HYDROGEOCHEMICAL CONDITION OF THE PIKROLIMNI LAKE (KILKIS GREECE)

In order to understand the hydrogeochemical conditions of the basin of Pikrolimni we collected water samples from the borehole in the thermal spa of Pikrolimni and samples of brine and sediments from the lake. We also sampled fresh water of the region. The depth of the borehole in the thermal spa is approximately 250 meters. This water is naturally sparkling, with a metallic aftertaste and a slight organic smell. The samples were taken twice during the year: in summer (8/2002) and in winter (2003). The analytical scheme includes field measurements of temperature, conductivity and pH. Major ions (Na+, K+, Ca2+, Mg2\ CI", Br, S04 2", C03 2", HC03", N03"), F and Br were determined, in laboratory, according to standard analytical methods. Samples were also subjected to isotopie analysis of δ Ο and δ2Η. The results from the chemical analyses of the samples, show that the waters taken from the borehole, are of the type Mg- (Na-Ca)-HCC>3 and the salts of the lake are of the type Na-CI- (CO3-S04). The salts of the lake result from mixing and condensation of the waters which are accumulated in the basin of the lake, and come not only from sources that feed the lake, e.g. waters from borehole, but also from rain water. The waters of these sources are mainly of meteoritic origin and circulate deeply, mixing probably with salt water of deeper and probably of warmer horizons. The latter comes in agreement with the hydrothermal field, which exists in the area. From hydrochemical data, the brines of summer clearly correspond to waters, which have been submitted under high degree of evaporation: they are residual mother solutions before the step of the precipitation of halite. During winter, dilution of brines and dissolution of depositing minerals by fresh water are observed. On the other hand, evaporating conditions are created in the lake during summer

PLEISTOCENE PALAEOCLIMATIC EVOLUTION FROM AGIOS GEORGIOS CAVE SPELEOTHEM (KILKIS, N. GREECE)

Palaeoclimatic reconstruction in N. Greece has been investigated in this study, using stable isotope analyses and U/Th dating of a speleothem (stalactite) from the cave of Agios Georgios (Kilkis). Sampling sequence was followed in detail in order to obtain high resolution analysis of the proxy. Speleothem δ18O entirely depends on two factors: changes in the δ18O of the percolation waters (a proxy for local rainfall δ18O) and the temperature of water-calcite fractionation inside the cave (a proxy for outside air temperatures). During periods of relatively stable temperatures, δ13C shifts are caused principally by variations in soil CO2 input and physico-chemical processes inside the cave. More important processes affect the δ13C signal of speleothem inside the cave are length of flow path and rates of CO2 degassing.The lower δ13C calcite values indicate greater respiratory activity of soils under wetter conditions. The stalagmite layers were dated through U/Th geochronological method, which places the carbonate precipitation in Middle Pleistocene (630-300ka BP). The isotopic composition of the layers was used in combination with the dating results to reconstruct the evolution of the area of Kilkis. Correlation with global climatic records shows that major climatic transitions that influenced northern hemisphere seem to have also affected the region of N. Greece

PLEISTOCENE PALAEOCLIMATIC EVOLUTION FROM AGIOS GEORGIOS CAVE SPELEOTHEM (KILKIS, N. GREECE)

Palaeoclimatic reconstruction in N. Greece has been investigated in this study, using stable isotope analyses and U/Th dating of a speleothem (stalactite) from the cave of Agios Georgios (Kilkis). Sampling sequence was followed in detail in order to obtain high resolution analysis of the proxy. Speleothem δ18O entirely depends on two factors: changes in the δ18O of the percolation waters (a proxy for local rainfall δ18O) and the temperature of water-calcite fractionation inside the cave (a proxy for outside air temperatures). During periods of relatively stable temperatures, δ13C shifts are caused principally by variations in soil CO2 input and physico-chemical processes inside the cave. More important processes affect the δ13C signal of speleothem inside the cave are length of flow path and rates of CO2 degassing.The lower δ13C calcite values indicate greater respiratory activity of soils under wetter conditions. The stalagmite layers were dated through U/Th geochronological method, which places the carbonate precipitation in Middle Pleistocene (630-300ka BP). The isotopic composition of the layers was used in combination with the dating results to reconstruct the evolution of the area of Kilkis. Correlation with global climatic records shows that major climatic transitions that influenced northern hemisphere seem to have also affected the region of N. Greece

