Evolution of microstructure and transport properties of cement pastes due to carbonation under a CO2 pressure gradient: a modeling approach

Most carbonation models only account for diffusion as the main transport mechanism rather than advection. Nevertheless, in the case of concrete used for underground waste disposal facilities, concrete may be subjected to a high hydrostatic pressure and the surrounding environment may contain a high dissolved CO2 concentration. Therefore, a combination of diffusion and advection should be taken into account. This is also the case in accelerated carbonation where a high CO2 pressure gradient is applied in which advection in the gas phase has a significant contribution to the carbonation process. This study aims at developing a model to predict the evolution of the microstructure and transport properties of cement pastes due to carbonation under accelerated conditions in which a pressure gradient of pure CO2 is applied. The proposed model is based on a macroscopic mass balance for carbon dioxide in gaseous and aqueous phases. Besides the prediction of the changes in transport properties (diffusivity, permeability), the model also enables to predict the changes in microstructure. Data from accelerated tests were used to validate the model. Preliminary verification with experimental results shows a good agreement

Decalcification of cement paste in NH4NO3 solution: microstructural alterations and its influence on the transport properties

Leaching of cement-based materials changes its properties such as a reduction in pH, an increase in porosity and transport properties and a detrimental effect on properties related to long-term durability. Therefore, a better understanding of leaching process is important including the relevant long-term effects for concretes used in waste disposal systems. However, the decalcification process is not easy to capture because it is extremely slow. In this study, an ammonium nitrate (NH4NO3) solution of 6 mol/l was used to accelerate the leaching kinetics. The experiments were performed on cement paste samples with different water/powder and limestone filler replacement ratios. The change of sample mass over time was monitored, and the amount of calcium ion leached out during the test was determined. Different post-analysis techniques like SEM, MIP and N2-adsorption were used to characterize the microstructural changes, while the degraded front was determined by phenolphthalein spraying. The effect of accelerated leaching on transport properties was studied by measuring the change in water permeability. Results show that (i) NH4NO3 solution is an aggressive but suitable agent to be used to accelerate the Ca leaching in cementitious materials while still keeping the “nature” of leaching; (ii) the square-root-time law of degradation is applicable under accelerated conditions; (iii) the porosity of the leached samples increases significantly and the critical pore size is shifted to larger radius; and (iv) the BET specific surface area of the leached sample is also significantly increased. These changes result in a significant increase in water permeability

Biomolecular evaluation of three contrasting rice cultivars (Oryza sativa L.) in salt stress response at seedling stage.

Salt contamination of soils due to climate change faces a severe environmental issue that affects crop production today. However, the response mechanism in plants to salt stress is not fully understood. The present study investigated molecular and biochemical changes under salt stress in rice seedlings of three rice cultivars, i.e., AGPPS114 (salt-tolerant), OM6967 (moderately tolerance), VD20 (salt-sensitive). Increasing salt concentration leads to a reduction in shoot/root length but different levels among the cultivars. In contrast, reactive oxygen species (ROS) accumulation and lipid peroxidation increased progressively with increasing salt concentration and time course treatment. However, at 250 ?M of NaCl, these parameters were more adversely affected in VD20 than AGPPS114 and OM6967. Using ICP showed that Na+ accumulation in rice root increased gradually with increasing NaCl concentrations in all cultivars under salt treatment but was low in salt-sensitive cultivar VD20 compared to other cultivars. Antioxidant enzyme activity analysis indicated catalase (CAT) and superoxide dismutase (SOD) were induced during salt treatment in all cultivars. The results also showed greater proline and glycine betaine accumulation in the AGPPS114 than OM6976 and VD20. qPCR indicated a significant difference in transcript levels of the Na+-transporter gene OsSOS1, OsNHX1 and OsHKT1s in AGPPS114 and OM6967 cultivars compared to VD20 cultivar. In summary, the active regulation of genes related to Na+ transport at the transcription level and with high glycine betaine and proline accumulation levels may be involved in salt tolerance mechanisms and thus might be useful for selecting tolerant plants

