Synthesis and X-ray crystal structure of [2(phosphinomethyl)ferrocenyl]diphenyl-phosphine

[2-(Phosphinomethyl)ferrocenyl]diphenylphosphine 2, is an air stable primary phosphine bearing a 1,2-disubstituted ferrocene framework, which has been prepared by reduction of the corresponding phosphonate. Confirmation of its structure has been obtained by X-ray single-crystals diffraction analysis. Despite its high stability toward oxidation, phosphine 2 still displays a normal coordinative behaviour toward [(pi-cymene)RuCl2]2. The expected (pi-cymene)RuCl2(phosphine) complex is formed by coordination of the primary phosphine function, while the conceivably competitive complexation of the PPh2 group was not observed

Evidence for a Cr metastable phase as a tracer in DLI-MOCVD chromium hard coatings usable in high temperature environment

Cr deposits are widely used as protective coatings but multifunctional performances are required in harsh environments motivating research on new processes. MOCVD of Cr metal coatings was carried out by direct liquid injection (DLI) of a unique solution containing bis(ethylbenzene)chromium as metal source and thiophenol as inhibitor of carbide formation. A low amount (<6%) of the metastable δ-Cr phase was found embedded in the stable α-Cr phase. The formation of this metastable phase originates from both the low deposition temperature (<723 K) and the use of thiophenol. It was not reported under other CVD conditions. Dense coatings were deposited by implementing a multilayer growth mode. Such coatings exhibit a high nanohardness of about 17 GPa. The δ-Cr metastable phase undergoes an irreversible structural transformation to bcc-Cr above 723 K. The mechanical properties of coatings are not affected by the structural transformation because of the similarity of their crystallographic structures (both cubic), their density very close (a volume contraction of only 0.4% during the transformation) and its low content. This metastable phase is a signature of the DLI-MOCVD process and it can be used as a tracer for Cr coatings operating in high temperature environment without loss of the basic properties

Box2Mask: Weakly Supervised 3D Semantic Instance Segmentation Using Bounding Boxes

Current 3D segmentation methods heavily rely on large-scale point-cloud datasets, which are notoriously laborious to annotate. Few attempts have been made to circumvent the need for dense per-point annotations. In this work, we look at weakly-supervised 3D semantic instance segmentation. The key idea is to leverage 3D bounding box labels which are easier and faster to annotate. Indeed, we show that it is possible to train dense segmentation models using only bounding box labels. At the core of our method, \name{}, lies a deep model, inspired by classical Hough voting, that directly votes for bounding box parameters, and a clustering method specifically tailored to bounding box votes. This goes beyond commonly used center votes, which would not fully exploit the bounding box annotations. On ScanNet test, our weakly supervised model attains leading performance among other weakly supervised approaches (+18 mAP@50). Remarkably, it also achieves 97% of the mAP@50 score of current fully supervised models. To further illustrate the practicality of our work, we train Box2Mask on the recently released ARKitScenes dataset which is annotated with 3D bounding boxes only, and show, for the first time, compelling 3D instance segmentation masks.Comment: Project page: https://virtualhumans.mpi-inf.mpg.de/box2mask

Description of the test cases

The high-level objective of MARS project was to understand the formation and behaviour of turbulent structures which affects the Reynolds stress and skin friction. The aim was, once understood, to apply flow control techniques in order to control these structures and reduce the overall drag derived from the Reynolds stress and mainly from the skin friction. Active flow control devices were the main interest; DBD plasma, Synthetic jets, Micro Blowing and Suction, Moving Surfaces were included on the list. To test all these devices, two test cases were defined, and a database and file repository were established in the project webserver. The present chapter is aimed to describe the test cases, including the set-up of the flow control devices, as well as to describe the file repository were all the data was stored.Peer ReviewedPostprint (author's final draft

Chromium carbide growth at low temperature by a highly efficient DLI-MOCVD process in effluent recycling mode

The effect of direct recycling of effluents on the quality of CrxCy coatings grown by MOCVD using direct liquid injection (DLI) of bis(ethylbenzene)chromium(0) in toluene was investigated. The results are compared with those obtained using non-recycled solutions of precursor. Both types of coatings exhibit the same features. They are amorphous in the temperature range 673–823 K. They exhibit a dense and glassy-like microstructure and a high hardness (> 23 GPa). Analyses at the nanoscale revealed a nanocomposite microstructure consisting of free-C domains embedded in an amorphous Cr7C3 matrix characterized by strong interfaces and leading to an overall composition slightly higher than Cr7C3. The stiffness and strength of these interfaces are mainly due to at least two types of chemical bonds between Cr atoms and free-C: (i) Cr intercalation between graphene sheets and(ii) hexahapto η6-Cr bonding on the external graphene sheets of the free-C domains. The density of these interactions was found increasing by decreasing the concentration of the injected solution, as this occurred using a recycled solution. As a result, “recycled” coatings exhibit a higher nanohardness (29 GPa) than “new” coatings (23 GPa). This work demonstrates that using bis(arene)M(0) precursors, direct recycling of effluents is an efficient route to improve the conversion yield of DLI-MOCVD process making it cost-effective and competitive to produce protective carbide coatings of transition metals which share the same metal zero chemistry

