Literature review of physical and chemical pretreatment processes for lignocellulosic biomass

Different pretreatment technologies published in public literature are described in terms of the mechanisms involved, advantages and disadvantages, and economic assessment. Pretreatment technologies for lignocellulosic biomass include biological, mechanical, chemical methods and various combinations thereof. The choice of the optimum pretreatment process depends very much on the objective of the biomass pretreatment, its economic assessment and environmental impact. Only a small number of pretreatment methods has been reported as being potentially cost-effective thus far. These include steam explosion, liquid hot water, concentrated acid hydrolysis and dilute acid pretreatments

Dynamical properties of a dissipative discontinuous map: A scaling investigation

The effects of dissipation on the scaling properties of nonlinear discontinuous maps are investigated by analyzing the behavior of the average squared action \left as a function of the $n$-th iteration of the map as well as the parameters $K$ and $\gamma$, controlling nonlinearity and dissipation, respectively. We concentrate our efforts to study the case where the nonlinearity is large; i.e., $K\gg 1$. In this regime and for large initial action $I_0\gg K$, we prove that dissipation produces an exponential decay for the average action \left. Also, for $I_0\cong 0$, we describe the behavior of \left using a scaling function and analytically obtain critical exponents which are used to overlap different curves of \left onto an universal plot. We complete our study with the analysis of the scaling properties of the deviation around the average action $\omega$.Comment: 20 pages, 7 figure

Simulation of Jahn-Teller-Dicke Magnetic Structural Phase Transition with Trapped Ions

We study theoretically the collective E$\otimes$e Jahn-Teller-Dicke distortion in a system of trapped ions. We focus in the limit of infinite range interactions in which an ensemble of effective spins interacts with two collective vibrational modes with U(1) symmetric couplings. Our model is exactly solvable in the thermodynamical limit and it is amenable to be solved by exact numerical diagonalization for a moderate number of ions. We show that trapped ions are ideally suited to study the emergence of spontaneous symmetry breaking of a continuous symmetry and magnetic structural phase transition in a mesoscopic system.Comment: 19 pages, 7 figure

Properties of bow-shock sources at the Galactic center

There are an enigmatic population of massive stars around the Galactic Center (GC) that were formed some Ma ago. A fraction of these stars has been found to orbit the supermassive black hole, SgrA*, in a projected clockwise disk, which suggests that they were formed in a formerly existing dense disk around SgrA*. We focus on the extended, near-infrared (NIR) sources IRS1W, IRS5, IRS10W, and IRS21 that have been suggested to be young, massive stars that form bow-shocks through their interaction with the ISM. Their nature has impeded accurate determination of their orbital parameters. We aim at establishing their nature and kinematics to test whether they form part of the clockwise disk. We performed NIR multi-wavelength imaging using adaptive optics (AO) and sparse aperture masking (SAM). We introduce a new method for self-calibration of the SAM PSF in dense stellar fields. The emission mechanism, morphology and kinematics of the targets were examined via 3D bow-shock models. We confirm previous findings that IRS21, IRS1W, and IRS5 are bow-shocks created by the interaction between mass-losing stars and the interstellar gas. The nature of IRS10W remains unclear. Our modeling shows that the bow-shock-emission is caused by thermal emission while the scattering of stellar light does not play any significant role. IRS 1W appears to be a bow-shock produced by an anisotropic stellar wind or by locally inhomogeneous ISM density. Our best-fit models provide an estimate of the local proper motion of the ISM in the NA in agreement with the published models. Assuming that all of the sources are tied to SgrA*, their orbital planes were obtained via a Monte-Carlo simulation. Our orbital analysis suggests that they are not part of any of the clockwise disk. We thus add more evidence to recent findings that a large part of the massive stars show apparently random orbital orientations.Comment: accepted for publication by A&A, 17 pages, 11 figures, 1 appendi

Direct Detection of the Tertiary Component in the Massive Multiple HD 150 136 with VLTI

Massive stars are of fundamental importance for almost all aspects of astrophysics, but there still exist large gaps in our understanding of their properties and formation because they are rare and therefore distant. It has been found that most O-stars are multiples. HD 150 136 is the nearest system to Earth with >100 M_sol, and provides a unique opportunity to study an extremely massive system. Recently, evidence for the existence of a third component in HD 150 136, in addition to the tight spectroscopic binary that forms the main component, was found in spectroscopic observations. Our aim was to image and obtain astrometric and photometric measurements of this component using long baseline optical interferometry to further constrain the nature of this component. We observed HD150136 with the near-infrared instrument AMBER attached to the ESO VLT Interferometer. The recovered closure phases are robust to systematic errors and provide unique information on the source asymmetry. Therefore, they are of crucial relevance for both image reconstruction and model fitting of the source structure. The third component in HD 150 136 is clearly detected in the high-quality data from AMBER. It is located at a projected angular distance of 7.3 mas, or about 13 AU at the line-of-sight distance of HD 150 136, at a position angle of 209 degrees East of North, and has a flux ratio of 0.25 with respect to the inner binary. We resolved the third component of HD 150 136 in J, H and K filters. The luminosity and color of the tertiary agrees with the predictions and shows that it is also an O main-sequence star. The small measured angular separation indicates that the tertiary may be approaching the periastron of its orbit. These results, only achievable with long baseline near infrared interferometry, constitute the first step towards the understanding of the massive star formation mechanisms

Excitation Enhancement of a Quantum Dot Coupled to a Plasmonic Antenna

Plasmonic antennas are key elements to control the luminescence of quantum emitters. However, the antenna's influence is often hidden by quenching losses. Here, the luminescence of a quantum dot coupled to a gold dimer antenna is investigated. Detailed analysis of the multiply excited states quantifies the antenna's influence on the excitation intensity and the luminescence quantum yield separately

Unveiling the near-infrared structure of the massive-young stellar object NGC 3603 IRS 9A with sparse aperture masking and spectroastrometry

Contemporary theory holds that massive stars gather mass during their initial phases via accreting disk-like structures. However, conclusive evidence for disks has remained elusive for the most massive young objects. This is mainly due to significant observational challenges. Incisive studies, even targeting individual objects, are therefore relevant to the progression of the field. NGC 3603 IRS 9A* is a young massive stellar object still surrounded by an envelope of molecular gas. Previous mid-infrared observations with long-baseline interferometry provided evidence for a disk of 50 mas diameter at its core. This work aims at a comprehensive study of the physics and morphology of IRS 9A at near-infrared wavelengths. New sparse aperture masking interferometry data taken with NACO/VLT at Ks and Lp filters were obtained and analysed together with archival CRIRES spectra of the H2 and BrG lines. The calibrated visibilities recorded at Ks and Lp bands suggest the presence of a partially resolved compact object of 30 mas at the core of IRS 9A, together with the presence of over-resolved flux. The spectroastrometric signal of the H2 line shows that this spectral feature proceeds from the large scale extended emission (300 mas) of IRS 9A, while the BrG line appears to be formed at the core of the object (20 mas). This scenario is consistent with the brightness distribution of the source for near- and mid-infrared wavelengths at various spatial scales. However, our model suffers from remaining inconsistencies between SED modelling and the interferometric data. Moreover, the BrG spectroastrometric signal indicates that the core of IRS 9A exhibits some form of complexity such as asymmetries in the disk. Future high-resolution observations are required to confirm the disk/envelope model and to flesh out the details of the physical form of the inner regions of IRS 9A.Comment: Accepted to be published in Astronomy & Astrophysics, 13 pages, 14 figure