1,220 research outputs found
A Comprehensive Emission Inventory of Bbiogenic Volatile Organic Compounds in Europe: Improved Seasonality and Land-cover
Biogenic volatile organic compounds (BVOC) emitted from vegetation are important for the formation of secondary pollutants such as ozone and secondary organic aerosols (SOA) in the atmosphere. Therefore, BVOC emission are an important input for air quality models. To model these emissions with high spatial resolution, the accuracy of the underlying vegetation inventory is crucial. We present a BVOC emission model that accommodates different vegetation inventories and uses satellite-based measurements of greenness instead of pre-defined vegetation periods. This approach to seasonality implicitly treats effects caused by water or nutrient availability, altitude and latitude on a plant stand. Additionally, we test the influence of proposed seasonal variability in enzyme activity on BVOC emissions. In its present setup, the emission model calculates hourly emissions of isoprene, monoterpenes, sesquiterpenes and the oxygenated volatile organic compounds (OVOC) methanol, formaldehyde, formic acid, ethanol, acetaldehyde, acetone and acetic acid. In this study, emissions based on three different vegetation inventories are compared with each other and diurnal and seasonal variations in Europe are investigated for the year 2006. Two of these vegetation inventories require information on tree-cover as an input. We compare three different land-cover inventories (USGS GLCC, GLC2000 and Globcover 2.2) with respect to tree-cover. The often-used USGS GLCC land-cover inventory leads to a severe reduction of BVOC emissions due to a potential miss-attribution of broad-leaved trees and reduced tree-cover compared to the two other land-cover inventories. To account for uncertainties in the land-cover classification, we introduce land-cover correction factors for each relevant land-use category to adjust the tree-cover. The results are very sensitive to these factors within the plausible range. For June 2006, total monthly BVOC emissions decreased up to â27% with minimal and increased up to +71% with maximal factors, while in January 2006, the changes in monthly BVOC emissions were â54 and +56% with minimal and maximal factors, respectively. The new seasonality approach leads to a reduction in the annual emissions compared with non-adjusted data. The strongest reduction occurs in OVOC (up to â32 %), the weakest in isoprene (as little as â19 %). If also enzyme seasonality is taken into account, however, isoprene reacts with the steepest decrease of annual emissions, which are reduced by â44% to â49 %, annual emissions of monoterpenes reduce between â30 and â35 %. The sensitivity of the model to changes in temperature depends on the climatic zone but not on the vegetation inventory. The sensitivity is higher for temperature increases of 3K (+31% to +64 %) than decreases by the same amount (â20 to â35 %). The climatic zones âCold except summerâ and âaridâ are most sensitive to temperature changes in January for isoprene and monoterpenes, respectively, while in June, âpolarâ is most sensitive to temperature for both isoprene and monoterpenes. Our model predicts the oxygenated volatile organic compounds to be the most abundant fraction of the annual European emissions (3571â5328 Gg yrâ1), followed by monoterpenes (2964â4124 Gg yrâ1), isoprene (1450â2650 Gg yrâ1) and sesquiterpenes (150â257 Gg yrâ1). We find regions with high isoprene emissions (most notably the Iberian Peninsula), but overall, oxygenated VOC dominate with 43â45% (depending on the vegetation inventory) contribution to the total annual BVOC emissions in Europe. Isoprene contributes between 18â21 %, monoterpenes 33â36% and sesquiterpenes contribute 1â2 %.We compare the concentrations of biogenic species simulated by an air quality model with measurements of isoprene and monoterpenes in Hohenpeissenberg (Germany) for both summer and winter. The agreement between observed and modelled concentrations is better in summer than in winter. This can partly be explained with the difficulty to model weather conditions in winter accurately, but also with the increased anthropogenic influence on the concentrations of BVOC compounds in winter. Our results suggest that land-cover inventories used to derive tree-cover must be chosen with care. Also, uncertainties in the classification of land-cover pixels must be taken into account and remain high. This problem must be addressed together with the remote sensing community. Our new approach using a greenness index for addressing seasonality of vegetation can be implemented easily in existing models. The importance of OVOC for air quality should be more deeply addressed by future studies, especially in smog chambers. Also, the fate of BVOC from the dominant region of the Iberian Peninsula should be studied more in detail
