PLEISTOCENE PALAEOCLIMATIC EVOLUTION FROM AGIOS GEORGIOS CAVE SPELEOTHEM (KILKIS, N. GREECE)

Palaeoclimatic reconstruction in N. Greece has been investigated in this study, using stable isotope analyses and U/Th dating of a speleothem (stalactite) from the cave of Agios Georgios (Kilkis). Sampling sequence was followed in detail in order to obtain high resolution analysis of the proxy. Speleothem δ18O entirely depends on two factors: changes in the δ18O of the percolation waters (a proxy for local rainfall δ18O) and the temperature of water-calcite fractionation inside the cave (a proxy for outside air temperatures). During periods of relatively stable temperatures, δ13C shifts are caused principally by variations in soil CO2 input and physico-chemical processes inside the cave. More important processes affect the δ13C signal of speleothem inside the cave are length of flow path and rates of CO2 degassing.The lower δ13C calcite values indicate greater respiratory activity of soils under wetter conditions. The stalagmite layers were dated through U/Th geochronological method, which places the carbonate precipitation in Middle Pleistocene (630-300ka BP). The isotopic composition of the layers was used in combination with the dating results to reconstruct the evolution of the area of Kilkis. Correlation with global climatic records shows that major climatic transitions that influenced northern hemisphere seem to have also affected the region of N. Greece

PLEISTOCENE PALAEOCLIMATIC EVOLUTION FROM AGIOS GEORGIOS CAVE SPELEOTHEM (KILKIS, N. GREECE)

Palaeoclimatic reconstruction in N. Greece has been investigated in this study, using stable isotope analyses and U/Th dating of a speleothem (stalactite) from the cave of Agios Georgios (Kilkis). Sampling sequence was followed in detail in order to obtain high resolution analysis of the proxy. Speleothem δ18O entirely depends on two factors: changes in the δ18O of the percolation waters (a proxy for local rainfall δ18O) and the temperature of water-calcite fractionation inside the cave (a proxy for outside air temperatures). During periods of relatively stable temperatures, δ13C shifts are caused principally by variations in soil CO2 input and physico-chemical processes inside the cave. More important processes affect the δ13C signal of speleothem inside the cave are length of flow path and rates of CO2 degassing.The lower δ13C calcite values indicate greater respiratory activity of soils under wetter conditions. The stalagmite layers were dated through U/Th geochronological method, which places the carbonate precipitation in Middle Pleistocene (630-300ka BP). The isotopic composition of the layers was used in combination with the dating results to reconstruct the evolution of the area of Kilkis. Correlation with global climatic records shows that major climatic transitions that influenced northern hemisphere seem to have also affected the region of N. Greece

PALAEOCLIMATIC EVOLUTION IN LOUTRA ARIDEAS CAVE (ALMOPIA SPELEOPARK, MACEDONIA, N. GREECE) BY STABLE ISOTOPIC ANALYSIS OF FOSSIL BEAR BONES AND TEETH

Carbon and oxygen stable isotope values (δ13C, δ18O) were obtained from structural carbonate in the bioapatite of bear bones (Ursus ingressus) from Loutra Arideas cave, Almopia Speleopark, Macedonia, N. Greece. Samples of Late Pleistocene bear bones were studied for palaeoclimatic reconstruction of the area. The age range of the fossil layers is from 32ka BP to a maximum of 38ka BP. Generally, the palaeoclimatic proxy is correlated with literature data for climatic variations in the area during Late Pleistocene, whereas dietary behavior was investigated taking into account possible diagenetic processes that may have affected the carbonate matrix of the bones

GEOCHEMICAL INVESTIGATION OF AQUIFER POLLUTION FROM WASTE MANAGEMENT. THE CASE OF KOMOTINI LANDFILL (GREECE)

According to European legislation, environmental control and monitoring of landfills has become of crucial importance. This study includes a thorough geochemical approach aiming to evaluate the environmental impact of the landfill of Komotini, N. Greece. Samples of waters were taken from inside the working landfill as well as from the area of the neighbouring old landfill. The waters were analyzed chemically (major elements and heavy metals) and isotopically (D and 18O). Also, biogas flow was measured and the ratio CH4/CO2. Based on the geomorphological, hydrogeological and land use data of the area, we proceeded to analyses of waters both from the area of the landfill and from the wider region (drainage basin). The obtained results were used to construct digital maps (GIS) in order to determine the special dispersion of the polluted aquifers. The biogas flow in the old and new garbage burial sites was measured by accumulation chamber device for methane and carbon dioxide ratio determination. The obtained results show an important agent of pollution in the water samples downstream from the landfill and in a distance more than 2km, along the dispersion of the leachate. The land use of the area was taken into account to evaluate the importance and the criticality of the situation

Evaluating model outputs using integrated global speleothem records of climate change since the last glacial

