Using the equivalent fiber approach in two-scale modeling of the elastic behavior of carbon nanotube/epoxy nanocomposite

In this study, the mechanical behavior of epoxy/carbon nanotubes (CNTs) nanocomposite is predicated by a two-scale modeling approach. At the nanoscale, a CNT, the interface between the CNT and the matrix and a layer of the matrix around the CNT are modeled and the elastic behavior of the equivalent fiber (EF) has been identified. The CNT/epoxy interface behavior is modeled by the Park-Paulino-Roesler (PPR) potential. At the microscale, the EFs are embedded in the matrix with the extracted elastic properties from the nanoscale model. The random pattern has been used for the dispersing of EFs in the representative volume element (RVE). The effect of CNTs agglomeration in the epoxy matrix has also been investigated at the micro level. The Young's modulus of the nanocomposite was extracted from simulation of the RVE. CNT/epoxy nanocomposites at four different volume fractions were manufactured and the modeling results were validated by tensile tests. The results of the numerical models are in good agreement with the experiments and micromechanics theory, and by considering agglomeration of CNT in the model, the modeling results match with the experiments

On the factors driving upper-ocean salinity variability at the western edge of the Eastern Pacific Fresh Pool

© The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Farrar, J. T., & Plueddemann, A. J. On the factors driving upper-ocean salinity variability at the western edge of the Eastern Pacific Fresh Pool. Oceanography, 32(2), (2019):30-39, doi:10.5670/oceanog.2019.209.The tropical Eastern Pacific Fresh Pool (EPFP) has some of the highest precipitation rates and lowest sea surface salinities found in the open ocean. In addition, the sea surface salinity in the EPFP exhibits one of the strongest annual cycles in the world ocean. The region is strongly affected by the meridionally migrating Intertropical Convergence Zone and is also influenced by large-scale ocean currents and wind-driven Ekman currents. Recognizing the complexity of competing regional influences and the importance of sea surface salinity as an integrator of freshwater forcing, the Salinity Processes Upper-ocean Regional Study (SPURS) was undertaken to better understand how ocean processes and surface freshwater fluxes set surface salinity. Instrumentation on a surface mooring, deployed for 14 months near the western edge of the EPFP, allowed estimation of the surface fluxes of momentum, heat, and freshwater. Subsurface instrumentation on the mooring provided upper-ocean vertical structure and horizontal currents. These observations, along with horizontal gradients of surface salinity from the Soil Moisture Active Passive (SMAP) satellite instrument, were used to estimate the surface-layer salinity budget at the western edge of the EPFP. While the low salinity associated with the presence of the EPFP at the mooring site was sustained by heavy rainfall, it was found that seasonal variability in large-scale currents was important to controlling the transition between the “salty” and “fresh” seasons. Ekman advection was important to prolonging local high salinity as rainfall decreased. Although illuminating some key processes, the temporal variability of the surface-layer salinity budget also shows significant complexity, with processes such as surface freshwater fluxes and vertical mixing making notable contributions. The surface flux term and the terms involving mixing across the base of the surface layer oppose and nearly cancel each other throughout the deployment, such that the horizontal advection term effectively accounts for most of the variability in surface salinity at the site on monthly to seasonal timescales. Further investigation, taking advantage of additional observations during SPURS-2, will be needed to more thoroughly examine the relevant physical processes.We are grateful for helpful comments on the manuscript from guest editor Andrey Shcherbina and two anonymous reviewers. We thank the members of the WHOI Upper Ocean Processes Group (Ben Pietro, Emerson Hasbrouck, Raymond Graham, Nan Galbraith, Kelan Huang, Sebastien Bigorre, Ben Greenwood, Jason Smith, Geoff Allsup, and Bob Weller) for their contributions to preparation, deployment, and recovery of the SPURS-2 surface mooring. We thank the captains and crews of R/V Roger Revelle and R/V Thomas Thompson, and the chief scientists for the deployment and recovery cruises (Andy Jessup and Kyla Drushka). SMAP salinity data are produced by Remote Sensing Systems and sponsored by the NASA Ocean Salinity Science Team (data are available at http://www.remss.com). This work was supported by NASA grants NNX15AG20G and 80NSSC18K1494. The buoy and mooring data will soon be available from the NASA JPL PO.DAAC data center

Atmospheric and offshore forcing of temperature variability at the shelf break

Author Posting. © The Oceanography Society, 2018. This article is posted here by permission of The Oceanography Society for personal use, not for redistribution. The definitive version was published in Oceanography 31, no. 1 (2018): 72–79, doi:10.5670/oceanog.2018.112.Knowledge of heat balance and associated temperature variability in the Northwest Atlantic coastal ocean is important for understanding impacts of climate change such as how ocean warming will affect the management of fisheries. Heat balances are particularly complicated near the edge of the continental shelf, where the cross-shelf temperature gradients within the shelf-break front complicate the competing influences of air-sea flux anomalies versus ocean advection. We review the atmospheric and oceanic processes associated with heat balance over the Northwest Atlantic continental shelf and slope, with an emphasis on the scale-dependent nature of the heat balance. We then use data from the Ocean Observatories Initiative (OOI) Pioneer Array to demonstrate heat balance scale dependence at the southern New England shelf break, and the capability of the array to capture multiscale ocean processes. Comparison of the cumulative effects of air-sea heat fluxes measured at the OOI Pioneer Array from May 2015 to April 2016 with the actual temperature change shows the importance of advective processes in overall heat balance near the shelf break.KC was partially supported by the National Science Foundation under grant OCE-1435602 and OCE- 1634094. GG was supported by the National Science Foundation under grant OCE-1657853. AP was supported by the National Science Foundation through the Cooperative Agreement (subaward) SA9-10 from the Consortium for Ocean Leadership to the Woods Hole Oceanographic Institution

