Unusual, basin-scale, fluid–rock interaction in the Palaeoproterozoic Onega basin from Fennoscandia : Preservation in calcite δ18O of an ancient high geothermal gradient

Acknowledgements We acknowledge financial support from ICDP for the drilling programme. AEF, ATB and ARP thank NERC for financial support through NE/G00398X/1. VAM thanks the Norwegian Research Council for financial support through 191530/V30. We are grateful for sample preparation and analyses to all the personnel at NGU lab. At SUERC we enjoyed exceptional analytical support from Julie Dougans. Anonymous reviewers and the editor provided comments that improved the final manuscript.Peer reviewedPostprin

The Stac Fada “impact ejecta” layer: not what it seems

The Stac Fada Member (SFM) forms part of the Stoer Group of the Torridonian of NW Scotland. The SFM is unique in the Torridonian, being characterized by the presence of greenish altered glass clasts. Its origin has been debated for decades with several hypotheses being proposed but all invoking some connection with volcanic activity in the region. More recently, Amor et al. suggested that the SFM represents “a chord section through the continuous ejecta blanket surrounding an impact crater”. Here, we confirm the presence of shocked material within the SFM and then discuss its origin

Petrography and geochemistry of carbonate rocks of the Paleoproterozoic Zaonega Formation, Russia : Documentation of C-13-depleted non-primary calcite

The Norwegian Research Council grant 191530/V30 to V.A. Melezhik fully funded the work of AEC, VAM and AL. ATB was supported by NERC grant NE/G00398X/1 to AEF and ARP. We are grateful for sample preparation and analyses to all the personnel at NGU lab. We appreciate the work on carbon and oxygen isotope analyses by Julie Dougans and Chris Taylor. Bojan Otoničar organized and helped with the CL work at the Karst Research Institute at Postojna. Arrangement of TOC, IC, and TC analyses at University of Münster is acknowledged to Harald Strauss.Peer reviewedPostprin

Sedimentology a Grenvillian Neoproterozoic foreland basin succession in northern Scotland: a new combined interpretation

The early Neoproterozoic Moine and Torridonian rocks, which occupy much of the Northern Highlands in Scotland, have traditionally been interpreted as separate entities, deposited in distinct early Neoproterozoic rift basins. The rocks are now divided across the later Caledonian Moine thrust structure: the Torridonian rocks (>6 km thick) occur in the Caledonian foreland, and the Moine rocks (>3km thick) in the hanging wall of the Moine thrust. New work, based on structural geology, sedimentology and detrital mineral dating presents evidence for these successions to be now correlated, and to have formed in a single foreland basin in front of the Grenville Orogen. As such the deposits provide arguably the largest preserved and most accessible record of the Grenvillian foreland basin. This paper presents the sedimentological data collected over the last 10 years across the Neoproterozoic succession in northern Scotland, to present a new combined stratigraphic interpretation of these rocks. Taken collectively, the early Neoproterozoic sequence is ca. 9km thick and displays alternating fluvial, and tidally-influenced shoreface lithofacies, within several cycles of progradation and retrogradation. Five main phases of sedimentological evolution are interpreted: (1) A progradational sucession from tidally-influenced shoreface facies to fluvial facies at the base of the succession (Sleat Group). (2) An abrupt but (near|)conformable switch to large-scale progradation with rapid and sustained high-energy braided river deposition (Applecross Fm and lower Morar group). (3) These high-energy fluvial lithofacies gradually are replaced upwards by lower-energy braidplain fluvial facies, or tidally-influenced braidplan and shoreface facies further east within a gradual large-scale (ca. 3km thick) retrogradational succession (Aultbea Fm and middle Morar Group). (4) This retrogradational phase is indicated to have culminated in a relatively rapid transgression and marine deposition (upper Morar Group). (5) A further progradation and retrogradation succession sequence is preserved in the uppermost Morar Group. The lithofacies suggest overall lower-energy depositional conditions in this phase - from with shallow-marine to tidally-influenced distal braidplain depositional settings. The final retrograding succession is followed by a second transgression to shallow marine conditions resulting in deposition of pelite. This represents the last phase of deposition preserved in upper most parts of the early Neoproterozoic rocks in Northern Scotland. These five main phases of sedimentological evolution provide insight to the development of the depositional environments within the Grenville foreland basin, resulting from changes in the basin form, accommodation space and sediment flux

Oxygenated conditions in the aftermath of the Lomagundi-Jatuli Event : the carbon isotope and rare earth element signatures of the Paleoproterozoic Zaonega Formation, Russia

