement.Un réseau de piézomètres installé en bordure des deux sites a permis pendant trente mois de prélever des échantillons d'eau et de les analyser. Dans chaque panache de contamination, l'alcalinité, les ions majeurs Na+, K+, Ca2+, Mg2+, Cl¯, le fer, le manganèse, l'azote total et ammoniacal, les DCO et DBO5 montrent des concentrations généralement supérieures à celles de L'eau naturelle ambiante. A proximité des deux Lieux d'enfouissement, les teneurs en cadmium, chrome, nickel et plomb excèdent les normes québécoises de potabiLité de l'eau. Dans chaque cas, ta distribution des contaminants est surtout régie par le réseau d'écoulement. La dispersion hydrodynamique et les réactions géochimiques dans le sous-sol sont des processus importants d'atténuation des contaminants.This paper describes the hydrogeological and geochemical features of two sanitary landfill sites located in the Province of Quebec : Laterriere and Ste-Sophie. The main objective is to evaluate the leachate attenuation performance of each site. For this project, the Quebec Ministry of the Environment chose two sites with contrasting hydrogeological settings.The Laterriere landfill, in operation since 1971, covers an area of about 32 ha. The refuse is deposited in an old sandpit and the landfill boundary is located 400 meters away from the Chicoutimi River, 25 meters above the stream water level. The bedrock topography shows a valley under the landfill which acts an an impervious base for the sand aquifer and induces a convergent groundwater flow towards the river.The Ste-Sophie landfill covers an area of 48 ha and began operating in 1976. The refuse zone is located on flat ground 350 meters away from the Ruisseau-aux-Castors. The refuse is deposited on a 3.5 meter layer of fine sands nearly saturated overlying a marine clay bed. A water table mound is observed beneath the landfill, resulting in diverging low lines outward from the center of the Landfill.For each site, the occurence and migration of contaminants was investigated using networks of piezometers. Sampling was performed monthly over a period of thirty months and thirty parameters were analyzed on each sample. The analytical results were entered in a database and treated by statistical methods.The shape of each contamination plume is controlled mainly by the groundwater flow system. At Laterriere, the plume is restricted to a narrow path between the landfill and the river and inside a bedrock valley. This flow net has been simulated by a two-dimensional finite elements model. At Ste-Sophie, the divergence of flow lines due to groundwater mounding beneath the site causes dispersion of contaminants around the landfill. The use of an analytical solution shows that longitudinal dispersivity is a major process of contaminant migration.For the two landfills, the highest concentrations of contaminants occur directly beneath or close to the boundaries of the landfills. Total alkalinity, Na+, K+, Ca2+, Mg2+, Cl¯, iron, manganèse, total and ammoniacal nitrogen, chemical and biological oxygen demand (COD and BOD) are much above background levels throughout the plume. Sulfate is also a major contaminant at Ste-Sophie with concentration of 1100/mg/l. The concentrations of cadmium, chrome, nickel and lead exceed the drinking water standards near the two landfill sites but they decline rapidly in the direction of flow. At Laterriere, the decline in chloride concentration measured at the discharge point S-23 is about 85 % while the decline of reactive contaminants, such as iron and COD, is respectively 98 and 99.7 %.Finally, we discuss hydrogeological criteria for landfill site selection in Quebec

Modeling Organizational Project Management

© 2019 Project Management Institute, Inc. The contemporary discourse on organizational project management (OPM) complements project, program, and portfolio management with emerging elements, such as governance, projectification, the project management office (PMO), and organizational design. This creates the need for an integrated model that defines the content and roles in OPM. This article addresses this by conceptually developing a seven-layered model that organizes 22 OPM elements, ranging from the corporate level to the management of individual projects. A theory is developed to explain the interaction of the elements and the layers within the model

Torsion–rotation global analysis of the first three torsional states (νt = 0, 1, 2) and terahertz database for methanol

Stimulated by recent THz measurements of the methanol spectrum in one of our laboratories, undertaken in support of NASA programs related to the Herschel Space Observatory (HSO) and the Atacama Large Millimeter Array (ALMA), we have carried out a global analysis of available microwave and high-resolution infrared data for the first three torsional states (νt = 0, 1, 2), and for J values up to 30. This global fit of approximately 5600 frequency measurements and 19 000 Fourier transform far infrared (FTFIR) wavenumber measurements to 119 parameters reaches the estimated experimental measurement accuracy for the FTFIR transitions, and about twice the estimated experimental measurement accuracy for the microwave, submillimeter-wave, and terahertz transitions. The present fit is essentially a continuation of our earlier work, but we have greatly expanded our previous data set and have added a large number of new torsion–rotation interaction terms to the Hamiltonian in our previously used computer program. The results, together with a number of calculated (but unmeasured) transitions, including their line strength, estimated uncertainty, and lower state energy, are made available in the supplementary material as a database formatted to be useful for astronomical searches. Some discussion of several open spectroscopic problems, e.g., (i) an improved notation for the numerous parameters in the torsion–rotation Hamiltonian, (ii) possible causes of the failure to fit frequency measurements to the estimated measurement uncertainty, and (iii) pitfalls to be avoided when intercomparing apparently identical parameters from the internal axis method and the rho axis method are also given