Effects of W/P ratio and limestone filler on permeability of cement pastes

Because of environmental and economic benefits, a fraction of cement is increasingly replaced by limestone fillers raising a question on to what extent limestone fillers affect the durability of cementitious materials. This work aims at understanding the effects of water/powder (w/p) ratio and limestone filler replacement on water permeability of cement pastes. A newly proposed technique using a controlled constant flow concept was applied to measure permeability of hardened cement paste samples following a factorial experimental design. It was observed that both limestone filler and w/p ratio significantly influence the water permeability. At a given w/p ratio, adding limestone filler made the microstructure coarser, especially for high w/p ratio. Nevertheless, if the comparison is based on a given water/cement (w/c) ratio instead of w/p ratio, the limestone filler replacement refined the microstructure in terms of capillary porosity and pore size distribution, resulting in permeability decreases of cement pastes. Furthermore, a modified Carmen-Kozeny relation was established which enables prediction of the permeability from capillary porosity and the critical pore diameter

A novel ontology framework supporting model-based tourism recommender

In this paper, we present a tourism recommender framework based on the cooperation of ontological knowledge base and supervised learning models. Specifically, a new tourism ontology, which not only captures domain knowledge but also specifies knowledge entities in numerical vector space, is presented. The recommendation making process enables machine learning models to work directly with the ontological knowledge base from training step to deployment step. This knowledge base can work well with classification models (e.g., k-nearest neighbours, support vector machines, or naıve bayes). A prototype of the framework is developed and experimental results confirm the feasibility of the proposed framework. © 2021, Institute of Advanced Engineering and Science. All rights reserved

Influence of Micro-Pore Connectivity and Micro-Fractures on Calcium Leaching of Cement Pastes — A Coupled Simulation Approach

A coupled numerical approach is used to evaluate the influence of pore connectivity and microcracks on leaching kinetics in fully saturated cement paste. The unique advantage of the numerical model is the ability to construct and evaluate a material with controlled properties, which is very difficult under experimental conditions. Our analysis is based on two virtual microstructures, which are different in terms of pore connectivity but the same in terms of porosity and the amount of solid phases. Numerical fracturing was performed on these microstructures. The non-fractured and fractured microstructures were both subjected to chemical leaching. Results show that despite very different material physical properties, for example, pore connectivity and effective diffusivity, the leaching kinetics remain the same as long as the amount of soluble phases, i.e., buffering capacity, is the same. The leaching kinetics also remains the same in the presence of microcracks

Modeling of parallel power MOSFETs in steady-state

In high-power applications, multiple power MOSFETs are connected in parallel and treated as a single switch in order to handle much larger total currents. In this paper, a parallel power MOSFETs model from the turnoff state until they reach their steady state is introduced. The model represents the relationship between each power MOSFET's gate voltage and the current distribution among them. The study's key purpose is to use the model for dealing with the asymmetry in sharing current and power loss between these semiconductor devices during the steady state region.Comment: 10 pages, 7 figures, The 2023 INTERNATIONAL SYMPOSIUM ON ADVANCED ENGINEERING (ISAE2023

SMART: A tool for analyzing and reconciling schema matching networks

Schema matching supports data integration by establishing correspondences between the attributes of independently designed database schemas. In recent years, various tools for automatic pair-wise matching of schemas have been developed. Since the matching process is inherently uncertain, the correspondences generated by such tools are often validated by a human expert. In this work, we go beyond the state-of-the-art of matching pairs of schemas and consider scenarios in which attribute correspondences are identified in a network of schemas. Here, correspondences between different schemas are interrelated, so that incomplete and erroneous matching results propagate in the network and the validation of a correspondence by an expert has ripple effects. To analyse and reconcile such matchings in schema networks, we present the Schema Matching Analyzer and Reconciliation Tool (SMART). It allows for the definition of network-level integrity constraints for the matching and, based thereon, detects and visualizes inconsistencies of the matching. The tool also supports the reconciliation of a matching by guiding an expert in the validation process and by offering semi-automatic conflict-resolution techniques