This study was supported by Estonian Research Council project PRG447, and the Estonian Centre of Analytical Chemistry. K.P. and A.L. were supported by the Research Council of Norway through its Centres of Excellence funding scheme grant No. 223259. K.P. acknowledges the Estonian Research Council grant MOBJD542 and T.M. PUT611.The c. 2.0 Ga Zaonega Formation of the Onega Basin (NW Russia) has been central in efforts to understand what led to the initial rise (Great Oxidation Event, GOE) and postulated fall in free atmospheric oxygen and associated high-amplitude carbon cycle excursions, the Lomagundi-Jatuli Event (LJE) and subsequent Shunga Event during Paleoproterozoic time. The Formation accumulated shortly after the LJE and encompasses both the recovery in the carbon cycle and hypothesised contraction of the oceanic oxidant pool. However, interpreting the correct environmental context recorded by geochemical signatures in the Zaonega rocks is difficult due to a complex depositional and diagenetic history. In order to robustly constrain that history, we undertook a multiproxy study (mineralogy, petrography, carbon isotope and rare earth element composition) of carbonate beds in the upper part of the Zaonega Formation recovered in the 102-m composite section of the OnZap drill-cores. Our findings differentiate primary environmental signatures from secondary overprinting and show that: (i) the best-preserved carbonate beds define an upwards increasing δ13Ccarb trend from c. -5.4‰ to near 0‰; and that (ii) large intra-bed δ13Ccarb variations reflect varying contributions of methanotrophic dissolved inorganic carbon (DIC) to the basinal DIC pool. Rare earth element and yttrium (REYSN) patterns confirm a marine origin of the carbonate beds whereas a consistent positive EuSN anomaly suggests a strong high temperature hydrothermal input during accumulation of the Zaonega Formation. Importantly, the presence of a negative CeSN anomaly in the REYSN pattern indicates an oxygenated atmosphere-ocean system shortly after the LJE and indicates that models invoking a fall in oxygen at that time require reassessment.PostprintPeer reviewe

Geology and geochronology of the Tana Basin, Ethiopia: LIP volcanism, super eruptions and Eocene–Oligocene environmental change

New geological and geochronological data define four episodes of volcanism for the Lake Tana region in the northern Ethiopian portion of the Afro–Arabian Large Igneous Province (LIP): pre-31 Ma flood basalt that yielded a single 40Ar/39Ar age of 34.05±0.54/0.56 Ma; thick and extensive felsic ignimbrites and rhyolites (minimum volume of 2–3×103 km3) erupted between 31.108±0.020/0.041 Ma and 30.844±0.027/0.046 Ma (U–Pb CA-ID-TIMS zircon ages); mafic volcanism bracketed by 40Ar/39Ar ages of 28.90±0.12/0.14 Ma and 23.75±0.02/0.04 Ma; and localised scoraceous basalt with an 40Ar/39Ar age of 0.033±0.005/0.005 Ma. The felsic volcanism was the product of super eruptions that created a 60–80 km diameter caldera marked by km-scale caldera-collapse fault blocks and a steep-sided basin filled with a minimum of 180 m of sediment and the present-day Lake Tana. These new data enable mapping, with a finer resolution than previously possible, Afro–Arabian LIP volcanism onto the timeline of the Eocene–Oligocene transition and show that neither the mafic nor silicic volcanism coincides directly with perturbations in the geochemical records that span that transition. Our results reinforce the view that it is not the development of a LIP alone but its rate of effusion that contributes to inducing global-scale environmental change

The Palaeoproterozoic global carbon cycle : insights from the Loch Maree Group, NW Scotland

Fieldwork was supported by the Edinburgh Geological Society Clough & Mykura Fund, the Carnegie Undergraduate Scholarship and a stipend provided by the Irvine Bequest through the University of St Andrews to G.B.K. Laboratory work, and isotope and geochronology analyses were financed by NERC grant NE/G00398X/1 to A.R.P., A.E.F., D.J.Condon and A.P.M. Thanks go to T. Donnelly, J. Dougans, A. Calder, D. Herd, B. Pooley and A. Mackie for laboratory assistance.Peer reviewedPostprin

Hydrothermal dedolomitisation of carbonate rocks of the Paleoproterozoic Zaonega Formation, NW Russia — Implications for the preservation of primary C isotope signals