The Digital Flynn Effect: Complexity of Posts on Social Media Increases over Time

Parents and teachers often express concern about the extensive use of social media by youngsters. Some of them see emoticons, undecipherable initialisms and loose grammar typical for social media as evidence of language degradation. In this paper, we use a simple measure of text complexity to investigate how the complexity of public posts on a popular social networking site changes over time. We analyze a unique dataset that contains texts posted by 942, 336 users from a large European city across nine years. We show that the chosen complexity measure is correlated with the academic performance of users: users from high-performing schools produce more complex texts than users from low-performing schools. We also find that complexity of posts increases with age. Finally, we demonstrate that overall language complexity of posts on the social networking site is constantly increasing. We call this phenomenon the digital Flynn effect. Our results may suggest that the worries about language degradation are not warranted

Resistless electron beam lithography process for the fabrication of sub-50 nm silicide structures

We report on a study of the fabrication of submicron silicide structures with a resistless lithography technique. Several different metals can be used as a basis for producing silicide using this method; in this work, results will be discussed for both platinum and nickel silicide. The feasibility of producing nanostructures using polycrystalline silicon as a base growth layer for metal–oxide– semiconductor, and other device applications have also been demonstrated. Threshold doses for this method for submicron lines (<50 nm) and square areas were obtained in order to establish a framework for the fabrication of more complex devices. Preliminary electrical measurements were carried out which indicate that the resistivity of the silicide is 45 [mu omega] cm, and that the barrier height of the silicide/(high resistivity silicon) interface is 0.56 eV

Gender specific factors contributing to cognitive resilience in APOE ɛ4 positive older adults in a population-based sample

Although APOE ɛ4 has been identified as the strongest genetic risk factor for Alzheimer’s Disease, there are some APOE ɛ4 carriers who do not go on to develop Alzheimer’s disease or cognitive impairment. This study aims to investigate factors contributing to this “resilience” separately by gender. Data were drawn from APOE ɛ4 positive participants who were aged 60 + at baseline in the Personality and Total Health Through Life (PATH) Study (N = 341, Women = 46.3%). Participants were categorised into “resilient” and “non-resilient” groups using Latent Class Analysis based on their cognitive impairment status and cognitive trajectory across 12 years. Logistic regression was used to identify the risk and protective factors that contributed to resilience stratified by gender. For APOE ɛ4 carriers who have not had a stroke, predictors of resilience were increased frequency of mild physical activity and being employed at baseline for men, and increased number of mental activities engaged in at baseline for women. The results provide insights into a novel way of classifying resilience among APOE ɛ4 carriers and risk and protective factors contributing to resilience separately for men and women

Exploring vertical and horizontal leadership in projects: A comparison of Indian and Australian contexts

Project-based organisational forms are becoming more and more prevalent in many industries, and leadership influences projects' success ultimately impacting the organisational performance. Two types of leadership styles have been explored: vertical and horizontal. This study aims to identify the nature and balance of vertical and horizontal leadership in projects to allow project managers to consciously poly these approaches in different situations. A case study-based approach is adopted wherein, two case studies from India and three case studies from Australia are included . A comparative study of leadership styles is performed to find the best contextual fit for leadership styles. The findings reveal that that national cultural is not a major factor in influencing project leadership. Rather, organisational culture and a shared understanding on leadership practices is what influences whether vertical or horizontal leadership will be more prevalent. Senior leaders' initiatives to create and support a culture of sharing ideasand decisions, backed by project manager's approach enable effective balance between horizontal and vertical leadership. Horizontal leadership is further by regular meetings and social interactions. Prevalence of horizontal leaderships is demonstrated in technical decisions, as team members have the best expertise to address technical issues. In contrast, strategic decisions are normally discussed with the project manager and often escalated to senior leaders for decisions

Multispectrum Analysis of the Oxygen A-band

Retrievals of atmospheric composition from near-infrared measurements require measurements of airmass to better than the desired precision of the composition. The oxygen bands are obvious choices to quantify airmass since the mixing ratio of oxygen is fixed over the full range of atmospheric conditions. The OCO-2 mission is currently retrieving carbon dioxide concentration using the oxygen A-band for airmass normalization. The 0.25% accuracy desired for the carbon dioxide concentration has pushed the required state-of-the-art for oxygen spectroscopy. To measure 02 A-band cross-sections with such accuracy through the full range of atmospheric pressure requires a sophisticated line shape model (Rautian or Speed-Dependent Voigt) with line mixing (LM) and collision induced absorption (CIA). Models of each of these phenomena exist, however, this work presents an integrated self-consistent model developed to ensure the best accuracy. It is also important to consider multiple sources of spectroscopic data for such a study in order to improve the dynamic range of the model and to minimize effects of instrumentation and associated systematic errors. The techniques of Fourier Transform Spectroscopy (FTS) and Cavity Ring-Down Spectroscopy (CRDS) allow complimentary information for such an analysis. We utilize multispectrum fitting software to generate a comprehensive new database with improved accuracy based on these datasets. The extensive information will be made available as a multi-dimensional cross-section (ABSCO) table and the parameterization will be offered for inclusion in the HITRANonline database