Although quantitative isotope data from speleothems has been used to evaluate isotope-enabled model simulations, currently no consensus exists regarding the most appropriate methodology through which to achieve this. A number of modelling groups will be running isotope-enabled palaeoclimate simulations in the framework of the Coupled Model Intercomparison Project Phase 6, so it is timely to evaluate different approaches to using the speleothem data for data–model comparisons. Here, we illustrate this using 456 globally distributed speleothem δ18O records from an updated version of the Speleothem Isotopes Synthesis and Analysis (SISAL) database and palaeoclimate simulations generated using the ECHAM5-wiso isotope-enabled atmospheric circulation model. We show that the SISAL records reproduce the first-order spatial patterns of isotopic variability in the modern day, strongly supporting the application of this dataset for evaluating model-derived isotope variability into the past. However, the discontinuous nature of many speleothem records complicates the process of procuring large numbers of records if data–model comparisons are made using the traditional approach of comparing anomalies between a control period and a given palaeoclimate experiment. To circumvent this issue, we illustrate techniques through which the absolute isotope values during any time period could be used for model evaluation. Specifically, we show that speleothem isotope records allow an assessment of a model's ability to simulate spatial isotopic trends. Our analyses provide a protocol for using speleothem isotope data for model evaluation, including screening the observations to take into account the impact of speleothem mineralogy on δ18O values, the optimum period for the modern observational baseline and the selection of an appropriate time window for creating means of the isotope data for palaeo-time-slices

Isotopic analysis for degradation diagnosis of calcite matrix in mortar

Mortar that was used in building as well as in conservation and restoration works of wall paintings have been analysed isotopically (δ13C and δ18O) in order to evaluate the setting environments and secondary processes, to distinguish the structural components used and to determine the exact causes that incurred the degradation phenomena. The material undergoes weathering and decay on a large proportion of its surface and in depth, due to the infiltration of water through the structural blocks. Mineralogical analysis indicated signs of sulphation and dissolution/ recrystallisation processes taking place on the material, whereas stable isotopes provided information relative to the origin of the CO2 and water during calcite formation and degradation processes. Isotopic change of the initial δ13C and δ18O in carbonate matrix was caused by alteration of the primary source of CO2 and H2O in mortar over time, particularly by recrystallisation of calcite with porewater, evaporated or re-condensed water, and CO2 from various sources of atmospheric and biogenic origin. Human influence (surface treatment) and biological growth (e.g. fungus) are major exogenic processes which may alter δ18O and δ13C in lime mortar. © 2009 Springer-Verlag

Clastic sedimentary features of beachrocks and their palaeo-environmental significance: comparison of past and modern coastal regimes

International audienceClastic sedimentary features of beachrocks and unconsolidated deposits of parent beaches were investigated along the northern Aegean coastline (Greece) to assess their suitability in palaeo-environmental reconstruction. Twelve paired datasets were collected in the Thermaikos, Toroneos, Siggitikos and Ierissos gulfs of the Chalkidiki Peninsula, the adjoining Kavala Gulf and Thassos Island, comprising beachrock cores and companion beach subsurface sediments. Particle size analyses based on univariate and bivariate statistics suggest that, during the time period of beachrock formation, depositional conditions differed distinctly from those of the modern parent beaches. The results imply difference of maturity level of beach evolution from the time of cementation (coarser materials-early stage of beach formation) to modern situation (finer materials-reworked and 'mature' beach sediments). Furthermore, the findings indicate increasing coastal protection due to beachrock exposure in the modern swash zone. In conclusion, it is suggested that textural analysis of beachrocks in comparison with unconsolidated sediments of the parent beach might provide information regarding differences of coastal depositional regimes and future research could focus on specific-layer analysis and comparison

PLEISTOCENE PALAEOCLIMATIC EVOLUTION FROM AGIOS GEORGIOS CAVE SPELEOTHEM (KILKIS, N. GREECE)

Palaeoclimatic reconstruction in N. Greece has been investigated in this study, using stable isotope analyses and U/Th dating of a speleothem (stalactite) from the cave of Agios Georgios (Kilkis). Sampling sequence was followed in detail in order to obtain high resolution analysis of the proxy. Speleothem δ18O entirely depends on two factors: changes in the δ18O of the percolation waters (a proxy for local rainfall δ18O) and the temperature of water-calcite fractionation inside the cave (a proxy for outside air temperatures). During periods of relatively stable temperatures, δ13C shifts are caused principally by variations in soil CO2 input and physico-chemical processes inside the cave. More important processes affect the δ13C signal of speleothem inside the cave are length of flow path and rates of CO2 degassing.The lower δ13C calcite values indicate greater respiratory activity of soils under wetter conditions. The stalagmite layers were dated through U/Th geochronological method, which places the carbonate precipitation in Middle Pleistocene (630-300ka BP). The isotopic composition of the layers was used in combination with the dating results to reconstruct the evolution of the area of Kilkis. Correlation with global climatic records shows that major climatic transitions that influenced northern hemisphere seem to have also affected the region of N. Greece