Determination of Lamb Wave Modes on Lithium-Ion Batteries Using Piezoelectric Transducers

This work presents a method to determine the type of Lamb mode (antisymmetric or symmetric) that propagates through a lithium-ion pouch cell. To determine the type of mode and the group velocity at a specific frequency, two- and three-transducer setups were created. For these setups, it is important that all transducers have the same polarization direction. Two transducers are affixed to the center of the cell at a distance of several centimeters from each other so that the group velocity can be determined. Using cross-correlation, the group velocity of the emerging mode can be calculated. The measurement setup and the processing method was first validated with experiments on acrylic glass and aluminum plates. The measurements were supported with FEM simulations and a numerically calculated model. The output voltages of the receiving piezo-elements obtained in the FEM simulation are in agreement with the underlying theories. The phase shift, which results from the output voltage of the piezo-elements mounted one above the other on different sides of the plate, shows the type of mode. The results of the experimental determination of the Lamb mode that propagates through a lithium-ion pouch cell were validated with a numerically calculated multi-layer model and therefore validate this novel experimental approach

Nanoboomerang-based inverse metasurfaces - a promising path towards ultrathin photonic devices for transmission operation

Metasurfaces have revolutionized photonics due to their ability to shape phase fronts as requested and to tune beam directionality using nanoscale metallic or dielectric scatterers. Here we reveal inverse metasurfaces showing superior properties compared to their positive counterparts if transmission mode operation is considered. The key advantage of such slot-type metasurfaces is the strong reduction of light in the parallel-polarization state, making the crossed-polarization, being essential for metasurface operation, dominant and highly visible. In the experiment, we show an up to four times improvement in polarization extinction for the individual metasurface element geometry consisting of deep subwavelength nanoboomerangs with feature sizes of the order of 100 nm. As confirmed by simulations, strong plasmonic hybridization yields two spectrally separated plasmonic resonances, ultimately allowing for the desired phase and scattering engineering in transmission. Due to the design flexibility of inverse metasurfaces, a large number of highly integrated ultra-flat photonic elements can be envisioned, examples of which include monolithic lenses for telecommunications and spectroscopy, beam shaper or generator for particle trapping or acceleration or sophisticated polarization control for microscopy

Bone Mass Distribution of the Distal Tibia in Normal, Osteopenic, and Osteoporotic Conditions: An Ex Vivo Assessment Using HR-pQCT, DXA, and Computational Modelling.

Osteoporosis leads to bone loss and structural deterioration, which increase the risk of fractures. The aim of this study was to characterize the three-dimensional (3D) bone mass distributions of the distal tibia in normal, osteopenic, and osteoporotic conditions. High-resolution peripheral quantitative computed tomography (HR-pQCT) of the 33 % of the distal tibia and local dual-energy X-ray absorptiometry were applied to 53 intact, fresh-frozen tibiae. The HR-pQCTs were graded to assign local T-scores and merged into three equally sized average normal, osteopenic, and osteoporotic surface models. Volumetric bone mineral density (vBMD) was determined using categorized T-scores, volumetric visualization, and virtual bore probes at the dia-, meta-, and epiphyseal sites (T-DIA, T-META, and T-EPI). We observed a distinct 3D bone mass distribution that was gradually uninfluenced by T-score categories. T-DIA was characterized by the lowest bone mass located in the medullary cavity and a wide homogenous cortex containing the maximum vBMD. The T-META showed decreased cortical thickness and maximal vBMD. At the T-EPI, the relatively low vBMD of the mostly trabecular bone was similar to the maximal cortical vBMD in this sub-region. Four trabecular regions of low bone mass were identified in the recesses. The bone content gradually decreased at all sites, whereas the pattern of bone mass distribution remained essentially unchanged, with the exception of disproportionate losses at T-DIA, T-META, and T-EPI that consistently showed increased endocortical, intracortical, and trabecular bone loss. Extra information can be obtained from the specific pattern of bone mass distribution, potential disproportionate bone losses, and method used

Spin Filter Effects in Mesoscopic Ring Structures

We study the spin-dependent conductance of ballistic mesoscopic ring systems in the presence of an inhomogeneous magnetic field. We show that, for the setup proposed, even a small Zeeman splitting can lead to a considerable spin polarisation of the current. Making use of a spin-switch effect predicted for such systems we propose a device of two rings connected in series that in principle allows for both creating and coherently controlling spin polarized currents at low temperatures.Comment: 5 pages, 8 figure

Conditions for Adiabatic Spin Transport in Disordered Systems

We address the controversy concerning the necessary conditions for the observation of Berry phases in disordered mesoscopic conductors. For this purpose we calculate the spin-dependent conductance of disordered two-dimensional structures in the presence of inhomogeneous magnetic fields. Our numerical results show that for both, the overall conductance and quantum corrections, the relevant parameter defining adiabatic spin transport scales with the square root of the number of scattering events, in generalization of Stern's original proposal [Phys. Rev. Lett. 68, 1022 (1992)]. This could hinder a clear-cut experimental observation of Berry phase effects in diffusive metallic rings.Comment: 5 pages, 4 figures. To appear in Phys. Rev. B (Rapid Communications