XPS and AFM study of interaction of organosilane and sizing with e-glass fibre surface

Organosilanes are often used in commercial sizings for glass fibres to provide wettability with the resin and promote strong interfacial adhesion to the matrix in a fibre reinforced polymer composite. The silane treatment is introduced as part of a complex deposition from an aqueous emulsion immediately at the spinaret and determines the optimum properties of the cured composite. To understand the interaction of organosilanes contained in sizings for glass surfaces, XPS was used to investigate the adsorption of γ-aminopropyltriethoxysilane (APS) from a simple sizing system containing a polyurethane (PU) film former. It has been found that both APS and the sizing (containing APS and PU) deposits on E-glass fibre surfaces contained components of differing hydrolytic stability. The differences observed in the AFM images of APS coated E-glass fibres before and after water extraction also confirmed that the APS deposit contained components with different water solubility

Chemical Bonding Technology: Direct Investigation of Interfacial Bonds

This is the third Flat-Plate Solar Array (FSA) Project document reporting on chemical bonding technology for terrestrial photovoltaic (PV) modules. The impetus for this work originated in the late 1970s when PV modules employing silicone encapsulation materials were undergoing delamination during outdoor exposure. At that time, manufacturers were not employing adhesion promoters and, hence, module interfaces in common with the silicone materials were only in physical contact and therefore easily prone to separation if, for example, water were to penetrate to the interfaces. Delamination with silicone materials virtually vanished when adhesion promoters, recommended by silicone manufacturers, were used. The activities related to the direct investigation of chemically bonded interfaces are described

Inhibited upper ocean restratification in nonequilibrium swell conditions

Author Posting. © American Geophysical Union, 2013. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 40 (2013): 3672–3676, doi:10.1002/grl.50708.Diurnal restratification of the ocean surface boundary layer (OSBL) represents a competition between mixing of the OSBL and solar heating. Langmuir turbulence (LT) is a mixing process in the OSBL, driven by wind and surface waves, that transfers momentum, heat, and mass. Observations in nonequilibrium swell conditions reveal that the OSBL does not restratify despite low winds and strong solar radiation. Motivated by observations, we use large-eddy simulations of the wave-averaged Navier-Stokes equations to show that LT is capable of inhibiting diurnal restratification of the OSBL. Incoming heat is redistributed vertically by LT, forming a warmer OSBL with a nearly uniform temperature. The inhibition of restratification is not reproduced by two common Reynolds-averaged Navier-Stokes equation models, highlighting the importance of properly representing sea-state dependent LT dynamics in OSBL models.This work was supported by the U.S. National Science Foundation (Grant OCE-1130678).2014-01-3

The Northwest Tropical Atlantic Station (NTAS) : NTAS-14 mooring turnaround cruise report

The Northwest Tropical Atlantic Station (NTAS) was established to address the need for accurate air-sea flux estimates and upper ocean measurements in a region with strong sea surface temperature anomalies and the likelihood of significant local air-sea interaction on interannual to decadal timescales. The approach is to maintain a surface mooring outfitted for meteorological and oceanographic measurements at a site near 15°N, 51°W by successive mooring turnarounds. These observations are used to investigate air-sea interaction processes related to climate variability. The NTAS Ocean Reference Station (ORS NTAS) is supported by the National Oceanic and Atmospheric Administration’s (NOAA) Climate Observation Program. This report documents recovery of the NTAS-13 mooring and deployment of the NTAS-14 mooring at the same site. Both moorings used Surlyn foam buoys as the surface element. These buoys were outfitted with two Air-Sea Interaction Meteorology (ASIMET) systems. Each system measures, records, and transmits via Argos satellite the surface meteorological variables necessary to compute air-sea fluxes of heat, moisture and momentum. The upper 160 m of the mooring line were outfitted with oceanographic sensors for the measurement of temperature, salinity and velocity. The mooring turnaround was done by the Upper Ocean Processes Group of the Woods Hole Oceanographic Institution (WHOI), onboard R/V Endeavor, Cruise EN549. The cruise took place between December 5 and 21 December 2014. The NTAS-14 mooring was deployed on December 13, and immediately followed by a 36-hour intercomparison period during which data from the buoy, telemetered through Argos satellite system, and the ship’s meteorological and oceanographic data were monitored. The NTAS-13 buoy had parted on September 23 and was recovered on October 28 while drifting freely near Martinique. The rest of the mooring, which had fallen to the seafloor was recovered during EN549, on December 17. This report describes these operations, as well as other work done on the cruise and some of the pre-cruise buoy preparations. Other operations during EN549 consisted in the recovery and deployment of Pressure Inverted Echo Sounders (PIES) and the acoustic download of data from PIES and subsurface moorings that are part of the Meridional Overturning Variability Experiment (MOVE) array. MOVE is designed to monitor the integrated deep meridional flow in the tropical North Atlantic. Two Argo floats were also deployed during the cruise on behalf of the Argo group at WHOI.Funding was provided by the National Oceanic and Atmospheric Administration under Grant No. NA14OAR4320158

