WATER COMMUNITIES IN THE REPUBLIC OF MACEDONIA: AN EMPIRICAL ANALYSIS OF MEMBERSHIP SATISFACTION AND PAYMENT BEHAVIOUR

The performance of Water Communities (WCs), a form of self-managing organisation for irrigation, in the Bregalnica region of the Republic of Macedonia is investigated. Analysis, drawing on primary survey data, focuses on the decision of farmers to join a WC (Heckman selection probit model), determinants of farmers’ satisfaction with their membership of WCs (ordered probit model) and factors associated with changes in farmers’ water payment behaviour (non-parametric CLAD model). Key determinants identified include transparency and trust with respect to the structure and operation of the WC, cost recovery rates, farm size and irrigation costs. Membership satisfaction is an important determinant of payment behaviour. Lessons for sustainable self-management are drawn.Irrigation, Self-management, Water User Associations, Eastern Europe, Macedonia,

Binding effects in multivalent Gibbs-Donnan equilibrium

The classical Gibbs-Donnan equilibrium describes excess osmotic pressure associated with confined colloidal charges embedded in an electrolyte solution. In this work, we extend this approach to describe the influence of multivalent ion binding on the equilibrium force acting on a charged rod translocating between two compartments, thereby mimicking ionic effects on force balance during in vitro DNA ejection from bacteriophage. The subtle interplay between Gibbs-Donnan equilibrium and adsorption equilibrium leads to a non-monotonic variation of the ejection force as multivalent salt concentration is increased, in qualitative agreement with experimental observations

Calculated collision induced absorption spectrum for He-Ar

Calculation of collision induced absorption spectra for helium-argo

The StoreGate: a Data Model for the Atlas Software Architecture

The Atlas collaboration at CERN has adopted the Gaudi software architecture which belongs to the blackboard family: data objects produced by knowledge sources (e.g. reconstruction modules) are posted to a common in-memory data base from where other modules can access them and produce new data objects. The StoreGate has been designed, based on the Atlas requirements and the experience of other HENP systems such as Babar, CDF, CLEO, D0 and LHCB, to identify in a simple and efficient fashion (collections of) data objects based on their type and/or the modules which posted them to the Transient Data Store (the blackboard). The developer also has the freedom to use her preferred key class to uniquely identify a data object according to any other criterion. Besides this core functionality, the StoreGate provides the developers with a powerful interface to handle in a coherent fashion persistable references, object lifetimes, memory management and access control policy for the data objects in the Store. It also provides a Handle/Proxy mechanism to define and hide the cache fault mechanism: upon request, a missing Data Object can be transparently created and added to the Transient Store presumably retrieving it from a persistent data-base, or even reconstructing it on demand.Comment: Talk from the 2003 Computing in High Energy and Nuclear Physics (CHEP03), La Jolla, Ca, USA, March 2003, 4 pages, LaTeX, MOJT00

Separation of suspended particles in microfluidic systems by directional-locking in periodic fields

We investigate the transport and separation of overdamped particles under the action of a uniform external force in a two-dimensional periodic energy landscape. Exact results are obtained for the deterministic transport in a square lattice of parabolic, repulsive centers that correspond to a piecewise-continuous linear-force model. The trajectories are periodic and commensurate with the obstacle lattice and exhibit phase-locking behavior in that the particle moves at the same average migration angle for a range of orientation of the external force. The migration angle as a function of the orientation of the external force has a Devil's staircase structure. The first transition in the migration angle was analyzed in terms of a Poincare map, showing that it corresponds to a tangent bifurcation. Numerical results show that the limiting behavior for impenetrable obstacles is equivalent to the high Peclet number limit in the case of transport of particles in a periodic pattern of solid obstacles. Finally, we show how separation occurs in these systems depending on the properties of the particles

On the Verge of One Petabyte - the Story Behind the BaBar Database System

The BaBar database has pioneered the use of a commercial ODBMS within the HEP community. The unique object-oriented architecture of Objectivity/DB has made it possible to manage over 700 terabytes of production data generated since May'99, making the BaBar database the world's largest known database. The ongoing development includes new features, addressing the ever-increasing luminosity of the detector as well as other changing physics requirements. Significant efforts are focused on reducing space requirements and operational costs. The paper discusses our experience with developing a large scale database system, emphasizing universal aspects which may be applied to any large scale system, independently of underlying technology used.Comment: Talk from the 2003 Computing in High Energy and Nuclear Physics (CHEP03), La Jolla, Ca, USA, March 2003, 6 pages. PSN MOKT01

Water Communities in the Republic of Macedonia: an empirical analysis of membership satisfaction and payment behaviour

The performance of Water Communities (WCs), a form of self-managing organisation for irrigation, in the Bregalnica region of the Republic of Macedonia is investigated. Analysis, drawing on primary survey data, focuses on the decision of farmers to join a WC (Heckman selection probit model), determinants of farmers’ satisfaction with their membership of WCs (ordered probit model) and factors associated with changes in farmers’ water payment behaviour (non-parametric CLAD model). Key determinants identified include transparency and trust with respect to the structure and operation of the WC, cost recovery rates, farm size and irrigation costs. Membership satisfaction is an important determinant of payment behaviour. Lessons for sustainable self-management are drawn.Irrigation, Self-management, Water User Associations, Resource /Energy Economics and Policy,

First-principles kinetic Monte Carlo simulations for heterogeneous catalysis, applied to the CO oxidation at RuO2(110)

We describe a first-principles statistical mechanics approach enabling us to simulate the steady-state situation of heterogeneous catalysis. In a first step density-functional theory together with transition-state theory is employed to obtain the energetics of all relevant elementary processes. Subsequently the statistical mechanics problem is solved by the kinetic Monte Carlo method, which fully accounts for the correlations, fluctuations, and spatial distributions of the chemicals at the surface of the catalyst under steady-state conditions. Applying this approach to the catalytic oxidation of CO at RuO2(110), we determine the surface atomic structure and composition in reactive environments ranging from ultra-high vacuum (UHV) to technologically relevant conditions, i.e. up to pressures of several atmospheres and elevated temperatures. We also compute the CO2 formation rates (turnover frequencies). The results are in quantitative agreement with all existing experimental data. We find that the high catalytic activity of this system is intimately connected with a disordered, dynamic surface ``phase'' with significant compositional fluctuations. In this active state the catalytic function results from a self-regulating interplay of several elementary processes.Comment: 18 pages including 9 figures; related publications can be found at http://www.fhi-berlin.mpg.de/th/th.htm

Kinetic Characterisation of a Single Chain Antibody against the Hormone Abscisic Acid: Comparison with Its Parental Monoclonal

A single-chain Fv fragment antibody (scFv) specific for the plant hormone abscisic acid (ABA) has been expressed in the bacterium Escherichia coli as a fusion protein. The kinetics of ABA binding have been measured using surface plasmon resonance spectrometry (BIAcore 2000) using surface and solution assays. Care was taken to calculate the concentration of active protein in each sample using initial rate measurements under conditions of partial mass transport limitation. The fusion product, parental monoclonal antibody and the free scFv all have low nanomolar affinity constants, but there is a lower dissociation rate constant for the parental monoclonal resulting in a three-fold greater affinity. Analogue specificity was tested and structure-activity binding preferences measured. The biologically-active (+)-ABA enantiomer is recognised with an affinity three orders of magnitude higher than the inactive (-)-ABA. Metabolites of ABA including phaseic acid, dihydrophaseic acid and deoxy-ABA have affinities over 100-fold lower than that for (+)-ABA. These properties of the scFv make it suitable as a sensor domain in bioreporters specific for the naturally occurring form of ABA