Improving the magnetic heating by disaggregating nanoparticles

Recently, potential applications of the magnetic heating for heterogeneous catalysis or organic synthesis have been reported. As these new applications are not limited by biocompatibility requirements, a wide range of possibilities for non-aqueous colloidal nanoparticles with enhanced magnetic properties is open. In this work, manganese and cobalt ferrite nanoparticles are synthesized by co-precipitation method with average particle size around 12 nm. The particles are either coated with tetramethylammonium hydroxide (TMAOH) and dispersed in water or with oleic acid (OA) and dispersed in hexane to produce aggregated or disaggregated nanoparticles, respectively. It is observed that the particle disaggregation improves significantly the heating efficiency from 12 to 96 W/g in the case of cobalt ferrite, and from 120 to 413 W/g for the manganese ferrite. The main responsible for this improvement is the reduction of hydrodynamic volume that allows a faster Brownian relaxation. This work also discusses the relevance of the size distribution

El VAP-CAP: una herramienta útil para la valoración del funcionamiento visual en bebés y niños con polidiscapacidad

Las autoras exponen su experiencia de utilización durante 18 años del Programa VAP-CAP (Visual Assessment and Programming-Capacity Attention and Processing) (Blanksby, 1992) como método de valoración del funcionamiento visual en el Programa de Atención Temprana del Centro de Recursos Educativos de la ONCE en Sevilla. Describen el modelo de atención temprana de este centro y los principales aspectos de la intervención. Hacen una breve descripción del VAP-CAP, analizan sus aportaciones específicas y refieren las adaptaciones realizadas sobre la traducción (de Susana Crespo) del manual y de los materiales complementarios, así como de las actividades de divulgación del programa

El VAP-CAP: una herramienta útil para la valoración del funcionamiento visual en bebés y niños con polidiscapacidad

Las autoras exponen su experiencia de utilización durante 18 años del Programa VAP-CAP (Visual Assessment and Programming-Capacity Attention and Processing) (Blanksby, 1992) como método de valoración del funcionamiento visual en el Programa de Atención Temprana del Centro de Recursos Educativos de la ONCE en Sevilla. Describen el modelo de atención temprana de este centro y los principales aspectos de la intervención. Hacen una breve descripción del VAP-CAP, analizan sus aportaciones específicas y refieren las adaptaciones realizadas sobre la traducción (de Susana Crespo) del manual y de los materiales complementarios, así como de las actividades de divulgación del programa

Impact of agent reliability and predictability on trust in real time human-agent collaboration

Trust is a prerequisite for effective human-agent collaboration. While past work has studied how trust relates to an agent's reliability, it has been mainly carried out in turn based scenarios, rather than during real-time ones. Previous research identified the performance of an agent as a key factor influencing trust. In this work, we posit that an agent's predictability also plays an important role in the trust relationship, which may be observed based on users' interactions. We designed a 2x2 within-groups experiment with two baseline conditions: (1) no agent (users' individual performance), and (2) near-flawless agent (upper bound). Participants took part in an interactive aiming task where they had to collaborate with different agents that varied in terms of their predictability, and were controlled in terms of their performance. Our results show that agents whose behaviours are easier to predict have a more positive impact on task performance, reliance and trust while reducing cognitive workload. In addition, we modelled the human-agent trust relationship and demonstrated that it is possible to reliably predict users' trust ratings using real-time interaction data. This work seeks to pave the way for the development of trust-aware agents capable of adapting and responding more appropriately to users

Magnetic Nanoparticles for Power Absorption: optimizing size, shape and magnetic properties

We present a study on the magnetic properties of naked and silica-coated Fe3O4 nanoparticles with sizes between 5 and 110 nm. Their efficiency as heating agents was assessed through specific power absorption (SPA) measurements as a function of particle size and shape. The results show a strong dependence of the SPA with the particle size, with a maximum around 30 nm, as expected for a Neel relaxation mechanism in single-domain particles. The SiO2 shell thickness was found to play an important role in the SPA mechanism by hindering the heat outflow, thus decreasing the heating efficiency. It is concluded that a compromise between good heating efficiency and surface functionality for biomedical purposes can be attained by making the SiO2 functional coating as thin as possible.Comment: 15 pages, 7 figures, 2 table

Particle interactions in liquid magnetic colloids by zero field cooled measurements: effects on heating efficiency

The influence of magnetic interactions in assemblies formed by either aggregated or disaggregated uniform gamma-Fe_2O_3 particles are investigated as a function of particle size, concentration, and applied field. Hyperthermia and magnetization measurements are performed in the liquid phase of colloids consisting of 8 and 13 nm uniform gamma-Fe_2O_3 particles dispersed in water and hexane. Although hexane allows the disagglomerated obtaining particle system; aggregation is observed in the case of water colloids. The zero field cooled (ZFC) curves show a discontinuity in the magnetization values associated with the melting points of water and hexane. Additionally, for 13 nm gamma-Fe_2O_3 dispersed in hexane, a second magnetization jump is observed that depends on particle concentration and shifts toward lower temperature by increasing applied field. This second jump is related to the strength of the magnetic interactions as it is only present in disagglomerated particle systems with the largest size, i.e., is not observed for 8 nm superparamagnetic particles, and surface effects can be discarded. The specific absorption rate (SAR) decreases with increasing concentration only for the hexane colloid, whereas for aqueous colloids, the SAR is almost independent of particle concentration. Our results suggest that, as a consequence of the magnetic interactions, the dipolar field acting on large particles increases with concentration, leading to a decrease of the SAR