Stratospheric chemistry and transport

A Chemical Tracer Model (CTM) that can use wind field data generated by the General Circulation Model (GCM) is developed to implement chemistry in the three dimensional GCM of the middle atmosphere. Initially, chemical tracers with simple first order losses such as N2O are used. Successive models are to incorporate more complex ozone chemistry

Indirect long-term global radiative cooling from NOx emissions

Anthropogenic emissions of short‐lived, chemically reactive gases, such as NO x and CO, are known to influence climate by altering the chemistry of the global troposphere and thereby the abundance of the greenhouse gases O3, CH4 and the HFCs. This study uses the characteristics of the natural modes of the tropospheric chemical system to decompose the greenhouse effect of NO x and CO emissions into (i) short‐lived modes involving predominantly tropospheric O3 and (ii) the long‐lived mode involving a global coupled CH4‐CO‐O3 perturbation. Combining these two classes of greenhouse perturbations—large, short‐lived, regional O3 increases and smaller, long‐lived, global decreases in CH4 and O3—we find that most types of anthropogenic NO x emissions lead to a negative radiative forcing and an overall cooling of the earth

Global impact of the Antarctic ozone hole: Simulations with a 3-D chemical transport model

A study of the Antarctic ozone hole was made with a 3-D chemical transport model using linearized photochemistry for ozone based on observed distribution. The tracer model uses the winds and convection from the GISS general circulation model (8 deg x 10 deg x 23 layers). A 3-year control run of the ozone distribution is compared with the observed climatology. In two experiments, a hypothetical Antarctic ozone hole is induced on October 1 and on November 1; the tracer model is integrated for 1 year with the standard linearized chemistry. The initial depletion, 90 percent of the O sub 3 poleward of 70 S between 25 and 180 mbar, amounts to about 5 percent of the total O sub 3 in the Southerm Hemisphere. As the vortex breaks down and the hole is dispersed, significant depletions to column ozone, of order 10 D.U., occur as far north as 36 S during Austral summer. One year later, about 25 percent of the original depletion remains, mostly below 100 mbar and poleward of 30 S. Details of the calculations are shown, along with a budget analysis showing the fraction of the hole filled in by photochemistry versus that transported into the troposhere

Present state of knowledge of the upper atmosphere 1988: An assessment report

This document was issued in response to the Clean Air Act Amendments of 1977, Public Law 95-95, mandating that NASA and other key agencies submit biennial reports to Congress and EPA. NASA is to report on the state of our knowledge of the upper atmosphere, particularly the stratosphere. This is the sixth ozone assessment report submitted to Congress and the concerned regulatory agencies. Part 1 contains an outline of the NASA Upper Atmosphere Research Program and summaries of the research efforts supported during the last two years. An assessment is presented of the state of knowledge as of March 15, 1988 when the Ozone Trends Panel, organized by NASA and co-sponsored by the World Meteorological Organization, NOAA, FAA and the United Nations Environment Program released an executive summary of its findings from a critical in-depth study involving over 100 scientists from 12 countries. Chapter summaries of the International Ozone Trends Panel Report form the major part of this report. Two other sections are Model Predictions of Future Ozone Change and Chemical Kinetics and Photochemical Data for Use in Stratospheric Modeling. Each of these sections and the report in its entirety were peer reviewed

The Perception of Fairness of Performance Appraisals

The perception of fairness in performance appraisals (PA) is one of the most important factors and considered a criterion when reviewing PA effectiveness (Jacobs, Kafry, and Zedeck, 1980). In this particular study, I examined numerous variables in three main categories: interpersonal, procedural, and outcome fairness. Keep in mind that although these are three distinct categories, they are all inter-related. One hundred ninety-two employees, from the research and development section of a large retail company, voluntarily participated. The results were slightly contradictory to what was expected yet they were good results. The interpersonal variable, manager effectiveness, along with the outcome variables, fair pay and rewards, and an employee\u27s last year\u27s performance rating are the strongest predictors of the perception of fairness. However, there was not a significant finding in age discriminatio

The Perception of Fairness of Performance Appraisals

The perception of fairness in performance appraisals (PA) is one of the most important factors and considered a criterion when reviewing PA effectiveness (Jacobs, Kafry, and Zedeck, 1980). In this particular study, I examined numerous variables in three main categories: interpersonal, procedural, and outcome fairness. Keep in mind that although these are three distinct categories, they are all inter-related. One hundred ninety-two employees, from the research and development section of a large retail company, voluntarily participated. The results were slightly contradictory to what was expected yet they were good results. The interpersonal variable, manager effectiveness, along with the outcome variables, fair pay and rewards, and an employee\u27s last year\u27s performance rating are the strongest predictors of the perception of fairness. However, there was not a significant finding in age discriminatio

