Qualitative analysis of plastic debris on beaches of Brunei Darussalam

Plastic debris is one of the major environmental concerns for the coastal area of Brunei Darussalam. It reduces the aesthetic appeals of the beaches in the country. The current study investigates marine debris on six different beaches of Brunei Darussalam along the South China Sea. Plastic was found the most abundant among whole debris by number (90.02%) and by weight (39.12%). It was classified by size (micro (100 mm)), colour (transparent, coloured, white and black). Fourier Transform Infrared Spectroscopy (FTIR) was used to investigate the types of plastics and additives present in it. Statistical analysis using Minitab 17 and Kruskal-Wallis test was performed for comparison of data at different study sites. All major types of plastics were found in different forms with varying quantities from which toxic chemicals may leach out during degradation. The highest abundance by the number of plastic debris was found on Muara beach with a mean value 74.428 n/m2 ± 34.33 n/m2, while the lowest abundance was found on Lumut beach 53 n/m2 ± 20.9 n/m2. The study shows beaches used for recreational facilities are likely to have more debris as compared to other beaches

Short hydrogen bonds enhance nonaromatic protein-related fluorescence.

Fluorescence in biological systems is usually associated with the presence of aromatic groups. Here, by employing a combined experimental and computational approach, we show that specific hydrogen bond networks can significantly affect fluorescence. In particular, we reveal that the single amino acid L-glutamine, by undergoing a chemical transformation leading to the formation of a short hydrogen bond, displays optical properties that are significantly enhanced compared with L-glutamine itself. Ab initio molecular dynamics simulations highlight that these short hydrogen bonds prevent the appearance of a conical intersection between the excited and the ground states and thereby significantly decrease nonradiative transition probabilities. Our findings open the door to the design of new photoactive materials with biophotonic applications

Short hydrogen bonds enhance nonaromatic protein-related fluorescence.

Fluorescence in biological systems is usually associated with the presence of aromatic groups. Here, by employing a combined experimental and computational approach, we show that specific hydrogen bond networks can significantly affect fluorescence. In particular, we reveal that the single amino acid L-glutamine, by undergoing a chemical transformation leading to the formation of a short hydrogen bond, displays optical properties that are significantly enhanced compared with L-glutamine itself. Ab initio molecular dynamics simulations highlight that these short hydrogen bonds prevent the appearance of a conical intersection between the excited and the ground states and thereby significantly decrease nonradiative transition probabilities. Our findings open the door to the design of new photoactive materials with biophotonic applications

Biodiversity and its use at taunsa barrage wildlife sanctuary, Pakistan

This study determined the livelihood conditions of the peoples of three villages (Bait Qaimwala, Basti Allahwali and Jannu) and their dependency on biodiversity of Taunsa Barrage Wildlife Sanctuary, Pakistan from 2009 to 2011. For socio-economic status, Participatory Human Resource Interaction Appraisal method was used and for biodiversity assessment, direct census method and point count were used. Floral biodiversity contained 79 species of plants including; trees (n=48 species); herbs (n=8 species); shrubs (n=9 species); grasses (n=7 species); reeds (n=5 species) and weeds (n=2 species). Fauna included fish (n=21 species), amphibians (n=3 species), reptiles (n=9 species), mammals (n=14 species) and birds (n=171) species. The high illiteracy rate (64 percent) in the surroundings of TBWS was estimated. Overall the local community was dependent on wetland products for use of fuel wood (77 percent), livestock grazing (100 percent), fishing (90 percent), hunting, freshwater turtles trading (10 percent) and others (9 percent). Villagers who live in mud-built houses constitute 42 percent, concrete houses 30 percent and thatched houses 28 percent. Typical means of transportation in the area was still animal driven cart (25 percent). In Bait Qaimwala 75 percent households were ultra poor. In Basti Allahwali 15 percent households were poor, 35 percent extremely poor and 5 percent ultra poor. In Jannu village, 55 percent households were poor and 45 percent were non poor. There is need to reorganize the social sector and help local communities to fully benefit from the potential of ecotourism. In conclusion, community participation for sustainable use of natural resources in wildlife sanctuary will give a new strength to biodiversity conservation in study area

Preparation and characterisation of sustainable wood plastic composites extracted from municipal solid waste

open access articleMunicipal solid waste (MSW) contains plastic waste that can be used as a sustainable green substitute to reduce oil footprints, CO2 emissions, and environmental pollution. This study aims to recycle plastic waste by manufacturing wood-plastic composites and to improve its mechanical properties by using additives, coupling agents, and lubricants. These composites are prepared by mixing 40–70% of wood flour with 20–25% of a polymer matrix. Wood was degraded at 220 C, and then the composites were processed at 50 C. The manufacturing process carried out in the study involved wood waste meshing, drying, shredding, drying, trimming, filling, blending, compounding, and extrusion moulding. The compounding of composites was accomplished in twin-screw extruders. Once the mixture was uniformly mixed, its final shape was given by a two-step extrusion moulding. Previously, researchers aimed at enhancing the mechanical properties of the composites, but our research focus was to improve their durability for different industrial applications. The results suggest that the impact strength is 17 MPa with 50% of wood powder ratio while the maximum value for the tensile strength is 32.5 MPa. About 50% of an increase in wood powder resulted in 8.1% bending strength increase from 26.1 to 32.8 MPa. Reducing the plastic matrix and the woodparticles water swelling ratio resulted in better mechanical properties. The wood species also affected the mechanical properties with their excellent dimensional stability and less variability. A high proportion of wood fibre tends to increase its steady-state torque and viscosity. The mechanical properties against different wood-flour proportions indicate that composite materials exhibit superior water swelling behaviour and extrusion quality

Effects of Protein Source, Whole Wheat and Butyric Acid on Live Performance, Gut Health and Amino Acid Digestibility in Broiler Chickens

A total of 896 1-day-old straight-run (Ross-308) broilers were used to investigate the interactive effects of protein source (PS), diet structure (DS) and butyric acid (BA) on live performance and carcass characteristics, gut development and its morphology and apparent ileal digestibility (AID) of protein and amino acids (AA). Eight experimental diets comprising 8 replicates with 14 birds each were tested in a 2 × 2 × 2 factorial arrangement with complete randomized design by two levels of BA (0 and 0.1%), two forms of DS (whole vs. ground wheat) and two PS, i.e., soybean meal and canola meal (SBM vs. CM). Throughout the entire experimental period (0 to 35 d), broilers fed SBM-based diets exhibited better (p p p p p = 0.001), BWG (p = 0.004) and FCR (p = 0.035) during the overall experimental period. Broilers fed WW had 6, 5, 8, 11 and 10% lower empty relative weights of crop, proventriculus, jejunum, ileum and colon and 25 and 15% heavier gizzard and pancreas, respectively, with longer villus height (p p = 0.031) and longer villus height-to-crypt depth ratio (p p p < 0.05) growth performance and digestibility of threonine, valine, leucine, isoleucine, phenylalanine, serine and aspartate. The broilers consuming SBM had 28% lower abdominal fat than those fed CM-based diets. In conclusion, harmful consequences of a less digestible PS can partially be compensated by the inclusion of WW, and supplementation of BA further reduces these detrimental effects