Harmonized chronologies of a global late Quaternary pollen dataset (LegacyAge 1.0)

Although numerous pollen records are available worldwide in various databases, their use for synthesis works is limited as the chronologies are, as yet, not harmonized globally, and temporal uncertainties are unknown. We present a chronology framework named LegacyAge 1.0 that includes harmonized chronologies of 2831 palynological records (out of 3471 available records), downloaded from the Neotoma Paleoecology Database (last access: April 2021) and 324 additional Asian records. All chronologies use the Bayesian framework implemented in Bacon version 2.5.3. Optimal parameter settings of priors (accumulation.shape, memory.strength, memory.mean, accumulation.rate, thickness) were identified based on previous experiences or iteratively after preliminary model inspection. The most common control points for the chronologies are radiocarbon dates (86.1 %), calibrated by the latest calibration curves (IntCal20 and SHcal20 for the terrestrial radiocarbon dates in the northern and southern hemispheres; Marine20 for marine materials). The original literature was consulted when dealing with obvious outliers and inconsistencies. Several major challenges when setting up the chronologies included the waterline issue (18.8 % of records), reservoir effect (4.9 %), and sediment deposition discontinuity (4.4 %). Finally, we numerically compare the LegacyAge 1.0 chronologies to the original ones and show that the chronologies of 95.4 % of records could be improved according to our assessment. Our chronology framework and revised chronologies provide the opportunity to make use of the ages and age uncertainties in synthesis studies of, for example, pollen-based vegetation and climate change. The LegacyAge 1.0 dataset and R code used are open-access and available at PANGAEA (https://doi.pangaea.de/10.1594/PANGAEA.933132) and Github (https://github.com/LongtermEcology/LegacyAge-1.0), respectively

Comprehensive tissue-specific proteome analysis of drought stress responses in Pennisetum glaucum (L.) R. Br. (Pearl millet)

Pearl millet is the fifth most important cereal crop worldwide and cultivated especially by small holder farmers in arid and semi-arid regions because of its drought and salt tolerance. The molecular mechanisms of drought stress tolerance in Pennisetum remain elusive. We have used a shotgun proteomics approach to investigate protein signatures from different tissues under drought and control conditions. Drought stressed plants showed significant changes in stomatal conductance and increased root growth compared to the control plants. Root, leaf and seed tissues were harvested and 2281 proteins were identified and quantified in total. Leaf tissue showed the largest number of significant changes (120), followed by roots (25) and seeds (10). Increased levels of root proteins involved in cell wall-, lipid-, secondary- and signaling metabolism and the concomitantly observed increased root length point to an impaired shoot–root communication under drought stress. The harvest index (HI) showed a significant reduction under drought stress. Proteins with a high correlation to the HI were identified using sparse partial least square (sPLS) analysis. Considering the importance of Pearl millet as a stress tolerant food crop, this study provides a first reference data set for future investigations of the underlying molecular mechanisms

Magnesia-Based Cements: A Journey of 150 Years, and Cements for the Future?

This review examines the detailed chemical insights that have been generated through 150 years of work worldwide on magnesium-based inorganic cements, with a focus on both scientific and patent literature. Magnesium carbonate, phosphate, silicate-hydrate, and oxysalt (both chloride and sulfate) cements are all assessed. Many such cements are ideally suited to specialist applications in precast construction, road repair, and other fields including nuclear waste immobilization. The majority of MgO-based cements are more costly to produce than Portland cement because of the relatively high cost of reactive sources of MgO and do not have a sufficiently high internal pH to passivate mild steel reinforcing bars. This precludes MgO-based cements from providing a large-scale replacement for Portland cement in the production of steel-reinforced concretes for civil engineering applications, despite the potential for CO2 emissions reductions offered by some such systems. Nonetheless, in uses that do not require steel reinforcement, and in locations where the MgO can be sourced at a competitive price, a detailed understanding of these systems enables their specification, design, and selection as advanced engineering materials with a strongly defined chemical basis