Primary extraosseous dural chondrosarcoma: a case report

Background: Dural chondrosarcoma is a very rare intracranial tumor, given that meninges do not normally contain cartilaginous tissue from which it can originate. We present a case of primary extraosseous dural chondrosarcoma. Case presentation: A 48-year-old woman presented to our tertiary center neurosurgery consultation with progressive headache, vomiting, vertigo, and gait instability of 5 months' duration. An initial brain CT revealed a large parietal mass with gross calcifications and subtle hyperostosis of the inner table. Subsequent brain MRI showed a heterogeneous expansive lesion with a honey-comb enhancement. Discussion of intra- or extra-axial location was warranted, and finally, initial presurgical suspicion of meningioma arose although some atypical imaging features were detected. The differential diagnosis included solitary fibrous tumor-hemangiopericytoma and dural metastasis. Total resection of the lesion was performed, extra-axial origin was confirmed, and pathology resulted in a primary dural chondrosarcoma. Conclusion: The importance of this case presentation lies in the unusual nature of the final diagnosis, the brief literature review and differential diagnosis with emphasis on imaging pearls, as well as the useful reminder for physicians to consider less frequent diseases when key findings do not unambiguously lead to the usual suspects

Optimization of the experimental set-up for a turbulent separated shear flow control by plasma actuator using genetic algorithms

Since 1947, when Schubauer and Skramstad established the basis of the technology with its revolutionary work about steady state tools and mechanisms for the flow management, the progress of the flow control technology and the development of devices have progressed constantly. Anyway, the applicability of such devices is limited, and only few of them have arrived to the assembly workshop. The problem is that the range of actuation is still limited. Despite their operability limitations, flow control devices are of great interest for the aeronautical industry. The number of projects investigating this technology demonstrates the relevance of in the Fluid Dynamic field. The scientific interest focus not only on the industrial applications and the improvement of the technology, but also on the deep understanding of the physical phenomena associated to the flow separation, turbulence formation associated to the final drag reduction aim. A clear example of what has been mentioned is the EC MARS research project (MARS project, FP7 project number 266326). Its objectives are aimed to a better understanding of the Reynolds Stress and turbulent flow related to both drag reduction and flow control. The research was carried out through the analysis of several flow control devices and the optimization of the parameters for some of them was an important element of the research. When solving a traditional fluid dynamics optimisation problem numerical flowanalysis are used instead of experimental ones due to their lower cost and shorter needed time for evaluation of candidate solutions. Nevertheless, in the particular case of the selected flow control plasma devices the experimental measurement of the performance of each candidate configuration has been much quicker than a numerical analysis. For this reason, the corresponding optimisation problem has been solved by coupling an evolutionary optimization algorithm with an experimental device. This paper discusses the design quality and efficiency gained by this innovative coupling.Peer ReviewedPostprint (author's final draft

Multi-input genetic algorithm for experimental optimization of the reattachment downstream of a backward-facing step with surface plasma actuator

The practical interest of flow control approaches is no more debated as flow control provides an effective mean for considerably increasing the performances of ground or air transport systems, among many others applications. Here a fundamental configuration is investigated by using non-thermal surface plasma discharge. A dielectric barrier discharge is installed at the step corner of a backward-facing step (Reh=30000, Re¿=1650). Wall pressure sensors are used to estimate the reattaching location downstream of the step. The primary objective of this paper is the coupling of a numerical optimizer with an experiment. More specifically, optimization by genetic algorithm is implemented experimentally in order to minimize the reattachment point downstream of the step model. Validation through inverse problem is firstly demonstrated. When coupled with the plasma actuator and the wall pressure sensors, the genetic algorithm finds the optimum forcing conditions with a good convergence rate, the best control design variables being in agreement with the literature that uses other types of control devices than plasma. Indeed, the minimum reattaching position is achieved by forcing the flow at the shear layer mode where a large spreading rate is obtained by increasing the periodicity of the vortex street and by enhancing the vortex pairing phenomena. At the best forcing conditions, the mean flow reattachment is reduced by 20%. This article, with its experiment-based approach, demonstrates the robustness of a single-objective multi-design optimization method, and its feasibility for wind tunnel experiments.Postprint (published version

Experimental optimization by genetic algorithm for flow separation control with surface plasma actuator

Postprint (published version

Drag reduction via turbulent boundary layer flow control

The final publication is available at Springer via http://dx.doi.org/10.1007/s11431-016-9013-6Turbulent boundary layer control (TBLC) for skin-friction drag reduction is a relatively new technology made possible through the advances in computational-simulation capabilities, which have improved the understanding of the flow structures of turbulence. Advances in micro-electronic technology have enabled the fabrication of active device systems able to manipulating these structures. The combination of simulation, understanding and micro-actuation technologies offers new opportunities to significantly decrease drag, and by doing so, to increase fuel efficiency of future aircraft. The literature review that follows shows that the application of active control turbulent skin-friction drag reduction is considered of prime importance by industry, even though it is still at a low technology readiness level (TRL). This review presents the state of the art of different technologies oriented to the active and passive control for turbulent skin-friction drag reduction and contributes to the improvement of these technologies.Peer ReviewedPostprint (author's final draft