Structure of ll- VI Lattice Mismatched Epilayers used for Blue-Green Lasers for Underwater Communication

Critical thickness (hc) is calculated for capped and uncapped lattice mismatched II-VIsemiconductor epilayers. Both the old equilibrium theory and the improved theory have been used.The calculated values are compared with the experimental data on epilayers of several II-VIsemiconductors and alloys. The observed values of hc are larger than the calculated values. Howeverthe discrepancy is much smaller than that found in InGaAs/GaAs and GeSilSi layers. Moreover ascompared to InGaAs/GaA.s:a nd GeSilSi layers, the experimental data show a much smaller scatter andcan be fitted with one curve. Strain relaxation in layers with thickness h > hc is also calculated. Strainrelaxation in ZnSe layers grown on (100) GaAs shows good agreement with the equilibrium theory. Inother cases the observed relaxation is sluggish, the residual strain is larger than its calculated value.Thick highly mismatched layers behave differently. The residual strain agrees with theory anddislocations are distributed periodically, A model to interpret these observations is suggested.Implications of this study on the stability of 11V- I strained layers are discussed

A New Global Ocean Climatology

A new global ocean temperature and salinity climatology is proposed for two time periods: a long time mean using multiple sensor data for the 1900–2017 period and a shorter time mean using only profiling float data for the 2003–2017 period. We use the historical database of World Ocean Database 2018. The estimation approach is novel as an additional quality control procedure is implemented, along with a new mapping algorithm based on Data Interpolating Variational Analysis. The new procedure, in addition to the traditional quality control approach, resulted in low sensitivity in terms of the first guess field choice. The roughness index and the root mean square of residuals are new indices applied to the selection of the free mapping parameters along with sensitivity experiments. Overall, the new estimates were consistent with previous climatologies, but several differences were found. The cause of these discrepancies is difficult to identify due to several differences in the procedures. To minimise these uncertainties, a multi-model ensemble mean is proposed as the least uncertain estimate of the global ocean temperature and salinity climatology

Ocean ensemble forecasting. Part I: Ensemble Mediterranean winds from a Bayesian hierarchical model

A Bayesian hierarchical model (BHM) is developed to estimate surface vector wind (SVW) fields and associated uncertainties over the Mediterranean Sea. The BHM–SVW incorporates data-stage inputs from analyses and forecasts of the European Centre for Medium-Range Weather Forecasts (ECMWF) and SVW retrievals from the QuikSCAT data record. The process-model stage of the BHM–SVW is based on a Rayleigh friction equation model for surface winds. Dynamical interpretations of posterior distributions of the BHM–SVW parameters are discussed. Ten realizations from the posterior distribution of the BHM–SVW are used to force the data-assimilation step of an experimental ensemble ocean forecast system for the Mediterranean Sea in order to create a set of ensemble initial conditions. The sequential data-assimilation method of the Mediterranean forecast system (MFS) is adapted to the ensemble implementation. Analyses of sample ensemble initial conditions for a single data-assimilation period in MFS are presented to demonstrate the multivariate impact of the BHM–SVW ensemble generation methodology. Ensemble initial-condition spread is quantified by computing standard deviations of ocean state variable fields over the ten ensemble members. The methodological findings in this article are of two kinds. From the perspective of statistical modelling, the process-model development is more closely related tophysicalbalances than inpreviousworkwithmodels for the SVW.Fromthe ocean forecast perspective, the generation of ocean ensemble initial conditions via BHM is shown to be practical for operational implementation in an ensemble ocean forecast system. Phenomenologically, ensemble spread generated via BHM–SVW occurs on ocean mesoscale time- and space-scales, in close association with strong synoptic-scale wind-forcing events. A companion article describes the impacts of the BHM–SVW ensemble method on the ocean forecast in comparisons with more traditional ensemble methods

