Excavations at 41LK67 a Prehistoric Site in the Choke Canyon Reservior, South Texas

In 1977-1978 excavations were conducted at 41 LK 67 in Live Oak County, south Texas, by the Center for Archaeological Research, The University of Texas at San Antonio. The investigation of this prehistoric archaeological site was part of an extensive program of reconnaissance and excavation necessitated by the construction of the Choke Canyon Reservoir on the Frio River by the Bureau of Reclamation. The site is situated in shallow colluvial deposits capping an old terrace remnant of the Frio River. The excavations involved 193 m2 in three separate areas and revealed Late Prehistoric and Late Archaic components. Recognizably older artifacts (including patinated chert flakes) from the surface and from excavations may represent older disturbed components or artifacts collected prehistorically from nearby sites. Radiocarbon dates, with medians ranging from 1590 to 660 B.C. (MASCA correction) are available only from the Late Archaic component. The principal kinds of debris recovered from the excavations are fire-cracked rock, cores and chipping debris, shells of snails and freshwater mussels, plainware potsherds, and chipped stone tools. Mussel shell was surprisingly abundant; more than 9000 specimens, including 3000 specimens identified taxonomically, were recovered. Fish otoliths were the only animal bones preserved, except for a few recent, intrusive elements. Debris frequencies from the two larger excavation blocks (Areas A and B) were factor analyzed. In most cases the analysis showed the strongest covariation occurring among different classes of chipping debris. For Area C factor analysis indicated that the strongest spatial patterning occurred in the upper part of the deposits. Unfortunately, the analysis was not particularly successful in defining activity sets. The small collection of chipped stone tools was examined microscopically. Two tool classes in particular, distally beveled tools (gouges) and quadrilateral bifaces (beveled knives) seem to represent more functionally specific tool forms, but other hafted bifaces (projectile points) show a wide range of use wear mostly unrelated to projectile use

X-ray properties of the white dwarf pulsar eRASSU J191213.9-441044

We report X-ray observations of the newly discovered pulsating white dwarf eRASSU J191213.9-441044 with Spectrum Roentgen Gamma and eROSITA (SRG/eROSITA) and XMM-Newton. The new source was discovered during the first eROSITA all-sky survey at a flux level of fX (0.2 - 2.3 keV) = 3.3 e-13 erg cm-2 s-1 and found to be spatially coincident with a G = 17.1 stellar Gaia-source at a distance of 237 pc. The flux dropped to about fX = 1 e-13 erg cm-2 s-1 during the three following eROSITA all-sky surveys and remained at this lower level during dedicated XMM-Newton observations performed in September 2022. With XMM-Newton, pulsations with a period of 319 s were found at X-ray and ultraviolet wavelengths occurring simultaneously in time, thus confirming the nature of eRASSU J191213.9-441044 as the second white-dwarf pulsar. The X-ray and UV-pulses correspond to broad optical pulses. Narrow optical pulses that occurred occasionally during simultaneous XMM-Newton/ULTRACAM observations have no X-ray counterpart. The orbital variability of the X-ray signal with a roughly sinusoidal shape was observed with a pulsed fraction of ~28% and maximum emission at orbital phase ~0.25. The ultraviolet light curve peaks at around binary phase 0.45. The X-ray spectrum can be described with the sum of a power law spectrum and a thermal component with a mean X-ray luminosity of Lx(0.2-10 keV) = 1.4 e30 erg s-1. The spectral and variability properties could indicate some residual accretion, in contrast to the case of the prototypical object AR Sco.Comment: 6 pages, 7 figures, A&A Letter accepte

Intrusion of warm Bering/Chukchi waters onto the shelf in the western Beaufort Sea

Author Posting. © American Geophysical Union, 2009. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 114 (2009): C00A11, doi:10.1029/2008JC004870.Wind-driven changes in the path of warm Bering/Chukchi waters carried by the Alaska Coastal Current (ACC) through Barrow Canyon during late summer are described from high-resolution hydrography, acoustic Doppler current profiler–measured currents, and satellite-measured sea surface temperature imagery acquired from mid-August to mid-September 2005–2007 near Barrow, Alaska. Numerical simulations are used to provide a multidecadal context for these observational data. Four generalized wind regimes and associated circulation states are identified. When winds are from the east or east-southeast, the ACC jet tends to be relatively strong and flows adjacent to the shelf break along the southern flank of Barrow Canyon. These easterly winds drive inner shelf currents northwestward along the Alaskan Beaufort coast where they oppose significant eastward intrusions of warm water from Barrow Canyon onto the shelf. Because these easterly winds promote sea level set down over the Beaufort shelf and upwelling along the Beaufort slope, the ACC jet necessarily becomes weaker, broader, and displaced seaward from the Beaufort shelf break upon exiting Barrow Canyon. Winds from the northeast promote separation of the ACC from the southern flank of Barrow Canyon and establish an up-canyon current along the southern flank that is fed in part by waters from the western Beaufort shelf. When winds are weak or from the southwest, warm Bering/Chukchi waters from Barrow Canyon intrude onto the western Beaufort shelf.This work was supported in 2005 and 2006 by NSF grants OPP-0436131 and OPP-0436166. In 2007, this work received support through Woods Hole Oceanographic Institution- NOAA Cooperative Institute for Climate and Ocean Research Cooperative Agreement NA17RJ1223 and University of Alaska Fairbanks-NOAA Cooperative Institute for Arctic Research Cooperative Agreement NA17RJ1224. Additional support was provided by the James M. and Ruth P. Clark Arctic Research Initiative Fund at the Woods Hole Oceanographic Institution

