Balancing Local Order and Long-Ranged Interactions in the Molecular Theory of Liquid Water

A molecular theory of liquid water is identified and studied on the basis of computer simulation of the TIP3P model of liquid water. This theory would be exact for models of liquid water in which the intermolecular interactions vanish outside a finite spatial range, and therefore provides a precise analysis tool for investigating the effects of longer-ranged intermolecular interactions. We show how local order can be introduced through quasi-chemical theory. Long-ranged interactions are characterized generally by a conditional distribution of binding energies, and this formulation is interpreted as a regularization of the primitive statistical thermodynamic problem. These binding-energy distributions for liquid water are observed to be unimodal. The gaussian approximation proposed is remarkably successful in predicting the Gibbs free energy and the molar entropy of liquid water, as judged by comparison with numerically exact results. The remaining discrepancies are subtle quantitative problems that do have significant consequences for the thermodynamic properties that distinguish water from many other liquids. The basic subtlety of liquid water is found then in the competition of several effects which must be quantitatively balanced for realistic results.Comment: 8 pages, 6 figure

COPTRAN - A method of optimum communication systems design

Single set of mathematical expressions describes system cost and probability of error of data transmission in terms of four basic parameters in the link equation. A Lagrange multiplier sets up equations whose solutions yield the optimum values for system design considerations and weight and cost values

Causality Violations in Cascade Models of Nuclear Collisions

Transport models have successfully described many aspects of intermediate energy heavy-ion collision dynamics. As the energies increase in these models to the ultrarelativistic regime, Lorentz covariance and causality are not strictly respected. The standard argument is that such effects are not important to final results; but they have not been seriously considered at high energies. We point out how and why these happen, how serious of a problem they may be and suggest ways of reducing or eliminating the undesirable effects.Comment: RevTeX, 23 pages, 9 (uuencoded) figures; to appear in Phys. Rev

Polyimides prepared from 3,5-diamino benzo trifluoride

High performance, thermooxidatively stable polyimides are prepared by reacting aromatic diamines with pendant trifluoromethyl groups and dianhydrides in an amide solvent to form a poly(amic acid), followed by cyclizing the poly(amic acid) to form the corresponding polyimide

Aromatic polyimides containing a dimethylsilane-linked dianhydride

A high-temperature stable, optically transparent, low dielectric aromatic polyimide is prepared by chemically combining equimolar quantities of an aromatic dianhydride reactant and an aromatic diamine reactant, which are selected so that one reactant contains at least one Si(CH3)2 group in its molecular structure, and the other reactant contains at least one -CF3 group in its molecular structure. The reactants are chemically combined in a solvent medium to form a solution of a high molecular weight polyamic acid, which is then converted to the corresponding polyimide

Isomeric oxydiphthalic anhydride polyimides

Much of the polyimide research at Langley Research Center has focused on isomeric modification of the diamine component; polyimides having considerably improved processability and adhesion have resulted. The present structure-property study was designed to investigate how isomeric attachment of the three oxydiphthalic anhydride (ODPA) polyimides affects their properties. Each dianhydride, 3,4,3',4'-oxydiphthalic anhydride (4,4'-OPDA,I), 2,3,2',3'-oxydiphthalic anhydride (3,3'-ODPA,II), and 2,3,3',4'-oxydiphthalic anhydride (3,4'-OPDA,III), was reacted with p-phenylenediamine, 4,4'-oxydianiline, 3,3'-diaminodiphenylsulfone, 3,3'-diaminobenzophenone, and 4,4'-bis(3-aminophenoxy)benzophenone in DMAc. The inherent viscosities of the resulting poly(amic acids) were determined. Thermally imidized films were studied for their creasability and solubility, as well as by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and wide angle X-ray scattering (WAXS). A comparison of these properties will be made

Comment on "Canonical and Mircocanonical Calculations for Fermi Systems"

In the context of nuclear physics Pratt recently investigated noninteracting Fermi systems described by the microcanonical and canonical ensemble. As will be shown his discussion of the model of equally spaced levels contains a flaw and a statement which is at least confusing.Comment: Comment on S. Pratt, Phys. Rev. Lett. 84, 4255 (2000) and nucl-th/990505

An XMM-Newton observation of the nova-like variable UX UMa: spatially and spectrally resolved two-component X-ray emission

In the optical and ultraviolet regions of the electromagnetic spectrum, UX Ursae Majoris is a deeply eclipsing cataclysmic variable. However, no soft X-ray eclipse was detected in ROSAT observations. We have obtained a 38 ksec XMM-Newton observation to further constrain the origin of the X-rays. The combination of spectral and timing information allows us to identify two components in the X-ray emission of the system. The soft component, dominant below photon energies of 2 keV, can be fitted with a multi-temperature plasma model and is uneclipsed. The hard component, dominant above 3 keV, can be fitted with a kT ~ 5 keV plasma model and appears to be deeply eclipsed. We suggest that the most likely source of the hard X-ray emission in UX UMa, and other systems in high mass transfer states, is the boundary layer.Comment: To appear in MNRAS Letter

Changes in intergenerational eating patterns and the impact on childhood obesity

The objective of this study was to examine intergenerational eating patterns within two sets of families, those with an obese child and those with a normal weight child, and to assess the impact of intergenerational influences on children's eating. A qualitative study design was used, incorporating focus groups and semi-structured interviews. Sixteen focus groups took place and 27 semi-structured interviews were held with different generations. Focus groups were conducted in the community with grandparents, parents and children from different families. This was followed by semi-structured interviews, involving individuals from three generations within families with an obese child and within families with a normal weight child. An examination of intergenerational eating has shown that eating patterns have changed regardless of whether or not families have children who are obese. The grandparent's eating patterns were more structured, whereas the children's eating patterns were less so. There have been more changes, and eating is less structured, within those families with an obese child than those families with a normal weight child. It is recommended that approaches to tackling childhood obesity concentrate on the family setting and the ways in which professionals can support families to change eating practices. Future research should formally test the relationship between the concept 'structured eating' and the 'what' of eating, in order to determine whether there is a link between intergenerational eating patterns and childhood obesity. © The Author(s) 2010