6,455 research outputs found
Diffusion bonding of IN 718 to VM 350 grade maraging steel
Diffusion bonding studies have been conducted on IN 718, VM 350 and the dissimilar alloy couple, IN 718 to maraging steel. The experimental processing parameters critical to obtaining consistently good diffusion bonds between IN 718 and VM 350 were determined. Interrelationships between temperature, pressure and surface preparation were explored for short bending intervals under vacuum conditions. Successful joining was achieved for a range of bonding cycle temperatures, pressures and surface preparations. The strength of the weaker parent material was used as a criterion for a successful tensile test of the heat treated bond. Studies of VM-350/VM-350 couples in the as-bonded condition showed a greater yielding and failure outside the bond region
Concerted reductive coupling of an alkyl chloride at Pt(IV)
Oxidation of a doubly cyclometallated platinum(II) complex results in two isomeric platinum(IV) complexes. Whereas the trans isomer is robust, being manipulable in air at room temperature, the cis isomer decomposes at −20 °C and above. Reductive coupling of an alkyl chloride at the cis isomer gives a new species which can be reoxidised. The independence of this coupling on additional halide rules out the reverse of an SN2 reaction, leaving a concerted process as the only sensible reaction pathway
Two heads are better than one: The association between condom decision-making and condom use errors and problems
This is an open access article - Copyright @ 2008 BMJ Publishing GroupObjectives: This exploratory study compared the frequency of condom use errors and problems between men reporting that condom use for penile–vaginal sex was a mutual decision compared with men making the decision unilaterally.
Methods: Nearly 2000 people completed a web-based questionnaire. A sub-sample of 660 men reporting that they last used a condom for penile–vaginal sex (within the past three months) was analysed. Nine condom use errors/problems were assessed. Multivariate analyses controlled for men’s age, marital status, and level of experience using condoms.
Results: Men’s unilateral decision-making was associated with increased odds of removing condoms before sex ended (adjusted odds ratio (AOR) 2.51, p=0.002), breakage (AOR 3.90, p=0.037), and slippage during withdrawal (AOR 2.04, p=0.019). Men’s self-reported level of experience using condoms was significantly associated with seven out of nine errors/problems, with those indicating less experience consistently reporting more errors/problems.
Conclusions: Findings suggest that female involvement in the decision to use condoms for penile–vaginal sex may be partly protective against some condom errors/problems. Men’s self-reported level of experience using condoms may be a useful indicator of the need for education designed to promote the correct use of condoms. Education programmes may benefit men by urging them to involve their female partner in condom use decisions.Funding for this project was provided by the Canada Research Chair in Social Justice and Sexual Health at the University of Windsor, and the Rural Center for AIDS/STD Prevention and The Kinsey Institute for Research in Sex, Gender, and Reproduction at Indiana University
The Insufficiency of the Causal Mechanisms of Scientific Naturalism
Chance and physical necessity, serving as the two accepted causal mechanisms of scientific naturalism, are incapable of explaining the origins of gravity, the gravitational constant, and other fine-tuning parameters associated with Big Bang Cosmology. This thesis explores the origins of Scientific Naturalism, the discovery of fine-tuning parameters associated with Big Bang Cosmology, and several theories proposed under the paradigm of scientific naturalism that attempt to explain, through either chance or physical necessity, how the universe originated
A theory-based approach to understanding condom errors and problems reported by men attending an STI clinic
The official published version can be accessed from the link below - Copyright @ 2008 Springer VerlagWe employed the information–motivation–behavioral skills (IMB) model to guide an investigation of correlates for correct condom use among 278 adult (18–35 years old) male clients attending a sexually transmitted infection (STI) clinic. An anonymous questionnaire aided by a CD-recording of the questions was administered. Linear Structural Relations Program was used to conduct path analyses of the hypothesized IMB model. Parameter estimates showed that while information did not directly affect behavioral skills, it did have a direct (negative) effect on condom use errors. Motivation had a significant direct (positive) effect on behavioral skills and a significant indirect (positive) effect on condom use errors through behavioral skills. Behavioral skills had a direct (negative) effect on condom use errors. Among men attending a public STI clinic, these findings suggest brief, clinic-based, safer sex programs for men who have sex with women should incorporate activities to convey correct condom use information, instill motivation to use condoms correctly, and directly enhance men’s behavioral skills for correct use of condoms
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Condoms are more effective when applied by males: a study of young black males in the United States
PurposeTo determine, among a sample of young black male (YBM), whether female application of male condoms for penile–vaginal intercourse would be associated with higher or lower rates of breakage or slippage. A secondary aim was to investigate if higher rates of breakage or slippage were associated with increased odds of acquiring chlamydia and/or gonorrhea.MethodsA cross-sectional study of 412 YBM, aged 15 to 23 years, was conducted in three US cities located in the Southern United States.ResultsAmong YBM reporting frequent female application of condoms, 43.5% reported one or more instance of breakage or slippage, compared with those reporting less frequent female application (27.2%, P = .003). Among YBM reporting one or more event of breakage or slippage, 25.4% tested positive for chlamydia and/or gonorrhea. In contrast, among those not reporting breakage or slippage, 17.2% tested positive (P = .047).ConclusionsFindings suggest that educational and behavioral interventions should seek to improve young women's skills relative to condom application and use. Further studies could also investigate whether intervention efforts should encourage some YBM to be responsible for their own condom application
Effect of Abundance and Survey Protocol on Estimates of Occupancy and Detection Probability for Northern Bobwhites
We compared estimates of occupancy of northern bobwhite (Colinus virginianus) between areas with relatively low and high abundance using single-survey and multiple-survey protocols, with and without accounting for detection probability, and investigated how time during the breeding season affected detection probability in Oklahoma, USA, in 2009–2011. Estimates of occupancy and detection probability increased as the number of survey occasions increased. Detection probability was significantly higher in the area of high abundance (P 0.001), and increased as the breeding season advanced from mid-May to late July. Accounting for detection probability increased occupancy estimates by 31% in the low-abundance area but only 1.9% in the high abundance area when using 3 survey occasions per year. Managers using occupancy to detect changes in bobwhite populations should use 4 survey occasions per year to ensure accurate estimates of both occupancy and detection probability
3-(2-Acetylanilino)propanoic acid
The title molecule, C11H13NO3, has its propanoic acid group in an extended conformation, such that the molecule is nearly planar, with a mean deviation of 0.036 Å [the maxima being 0.106 (1) and 0.110 (1) Å for the two methylene C atoms]. The NH group forms an intramolecular hydrogen bond with the acetyl group; in the crystal COOH group forms a centrosymmetric hydrogen-bonded dimer
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