Fingerprinting the origin of sheep milk products based on H-O-C-N isotopes

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Isotopic analysis for degradation diagnosis of calcite matrix in mortar

Mortar that was used in building as well as in conservation and restoration works of wall paintings have been analysed isotopically (δ13C and δ18O) in order to evaluate the setting environments and secondary processes, to distinguish the structural components used and to determine the exact causes that incurred the degradation phenomena. The material undergoes weathering and decay on a large proportion of its surface and in depth, due to the infiltration of water through the structural blocks. Mineralogical analysis indicated signs of sulphation and dissolution/ recrystallisation processes taking place on the material, whereas stable isotopes provided information relative to the origin of the CO2 and water during calcite formation and degradation processes. Isotopic change of the initial δ13C and δ18O in carbonate matrix was caused by alteration of the primary source of CO2 and H2O in mortar over time, particularly by recrystallisation of calcite with porewater, evaporated or re-condensed water, and CO2 from various sources of atmospheric and biogenic origin. Human influence (surface treatment) and biological growth (e.g. fungus) are major exogenic processes which may alter δ18O and δ13C in lime mortar. © 2009 Springer-Verlag

Evaluatie van hydrogeologische verkenningstechnieken voor sedimentlagen boven steenzoutvoorkomens

Abstract niet beschikbaarSafety assessment studies are currently being carried out in relation to the final disposal of hazardous chemical or radioactive waste in rock-salt formations. Subrosion of rock-salt is considered to be one of the important natural processes that could reduce the barrier function of the rock-salt and ultimately induce release of disposed waste into groundwater. In order to validate the geohydrological models for subrosion, the deep groundwater system and the origin of the dissolved salts should be known. The aim of this project is to find out which methods are suitable to obtain relevant geohydro- logical and geohydrochemical data and to indicate, if possible, their uncertainty. The geohydrological methods used for this purpose have been subject of studies described in two previous interim-reports. This report concerns the geohydrochemical methods.E

Natural tracers for identifying the origin of the thermal fluids emerging along the Aegean Volcanic arc (Greece): Evidence of Arc-Type Magmatic Water (ATMW) participation.

International audienc

Stable isotope and chloride, boron study for tracing sources of boron contamination in groundwater: Boron contents in fresh and thermal water in different areas in Greece

International audienc

PLEISTOCENE PALAEOCLIMATIC EVOLUTION FROM AGIOS GEORGIOS CAVE SPELEOTHEM (KILKIS, N. GREECE)

Palaeoclimatic reconstruction in N. Greece has been investigated in this study, using stable isotope analyses and U/Th dating of a speleothem (stalactite) from the cave of Agios Georgios (Kilkis). Sampling sequence was followed in detail in order to obtain high resolution analysis of the proxy. Speleothem δ18O entirely depends on two factors: changes in the δ18O of the percolation waters (a proxy for local rainfall δ18O) and the temperature of water-calcite fractionation inside the cave (a proxy for outside air temperatures). During periods of relatively stable temperatures, δ13C shifts are caused principally by variations in soil CO2 input and physico-chemical processes inside the cave. More important processes affect the δ13C signal of speleothem inside the cave are length of flow path and rates of CO2 degassing.The lower δ13C calcite values indicate greater respiratory activity of soils under wetter conditions. The stalagmite layers were dated through U/Th geochronological method, which places the carbonate precipitation in Middle Pleistocene (630-300ka BP). The isotopic composition of the layers was used in combination with the dating results to reconstruct the evolution of the area of Kilkis. Correlation with global climatic records shows that major climatic transitions that influenced northern hemisphere seem to have also affected the region of N. Greece