XÂY DỰNG BỘ CHỈ TIÊU PHÁT TRIỂN BỀN VỮNG VỀ CÁC LĨNH VỰC KINH TẾ, XÃ HỘI VÀ MÔI TRƯỜNG CÁC TỈNH TÂY NGUYÊN

A  sustainable  development  indication  set  plays  a  very  important  role  for  assessing,  monitoring  the  sustainable development  status  in  a  region,  supporting  policy,  decision makers to  propose  confident  decisions  to control  economic, social, and environmental themes toward sustainable developmet. The content, procedure, methodology, and methods to establish the sustainable development indicator set in Tay Nguyen (SDI) were figured out; proposing a list of sustainable development indicators for Tay Nguyen consisting of 77 indicators at regional scale, 70 indicators at provincial scale, 49 indicators at district scale. The  SDI could comprehensively show overall development process toward sustainable by 13 themes (economic field - 3 themes; social field - 5 themes; and environmental field - 5 themes). The paper outlined the SDI’s definition and indicated SDI’s significance through linkages between the sustainable development indicators and sustainable development themes.ReferencesLê Thạc Cán, Trần Thùy Chi, Nguyễn Thế Chinh, Nguyễn Viết Thịnh, Ngô Đăng Trí, Nguyễn Thanh Tuấn, Trần Văn Ý và James Hennessy, 2013. Kết quả bước đầu của Đề tài “Nghiên cứu xây dựng Bộ chỉ tiêu phát triển bền vững các lĩnh vực kinh tế xã hội và môi trường các tỉnh Tây Nguyên”, Tạp chí Khoa học Công nghệ Việt Nam, ISSN 1859-4794. No14, 2013, p 61-64. Dhakal S. 2002. Report on Indicator related research for Kitakyushu Initiative. Ministry of Environment, Japan. Harold A. Linstone, Murray Turoff, 2002. The Delphi Method: Techniques and Applications. Hui-Chun Chu, Gwo-Jen Hwang, 2008. A Delphi-based approach to developing expert systems with the cooperation of multiple experts, Expert Systems with Applications, 34(4), 2826- 840. (SCI). Jean Hugé, Hai Le Trinh, Pham Hoang Hai, Jan Kuilman and Luc Hens, 2009. Sustainability indicators for clean development mechanism projects in Vietnam, Springer Netherlands. Environment, Development and Sustainability, August 2010, Volume 12, Issue 4, pp 561-571. Trần Văn Ý, Lê Thạc Cán, Trần Thùy Chi, Nguyễn Thế Chinh, Ngô Đăng Trí, Nguyễn Viết Thịnh, Nguyễn Thanh Tuấn, 2013. Bộ chỉ tiêu phát triển bền vững về các lĩnh vực kinh tế, xã hội và môi trường các tỉnh Tây Nguyên. Kỷ yếu hội thảo quốc tế lần thứ tư, Việt Nam học, Nhà xuất bản Khoa học xã hội, Hà Nội, ngày 26-28/11/2012, tập IV, 386-400. Bộ Kế hoạch và Đầu tư, 2010. Hệ thống chỉ tiêu thống kê quốc gia (Ban hành theo Quyết định số 43/2010/QĐ/TTg ngày 02 tháng 6 năm 2010 của Thủ tướng Chính phủ). UNDP và MPI, 2005. Identification of a sustainable development indicators set and mechanism for building a sustainable development database in Vietnam (Project VIE/01/021 “Implementation of Vietnam Agenda 21”) United Nations, 2007. Indicators of Sustainable Development: Guidelines and Methodologies. Thủ tướng Chính phủ, 2012. Các chỉ tiêu giám sát và đánh giá phát triển bền vững Việt Nam giai đọan 2011-2020 (Ban hành kèm theo Quyết định số 432/QĐ-TTg ngày 12 tháng 4 năm 2012 của Thủ tướng Chính phủ). Thủ tướng Chính phủ, 2013. Bộ chỉ tiêu giám sát, đánh giá phát triển bền vững địa phương giai đoạn 2013-2020 (Ban hành kèm theo Quyết định số 2157/QĐ-TTg ngày 11 tháng 11 năm 2013 của Thủ tướng Chính phủ). A  sustainable  development  indication  set  plays  a  very  important  role  for  assessing,  monitoring  the  sustainable development  status  in  a  region,  supporting  policy,  decision makers to  propose  confident  decisions  to control  economic, social, and environmental themes toward sustainable developmet. The content, procedure, methodology, and methods to establish the sustainable development indicator set in Tay Nguyen (SDI) were figured out; proposing a list of sustainable development indicators for Tay Nguyen consisting of 77 indicators at regional scale, 70 indicators at provincial scale, 49 indicators at district scale. The  SDI could comprehensively show overall development process toward sustainable by 13 themes (economic field - 3 themes; social field - 5 themes; and environmental field - 5 themes). The paper outlined the SDI’s definition and indicated SDI’s significance through linkages between the sustainable development indicators and sustainable development themes