Latitudinal dependence of wind-induced near-inertial energy

Mid-latitude storms, accounting for the majority of wind energy input to near-inertial motions in the ocean, are known to shift their track significantly from one year to another. The consequence of such storm track shifts on wind-induced near-inertial energy (NIE) is yet unknown. Here, the latitudinal dependence of wind-induced NIE is first analysed in the framework of the slab model and then tested using two numerical ocean models. It is found that the NIE input by pure inertial wind stress forcing, which dominates the wind energy input to near-inertial motions, is independent of latitude. As a consequence, the NIE generated by white-noise wind stress forcing is also latitudinally independent. In contrast, the NIE generated by red-noise wind stress forcing shows strong dependence on latitude owing to longer inertial periods at lower latitudes capable of sampling greater inertial wind stress forcing. Given that the observed surface wind stress spectra are red, results from this study suggest that an equatorward shift of the storm track is likely to result in an increase in wind-induced NIE in the ocean, while the opposite is true for a poleward shift

Linking glacially modified waters to catchment-scale subglacial discharge using autonomous underwater vehicle observations

© The Author(s), 2016. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Cryosphere 10 (2016): 417-432, doi:10.5194/tc-10-417-2016.Measurements of near-ice (<  200 m) hydrography and near-terminus subglacial hydrology are lacking, due in large part to the difficulty in working at the margin of calving glaciers. Here we pair detailed hydrographic and bathymetric measurements collected with an autonomous underwater vehicle as close as 150 m from the ice–ocean interface of the Saqqarliup sermia–Sarqardleq Fjord system, West Greenland, with modeled and observed subglacial discharge locations and magnitudes. We find evidence of two main types of subsurface glacially modified water (GMW) with distinct properties and locations. The two GMW locations also align with modeled runoff discharged at separate locations along the grounded margin corresponding with two prominent subcatchments beneath Saqqarliup sermia. Thus, near-ice observations and subglacial discharge routing indicate that runoff from this glacier occurs primarily at two discrete locations and gives rise to two distinct glacially modified waters. Furthermore, we show that the location with the largest subglacial discharge is associated with the lighter, fresher glacially modified water mass. This is qualitatively consistent with results from an idealized plume model.Support was provided by the National Science Foundation’s Office of Polar Programs (NSF-OPP) through PLR-1418256 to F. Straneo, S. B. Das and A. J. Plueddemann, PLR-1023364 to S. B. Das, and through the Woods Hole Oceanographic Institution Ocean and Climate Change Institute Arctic Research Initiative to F. Straneo, S. B. Das, and A. J. Plueddemann. L. A. Stevens was also supported by a National Science Foundation Graduate Research Fellowship. S. B. Das was also supported by the Woods Hole Oceanographic Institution James E. and Barbara V. Moltz Research Fellowship. M. Morlighem was supported by the National Aeronautics and Space Administration’s (NASA) Cryospheric Sciences Program through NNX15AD55G

Phytoplankton bloom phenomena in the North Atlantic Ocean and Arabian Sea

Author Posting. © The Author(s), 2014. This is the author's version of the work. It is posted here by permission of International Council for the Exploration of the Sea for personal use, not for redistribution. The definitive version was published in ICES Journal of Marine Science 72 (2015): 2021-2028, doi:10.1093/icesjms/fsu241.We review bio-optical and physical data from three mooring experiments, the Marine Light–Mixed Layers programme in spring 1989 and 1991 in the Iceland Basin (59°N/21°W), and the Forced Upper Ocean Dynamics Experiment in the central Arabian Sea from October 1994 to 1995 (15.5°N/61.5°E). In the Iceland Basin, from mid-April to mid-June in 1989, chlorophyll-a concentrations are sensitive to small changes in stratification, with intermittent increases early in the record. The spring increase occurs after 20 May, coincident with persistent water column stratification. In 1991, the bloom occurs 2 weeks earlier than in 1989, with a background of strong short-term and diurnal variability in mixed layer depth and minimal horizontal advection. In the Arabian Sea, the mixing response to the northeast and southwest monsoons, plus the response to mesoscale eddies, produces four blooms over the annual cycle. The mixed layer depth in the Arabian Sea never exceeds the euphotic zone, allowing interactions between phytoplankton and grazer populations to become important. For all three mooring experiments, change in water column stratification is key in producing phytoplankton blooms.2016-01-0