Production Mechanism of C2-C4 Hydrocarbons in Sea Water: Field Measurements and Experiment
The production mechanism of light nonmethane hydrocarbons (NMHC) in seawater was investigated during the North Atlantic atmospheric chemistry program (NATAC) in April and May 1991 in the European coastal seas and the North Atlantic. A significant alkene production occurred in the presence of light only. Under conditions of negligible NMHC emissions (low wind velocity) increasing hydrocarbon concentrations were observed during daytime, whereas the concentrations remained constant during night. NMHC formation experiments were carried out with seawater filled in quartz glass bottles and showed the same dependence of light. Experiments with differently pretreated seawater samples indicated that the presence of dissolved organic material (DOM) is also necessary for alkene production. We suggest a two-step production mechanism for alkenes: first DOM is released, probably from algae, then part of this material is photochemically transformed into alkenes. The production rates in the quartz glass bottles were comparable to the production rates in the ocean surface. This indicates that the processes occurring in the experimental setups represent the processes occurring in the field. Since the production - and emission rates were in the same range it can be concluded that the budget of light alkenes in the remote marine environment is determined by the production in seawater as the dominant source and the flux into the atmosphere as the main loss process
Dissipative Field Theory with Caldeira-Leggett Method and its Application to Disoriented Chiral Condensation
The effective field theory including the dissipative effect is developed
based on the Caldeira-Leggett theory at the classical level. After the
integration of the small field fluctuations considered as the field radiation,
the integro-differential field equation is given and shown to include the
dissipative effects. In that derivation, special cares should be taken for the
boundary condition of the integration. Application to the linear sigma model is
given, and the decay process of the chiral condensate is calculated with it,
both analytically in the linear approximation and numerically. With these
results, we discuss the stability of chiral condensates within the quenched
approximation.Comment: 16pages, ReV-Te
Schottky mass measurements of heavy neutron-rich nuclides in the element range 70\leZ \le79 at the ESR
Storage-ring mass spectrometry was applied to neutron-rich Au
projectile fragments. Masses of Lu, Hf, Ta,
W, and Re nuclei were measured for the first time. The
uncertainty of previously known masses of W and Os nuclei
was improved. Observed irregularities on the smooth two-neutron separation
energies for Hf and W isotopes are linked to the collectivity phenomena in the
corresponding nuclei.Comment: 10 pages, 9 figures, 2 table
Collaboration scripts - a conceptual analysis
This article presents a conceptual analysis of collaboration scripts used in face-to-face and computer-mediated collaborative learning. Collaboration scripts are scaffolds that aim to improve collaboration through structuring the interactive processes between two or more learning partners. Collaboration scripts consist of at least five components: (a) learning objectives, (b) type of activities, (c) sequencing, (d) role distribution, and (e) type of representation. These components serve as a basis for comparing prototypical collaboration script approaches for face-to-face vs. computer-mediated learning. As our analysis reveals, collaboration scripts for face-to-face learning often focus on supporting collaborators in engaging in activities that are specifically related to individual knowledge acquisition. Scripts for computer-mediated collaboration are typically concerned with facilitating communicative-coordinative processes that occur among group members. The two lines of research can be consolidated to facilitate the design of collaboration scripts, which both support participation and coordination, as well as induce learning activities closely related to individual knowledge acquisition and metacognition. In addition, research on collaboration scripts needs to consider the learnersâ internal collaboration scripts as a further determinant of collaboration behavior. The article closes with the presentation of a conceptual framework incorporating both external and internal collaboration scripts