Suzaku Observations of Active Galactic Nuclei Detected in the Swift/BAT Survey: Discovery of "New Type" of Buried Supermassive Black Holes

We present the Suzaku broad band observations of two AGNs detected by the Swift/BAT hard X-ray (>15 keV) survey that did not have previous X-ray data, Swift J0601.9-8636 and Swift J0138.6-4001. The Suzaku spectra reveals in both objects a heavily absorbed power law component with a column density of NH =~ 10^{23.5-24} cm^{-2} that dominates above 10 keV, and an intense reflection component with a solid angle >~ $2\pi$ from a cold, optically thick medium. We find that these AGNs have an extremely small fraction of scattered light from the nucleus, <~ 0.5% with respect to the intrinsic power law component. This indicates that they are buried in a very geometrically-thick torus with a small opening angle and/or have unusually small amount of gas responsible for scattering. In the former case, the geometry of Swift J0601.9-8636 should be nearly face-on as inferred from the small absorption for the reflection component. The discovery of two such objects in this small sample implies that there must be a significant number of yet unrecognized, very Compton thick AGNs viewed at larger inclination angles in the local universe, which are difficult to detect even in the currently most sensitive optical or hard X-ray surveys.Comment: 4 pages, 3 figures, accepted for publication in ApJ Lette

Nerve Agent Hydrolysis Activity Designed into a Human Drug Metabolism Enzyme

Organophosphorus (OP) nerve agents are potent suicide inhibitors of the essential neurotransmitter-regulating enzyme acetylcholinesterase. Due to their acute toxicity, there is significant interest in developing effective countermeasures to OP poisoning. Here we impart nerve agent hydrolysis activity into the human drug metabolism enzyme carboxylesterase 1. Using crystal structures of the target enzyme in complex with nerve agent as a guide, a pair of histidine and glutamic acid residues were designed proximal to the enzyme's native catalytic triad. The resultant variant protein demonstrated significantly increased rates of reactivation following exposure to sarin, soman, and cyclosarin. Importantly, the addition of these residues did not alter the high affinity binding of nerve agents to this protein. Thus, using two amino acid substitutions, a novel enzyme was created that efficiently converted a group of hemisubstrates, compounds that can start but not complete a reaction cycle, into bona fide substrates. Such approaches may lead to novel countermeasures for nerve agent poisoning

High modulus regenerated cellulose fibers spun from a low molecular weight microcrystalline cellulose solution

We have developed a novel process to convert low molecular weight microcrystalline cellulose into stiff regenerated cellulose fibers using a dry-jet wet fiber spinning process. Highly aligned cellulose fibers were spun from optically anisotropic microcrystalline cellulose/1-ethyl-3-methylimidazolium diethyl phosphate (EMImDEP) solutions. As the cellulose concentration increased from 7.6 to 12.4 wt %, the solution texture changed from completely isotropic to weakly nematic. Higher concentration solutions (>15 wt %) showed strongly optically anisotropic patterns, with clearing temperatures ranging from 80 to 90 °C. Cellulose fibers were spun from 12.4, 15.2, and 18.0 wt % cellulose solutions. The physical properties of these fibers were studied by scanning electron microscopy (SEM), wide angle X-ray diffraction (WAXD), and tensile testing. The 18.0 wt % cellulose fibers, with an average diameter of ∼20 μm, possessed a high Young’s modulus up to ∼22 GPa, moderately high tensile strength of ∼305 MPa, as well as high alignment of cellulose chains along the fiber axis confirmed by X-ray diffraction. This process presents a new route to convert microcrystalline cellulose, which is usually used for low mechanical performance applications (matrix for pharmaceutical tablets and food ingredients, etc.) into stiff fibers which can potentially be used for high-performance composite materials

Roadmaps to Utopia: Tales of the Smart City

Notions of the Smart City are pervasive in urban development discourses. Various frameworks for the development of smart cities, often conceptualized as roadmaps, make a number of implicit claims about how smart city projects proceed but the legitimacy of those claims is unclear. This paper begins to address this gap in knowledge. We explore the development of a smart transport application, MotionMap, in the context of a £16M smart city programme taking place in Milton Keynes, UK. We examine how the idealized smart city narrative was locally inflected, and discuss the differences between the narrative and the processes and outcomes observed in Milton Keynes. The research shows that the vision of data-driven efficiency outlined in the roadmaps is not universally compelling, and that different approaches to the sensing and optimization of urban flows have potential for empowering or disempowering different actors. Roadmaps tend to emphasize the importance of delivering quick practical results. However, the benefits observed in Milton Keynes did not come from quick technical fixes but from a smart city narrative that reinforced existing city branding, mobilizing a growing network of actors towards the development of a smart region. Further research is needed to investigate this and other smart city developments, the significance of different smart city narratives, and how power relationships are reinforced and constructed through them

Seasonality of Overseas Tourism Demand in Scotland: A Regional Analysis

This paper examines patterns of seasonality in international tourism to the regions of Scotland. Quarterly numbers of overnight stays are disaggregated by trip purpose. Seasonality in vacation tourism to Scotland is shown to be defined by more than a simple rural–urban division. Overseas visiting friends and relatives (VFR) tourism is largely an urban phenomenon and is consequently less seasonal than vacation tourism. Lower seasonal concentration of VFR tourism is not uniform across the regions. Although levels of seasonal intensity of business tourism to the three principal cities of Scotland are approximately the same, there are noticeable variations over time