8 research outputs found

    PROGRESS IN THE KNOWLEDGE OF C2H2C_{2}H_{2} SPECTROSCOPIC PARAMETERS IN THE IR

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    Author Institution: Harvard-Smithsonian Center for Astrophysics, Atomic and Molecular Physics Division; Laboratoire de Physique Mol\'eculaire et Applications, CNRS, case courrier 76, Universit\'e Pierre-et-Marie-Curie; Groupe de Spectrom\'etrie Mol\'eculaire et Atmosph\'erique, Universit\'e de Reims-Champagne-Ardenne, CNRSThe acetylene molecule is important for atmospheric, planetary, and astrophysics applications. In order to improve the knowledge of C2H2C_{2}H_{2}, systematic measurements of line parameters have been performed. Two main spectral regions have been studied in this work. First, in the 13.6−μm13.6-{\mu}m region, line intensities were revisited for the ν5\nu_{5} band and determined for some hot bands, allowing us to update the HITRAN database. Second, in the 5−μm5-{\mu}m region, numerous line parameters, including positions, intensities, self-broadening coefficients, and self-shifting coefficients of lines belonging to 18 bands were measured for the first time. Intensities were also measured for some new lines in the 4.5−μm4.5-{\mu}m region, and a good agreement was observed between previous measurements. Concerning the 3−μm3-{\mu}m region, where two cold bands were already analyzed for positions and intensities, but where the intensities of numerous hot lines are missing in HITRAN, a study is in progress, and preliminary results will be presented

    The 2003 edition of the GEISA/IASI spectroscopic database

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    The content of the current (2003) version, GEISA/IASI-03, of the computer-accessible spectroscopic database, GEISA/IASI, is described. This "system" or database is comprised of three independent spectroscopic archives, which are (a) a database of individual spectral line parameters on 14 molecules, H2O, CO2, O3, N2O, CO, CH4, O2, NO, SO2, NO2, HNO3, OCS, C2H2, N2, and the related 51 isotopomers and isotopologues, representing 702,550 entries, in the spectral range 599-3001 cm-1, (b) a database of spectral absorption cross-sections (6,572,329 entries related to six molecules, CFC-11, CFC-12, CFC-14, HCFC-22, N2O5, CCl4), and a catalogue of microphysical and optical properties (mainly, the refractive indices) of atmospheric aerosols. The modifications and improvements, which have been implemented since the earlier editions of this database, in terms of content and management, have been explained in detail. GEISA/IASI has been created with the specific purpose of assessing the capability of measurement by the IASI instrument within the designated goals of ISSWG in the frame of the CNES/EUMETSAT European Polar System preparation. All the archived data can be handled through a user-friendly associated management software, which is posted on the ARA/LMD group web site at http://ara.lmd.polyechnique.fr. © 2005 Elsevier Ltd. All rights reserved.SCOPUS: ar.jinfo:eu-repo/semantics/publishe

    The GEISA spectroscopic database: Current and future archive for Earth and planetary atmosphere studies

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    The development of Gestion et Etude des Informations Spectroscopiques Atmosphériques (GEISA: Management and Study of Spectroscopic Information) was started over three decades at Laboratoire de Météorologie Dynamique (LMD) in France. GEISA is a computer accessible spectroscopic database, designed to facilitate accurate forward radiative transfer calculations using a line-by-line and layer-by-layer approach. More than 350 users have been registered for on-line use of the GEISA facilities. The current 2003 edition of GEISA (GEISA-03) is a system comprising three independent sub-databases devoted respectively to: line transition parameters, infrared and ultraviolet/visible absorption cross-sections, microphysical and optical properties of atmospheric aerosols. Currently, GEISA is involved in activities related to the assessment of the capabilities of IASI (Infrared Atmospheric Sounding Interferometer on board of the METOP European satellite) through the GEISA/IASI database derived from GEISA. The GEISA-03 content is presented, placing emphasis on molecular species of interest for Earth and planetary atmosphere studies, with details on the updated 2008 archive underway. A critical assessment on the needs, in terms of molecular parameters archive, related with recent satellite astrophysical missions is made. Detailed information on free on-line GEISA and GEISA/IASI access is given at http://ara.lmd.polytechnique.fr and http://ether.ipsl.jussieu.fr. © 2008 Elsevier Ltd. All rights reserved.SCOPUS: ar.jinfo:eu-repo/semantics/publishe
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