Stochastic Theory of Relativistic Particles Moving in a Quantum Field: II. Scalar Abraham-Lorentz-Dirac-Langevin Equation, Radiation Reaction and Vacuum Fluctuations
We apply the open systems concept and the influence functional formalism
introduced in Paper I to establish a stochastic theory of relativistic moving
spinless particles in a quantum scalar field. The stochastic regime resting
between the quantum and semi-classical captures the statistical mechanical
attributes of the full theory. Applying the particle-centric world-line
quantization formulation to the quantum field theory of scalar QED we derive a
time-dependent (scalar) Abraham-Lorentz-Dirac (ALD) equation and show that it
is the correct semiclassical limit for nonlinear particle-field systems without
the need of making the dipole or non-relativistic approximations. Progressing
to the stochastic regime, we derive multiparticle ALD-Langevin equations for
nonlinearly coupled particle-field systems. With these equations we show how to
address time-dependent dissipation/noise/renormalization in the semiclassical
and stochastic limits of QED. We clarify the the relation of radiation
reaction, quantum dissipation and vacuum fluctuations and the role that initial
conditions may play in producing non-Lorentz invariant noise. We emphasize the
fundamental role of decoherence in reaching the semiclassical limit, which also
suggests the correct way to think about the issues of runaway solutions and
preacceleration from the presence of third derivative terms in the ALD
equation. We show that the semiclassical self-consistent solutions obtained in
this way are ``paradox'' and pathology free both technically and conceptually.
This self-consistent treatment serves as a new platform for investigations into
problems related to relativistic moving charges.Comment: RevTex; 20 pages, 3 figures, Replaced version has corrected typos,
slightly modified derivation, improved discussion including new section with
comparisons to related work, and expanded reference
Global methylation profiling of lung cancer identifies novel methylated genes
Epigenetic changes, including DNA methylation, are a common finding in cancer. In lung cancers methylation of cytosine residues may affect tumor initiation and progression in several ways, including the silencing of tumor suppressor genes through promoter methylation and by providing the targets for adduct formation of polycyclic aromatic hydrocarbons present in combustion products of cigarette smoke. Although the importance of aberrant DNA methylation is well established, the extent of DNA methylation in lung cancers has never been determined. Restriction landmark genomic scanning (RLGS) is a highly reproducible two-dimensional gel electrophoresis that allows the determination of the methylation status of up to 2000 promoter sequences in a single gel. We selected 1184 CpG islands for RLGS analysis and determined their methylation status in 16 primary non-small cell lung cancers. Some tumors did not show methylation whereas others showed up to 5.3% methylation in all CpG islands of the profile. Cloning of 21 methylated loci identified 11 genes and 6 ESTs. We demonstrate that methylation is part of the silencing process of BMP3B in primary tumors and lung cancer cell lines
3D characterization of CdSe nanoparticles attached to carbon nanotubes
The crystallographic structure of CdSe nanoparticles attached to carbon
nanotubes has been elucidated by means of high resolution transmission electron
microscopy and high angle annular dark field scanning transmission electron
microscopy tomography. CdSe rod-like nanoparticles, grown in solution together
with carbon nanotubes, undergo a morphological transformation and become
attached to the carbon surface. Electron tomography reveals that the
nanoparticles are hexagonal-based with the (001) planes epitaxially matched to
the outer graphene layer.Comment: 7 pages, 8 figure
RNAi technology and its use in studying the function of nuclear receptors and coregulators
Until just a few years ago, RNA interference (RNAi) technology was restricted to the research fields of plants, C. elegans or Drosophila. The discovery of gene silencing by in vitro synthesized double-stranded RNA (dsRNA) in mammalian cells has made the use of RNAi possible in nearly the entire life science kingdom. DNA vectors delivering small interfering RNA (siRNA) directed by polymerase III or polymerase II promoters to persistently inhibit target genes expression have extended this technology to study in vivo function of these genes. Recently, RNAi has been used as a powerful tool in the functional analysis of nuclear receptors and their coregulators. This short review will cover studies in this area
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