Present state of knowledge of the upper atmosphere 1990: An assessment report

NASA is charged with the responsibility to report on the state of the knowledge of the Earth's upper atmosphere, particularly the stratosphere. Part 1 of this report, issued earlier this year, summarized the objectives, status, and accomplishments of the research tasks supported under NASA's Upper Atmosphere Research Program during the last two years. New findings since the last report to Congress was issued in 1988 are presented. Several scientific assessments of the current understanding of the chemical composition and physical structure of the stratosphere are included, in particular how the abundance and distribution of ozone is predicted to change in the future. These reviews include: a summary of the most recent international assessment of stratospheric ozone; a study of future chlorine and bromine loading of the atmosphere; a review of the photochemical and chemical kinetics data that are used as input parameters for the atmospheric models; a new assessment of the impact of Space Shuttle launches on the stratosphere; a summary of the environmental issues and needed research to evaluate the impact of the newly re-proposed fleet of stratospheric supersonic civil aircraft; and a list of the contributors to this report and the science assessments which have formed our present state of knowledge of the upper atmosphere and ozone depletion

The atmospheric effects of stratospheric aircraft: A topical review

In the late 1960s the aircraft industry became interested in developing a fleet of supersonic transports (SSTs). Between 1972 and 1975, the Climatic Impact Assessment Program (CIAP) studied the possible environmental impact of SSTs. For environmental and economic reasons, the fleet of SSTs was not developed. The Upper Atmosphere Research Program (UARP) has recently undertaken the responsibility of directing scientific research needed to assess the atmospheric impact of supersonic transports. The UARP and the High-Speed Research Program asked Harold Johnston to review the current understanding of aircraft emissions and their effect on the stratosphere. Johnston and his colleagues have recently re-examined the SST problem using current models for stratospheric ozone chemistry. A unique view is given here of the current scientific issues and the lessons learned since the beginning of CIAP, and it links the current research program with the assessment process that began two years ago

Five blind men and the elephant: what can the NASA Aura ozone measurements tell us about stratosphere-troposphere exchange?

We examine whether the individual ozone (O<sub>3</sub>) measurements from the four Aura instruments can quantify the stratosphere-troposphere exchange (STE) flux of O<sub>3</sub>, an important term of the tropospheric O<sub>3</sub> budget. The level 2 (L2) Aura swath data and the nearly coincident ozone sondes for the years 2005–2006 are compared with the 4-D, high-resolution (1° × 1° × 40-layer × 0.5 h) model simulation of atmospheric ozone for the same period from the University of California, Irvine chemistry transport model (CTM). The CTM becomes a transfer standard for comparing individual profiles from these five, not-quite-coincident measurements of atmospheric ozone. Even with obvious model discrepancies identified here, the CTM can readily quantify instrument-instrument biases in the tropical upper troposphere and mid-latitude lower stratosphere. In terms of STE processes, all four Aura datasets have some skill in identifying stratosphere-troposphere folds, and we find several cases where both model and measurements see evidence of high-O<sub>3</sub> stratospheric air entering the troposphere. In many cases identified in the model, however, the individual Aura profile retrievals in the upper troposphere and lower stratosphere show too much noise, as expected from their low sensitivity and coarse vertical resolution at and below the tropopause. These model-measurement comparisons of individual profiles do provide some level of confidence in the model-derived STE O<sub>3</sub> flux, but it will be difficult to integrate this flux from the satellite data alone

Sea Spray Aerosol: Where Marine Biology Meets Atmospheric Chemistry.

Atmospheric aerosols have long been known to alter climate by scattering incoming solar radiation and acting as seeds for cloud formation. These processes have vast implications for controlling the chemistry of our environment and the Earth's climate. Sea spray aerosol (SSA) is emitted over nearly three-quarters of our planet, yet precisely how SSA impacts Earth's radiation budget remains highly uncertain. Over the past several decades, studies have shown that SSA particles are far more complex than just sea salt. Ocean biological and physical processes produce individual SSA particles containing a diverse array of biological species including proteins, enzymes, bacteria, and viruses and a diverse array of organic compounds including fatty acids and sugars. Thus, a new frontier of research is emerging at the nexus of chemistry, biology, and atmospheric science. In this Outlook article, we discuss how current and future aerosol chemistry research demands a tight coupling between experimental (observational and laboratory studies) and computational (simulation-based) methods. This integration of approaches will enable the systematic interrogation of the complexity within individual SSA particles at a level that will enable prediction of the physicochemical properties of real-world SSA, ultimately illuminating the detailed mechanisms of how the constituents within individual SSA impact climate