Alkylation of rabbit muscle creatine kinase surface methionine residues inhibits enzyme activity in vitro

Creatine kinase (CK) catalyzes the formation of phosphocreatine from adenosine triphosphate (ATP) and creatine. The highly reactive free cysteine residue in the active site of the enzyme (Cys283) is considered essential for the enzymatic activity. In previous studies we demonstrated that Cys283 is targeted by the alkylating chemical warfare agent sulfur mustard (SM) yielding a thioether with a hydroxyethylthioethyl (HETE)-moiety. In the present study, the effect of SM on rabbit muscle CK (rmCK) activity was investigated with special focus on the alkylation of Cys283 and of reactive methionine (Met) residues. For investigation of SM-alkylated amino acids in rmCK, micro liquid chromatography-electrospray ionization high-resolution tandem-mass spectrometry measurements were performed using the Orbitrap technology. The treatment of rmCK with SM resulted in a decrease of enzyme activity. However, this decrease did only weakly correlate to the modification of Cys283 but was conclusive for the formation of Met70-HETE and Met179-HETE. In contrast, the activity of mutants of rmCK produced by side-directed mutagenesis that contained substitutions of the respective Met residues (Met70Ala, Met179Leu, and Met70Ala/Met179Leu) was highly resistant against SM. Our results point to a critical role of the surface exposed Met70 and Met179 residues for CK activity

Hindfoot and Foot Arch Reconstruction by Atypical Subtalar Arthrodesis and Achilles Tendon Lengthening for a Severe Comminuted Calcaneal Fracture: A Case Report

Open calcaneus fractures are rare but severe injuries. Highenergy trauma often causes significant soft tissue and bone damage, posing extraordinary challenges for treatment.3 The rates of complications associated with treatment are high, including malunion, nonunion, and fracture-related infections.5 These complications are associated with an amputation rate of the lower limb of 8%.2 Even if amputation is avoided and treatment and complication management are successful, the patient’s quality of life is compromised, similar to those suffering from bone infections in the long bones. Apart from compromised soft tissue, bone defects present the main obstacle to successful treatment. Anatomical bone reconstruction becomes difficult, if not impossible, in cases of severe compound fractures. Open fractures necessitate thorough surgical debridement to prevent infection, which may result in significant bone defects requiring bone reconstruction.3,4 Given the immense challenges of surgical treatment following high-energy injuries, where bone transplantation and extensive osteosynthesis offer limited promise, we present a case illustrating an atypical subtalar arthrodesis and hindfoot reconstruction in a patient with a Gustilo type IIIa° comminuted calcaneus fracture

The impact of high-end climate change on agricultural welfare

Climate change threatens agricultural productivity worldwide, resulting in higher food prices. Associated economic gains and losses differ not only by region but also between producers and consumers and are affected by market dynamics. On the basis of an impact modeling chain, starting with 19 different climate projections that drive plant biophysical process simulations and ending with agro-economic decisions, this analysis focuses on distributional effects of high-end climate change impacts across geographic regions and across economic agents. By estimating the changes in surpluses of consumers and producers, we find that climate change can have detrimental impacts on global agricultural welfare, especially after 2050, because losses in consumer surplus generally outweigh gains in producer surplus. Damage in agriculture may reach the annual loss of 0.3% of future total gross domestic product at the end of the century globally, assuming further opening of trade in agricultural products, which typically leads to interregional production shifts to higher latitudes. Those estimated global losses could increase substantially if international trade is more restricted. If beneficial effects of atmospheric carbon dioxide fertilization can be realized in agricultural production, much of the damage could be avoided. Although trade policy reforms toward further liberalization help alleviate climate change impacts, additional compensation mechanisms for associated environmental and development concerns have to be considered

X-ray microtomography is a novel method for accurate evaluation of small-bowel mucosal morphology and surface area

The often poorly orientated small-bowel mucosal biopsies taken for the diagnostics of celiac disease and other intestinal disorders are prone to misinterpretation. Furthermore, conventional histopathology has suboptimal sensitivity for early histopathological changes observed in short-term challenge studies. X-ray microtomography (micro-CT) is a promising new method for accurate imaging of human-derived biological samples. Here, we report that micro-CT could be utilized to create virtual reconstructions of endoscopically obtained intestinal biopsies. The formed digital 3D images enabled selection of always optimal cutting angles for accurate measurement of the mucosal damage and revealed diagnostic lesions in cases interpreted as normal with conventional histomorphometry. We also demonstrate that computer-assisted point cloud analysis can be used to calculate biologically meaningful surface areas of the biopsies in different stages of mucosal damage with excellent replicability and correlation with other disease parameters. We expect the improved diagnostic accuracy and capability to measure the surface areas to provide a powerful tool for the diagnostics of intestinal diseases and for future clinical and pharmaceutical trials.Peer reviewe