This study was supported by Estonian Science Agency project PUT696 and PRG447, and Estonian Centre of Analytical Chemistry. K.P. and A.L. were supported by the Research Council of Norway through its Centres of Excellence funding scheme grant No. 223259.The Paleoproterozoic Zaonega Formation in Karelia, NW Russia, has played a key role in understanding the environmental conditions postdating the Great Oxidation and Lomagundi-Jatuli Events. Its carbonate- and organic-rich rocks (shungite) define the postulated Shunga Event representing an accumulation of very organic-rich sediments at c. 2 Ga and are central in ideas about changing ocean-atmosphere composition in the wake of those worldwide biogeochemical phenomena. Our work focussed on a key interval of carbonate rocks in the upper part of the Formation to: (i) obtain new high-resolution carbon, oxygen and strontium isotope data complemented by detailed petrography and mineralogical characterisation and (ii) expand upon previous studies by using our data to constrain geochemical modelling and show in greater detail how magmatic hydrothermal fluids induced dedolomitisation and altered geochemical signals. Our findings show that the δ13Ccarb of calcite-rich intervals are the most altered, with values between −16.9 to 0.6‰, whereas the dolomite-dominated parts retain the best-preserved (i.e. most original) values. Those define a trend of steadily increasing δ13Ccarb, from −6 to +0.5‰, which we interpret as a return to normal marine conditions and carbonate‑carbon values following the Lomagundi-Jatuli Event.PostprintPeer reviewe

The grandest of them all : the Lomagundi-Jatuli Event and Earth's oxygenation

Funding: K.K., A.L. and T.K. received funding from Estonian Science Agency Project PRG447 and Yu.D., A.R., D.R. and P.M. were supported by the state assignment of the Institute of Geology, Karelian Research Centre of the Russian Academy of Sciences.The Paleoproterozoic Lomagundi–Jatuli Event (LJE) is generally considered the largest, in both amplitude and duration, positive carbonate C-isotope (δ13Ccarb) excursion in Earth history. Conventional thinking is that it represents a global perturbation of the carbon cycle between 2.3–2.1 Ga linked directly with, and in part causing, the postulated rise in atmospheric oxygen during the Great Oxidation Event. In addition to new high-resolution δ13Ccarb measurements from LJE-bearing successions of NW Russia, we compiled 14 943 δ13Ccarb values obtained from marine carbonate rocks 3.0–1.0 Ga in age and from selected Phanerozoic time intervals as a comparator of the LJE. Those data integrated with sedimentology show that, contra to consensus, the δ13Ccarb trend of the LJE is facies (i.e. palaeoenvironment) dependent. Throughout the LJE interval, the C-isotope composition of open and deeper marine settings maintained a mean δ13Ccarb value of +1.5 ± 2.4‰, comparable to those settings for most of Earth history. In contrast, the 13C-rich values that are the hallmark of the LJE are limited largely to nearshore-marine and coastal-evaporitic settings with mean δ13Ccarb values of +6.2 ± 2.0‰ and +8.1 ± 3.8‰, respectively. Our findings confirm that changes in δ13Ccarb are linked directly to facies changes and archive contemporaneous dissolved inorganic carbon pools having variable C-isotopic compositions in laterally adjacent depositional settings. The implications are that the LJE cannot be construed a priori as representative of the global carbon cycle or a planetary-scale disturbance to that cycle, nor as direct evidence for oxygenation of the ocean–atmosphere system. This requires rethinking models relying on those concepts and framing new ideas in the search for understanding the genesis of the grandest of all positive C-isotope excursions, its timing and its hypothesized linkage to oxygenation of the atmosphere.Publisher PDFPeer reviewe

A refined late-Cryogenian – Ediacaran Earth history of South China: : phosphorous-rich marbles of the Dabie and Sulu orogens

This research was supported by the National Natural Science Foundation of China Grant Numbers 41473039 and 4151101015, and by the Estonian Science Agency project PUT0696.The late-Cryogenian – Ediacaran geological framework for South China is constructed principally from sedimentary successions preserved in the central and western regions of the Yangtze Block. New stratigraphic and carbonate-carbon isotope data allow us to extend that framework into the exhumed HP-UHP subduction complexes of the eastern Dabie and Sulu orogens that separate the South and North China cratons. Those data show that marble and phosphorous-rich (P-rich) units in those complexes were originally part of an Ediacaran shallow-marine shelf-carbonate platform. The basal pebbly schist (metadiamictite) and lowermost P-rich marble of the Jinping Formation (Haizhou Group) in the Sulu Orogen matches in both facies character and C-isotope profile that of the Marinoan-equivalent glacial-cap carbonate couplet of the Nantuo and Doushantuo formations. The Daxinwu Formation (Susong Group) in the eastern Dabie Orogen contains a marble unit that has, for several hundreds of metres, a strikingly uniform C-isotope profile of low δ13C positive values and is overlain by a P-rich graphitic schist; these features match those of the late Ediacaran to early Cambrian Dengying Formation. These correlations establish that the HP-UHP metasedimentary rocks, many of which were once considered to be Palaeo- to Mesoproterozoic in age, are a Neoproterozoic-age cover sequence of the continental margin of the Yangtze Block. Further, their widespread development limits their utility as indicators of offset across the Tan-Lu fault zone and, instead, favours tectonic models that interpret that feature as a continental-scale tear fault formed during the Mesozoic collision and suturing of the North and South China cratons.PostprintPeer reviewe