Ocean ensemble forecasting. Part II: Mediterranean Forecast System response

This article analyzes the ocean forecast response to surface vector wind (SVW) distributions generated by a Bayesian hierarchical model (BHM) developed in Part I of this series. A new method for ocean ensemble forecasting (OEF), the socalled BHM-SVW-OEF, is described. BHM-SVW realizations are used to produce and force perturbations in the ocean state during 14 day analysis and 10 day forecast cycles of the Mediterranean Forecast System (MFS). The BHM-SVW-OEF ocean response spread is amplified at the mesoscales and in the pycnocline of the eddy field. The new method is compared with an ensemble response forced by European Centre for Medium-Range Weather Forecasts (ECMWF) ensemble prediction system (EEPS) surface winds, and with an ensemble forecast started from perturbed initial conditions derived froman ad hoc thermocline intensified random perturbation (TIRP) method. The EEPS-OEF shows spread on basin scales while the TIRP-OEF response is mesoscale-intensified as in the BHM-SVW-OEF response. TIRP-OEF perturbations fill more of the MFS domain, while the BHM-SVW-OEF perturbations are more location-specific, concentrating ensemble spread at the sites where the ocean-model response to uncertainty in the surface wind forcing is largest

Mediterranean Forecasting System: forecast and analysis assessment through skill scores

Abstract. This paper describes the first evaluation of the quality of the forecast and analyses produced at the basin scale by the Mediterranean ocean Forecasting System (MFS) (http://gnoo.bo.ingv.it/mfs). The system produces short-term ocean forecasts for the following ten days. Analyses are produced weekly using a daily assimilation cycle. The analyses are compared with independent data from buoys, where available, and with the assimilated data before the data are inserted. In this work we have considered 53 ten days forecasts produced from 16 August 2005 to 15 August 2006. The forecast skill is evaluated by means of root mean square error (rmse) differences, bias and anomaly correlations at different depths for temperature and salinity, computing differences between forecast and analysis, analysis and persistence and forecast and persistence. The Skill Score (SS) is defined as the ratio of the rmse of the difference between analysis and forecast and the rmse of the difference between analysis and persistence. The SS shows that at 5 and 30 m the forecast is always better than the persistence, but at 300 m it can be worse than persistence for the first days of the forecast. This result may be related to flow adjustments introduced by the data assimilation scheme. The monthly variability of SS shows that when the system variability is high, the values of SS are higher, therefore the forecast has higher skill than persistence. We give evidence that the error growth in the surface layers is controlled by the atmospheric forcing inaccuracies, while at depth the forecast error can be interpreted as due to the data insertion procedure. The data, both in situ and satellite, are not homogeneously distributed in the basin; therefore, the quality of the analyses may be different in different areas of the basin

Ocean Ensemble Forecasting, Part II: Mediterranean Forecast System Response

This paper analyzes the ocean forecast response to surface vector wind (SVW) distributions generated by a Bayesian Hierarchical Model (BHM) developed in Part I (Milliff et al., 2009). A new method for Ocean Ensemble Forecasting (OEF), so-called BHM-SVW-OEF, is described. BHM-SVW realizations are used to produce and force perturbations in the ocean state during 14-day analysis and 10-day forecast cycles of the Mediterranean Forecast System (MFS). The BHM-SVW-OEF ocean response spread is amplified at the mesoscales and pycnocline of the eddy field. The new method is compared to an ensemble response forced by ECMWF Ensemble Prediction System (EEPS) surface winds, and to an ensemble forecast started from perturbed initial conditions derived from an ad hoc Thermocline Intensified Random Perturbation (TIRP) method. The EEPS-OEF shows spread at the basin scales while the TIRP-OEF response is mesoscale intensified as in the BHM-SVW-OEF response. TIRP-OEF perturbations fill more of the MFS domain while the BHM-SVW-OEF perturbations are more location-specific, concentrating ensemble spread at the sites where the ocean model response to uncertainty in the surface wind forcing is largest. The BHM-SVW-OEF method offers a practical and objective means for producing short-term forecast spread by modeling surface atmospheric forcing uncertainties that have maximum impact at the ocean mesoscales

Mediterranean Forecasting System: forecast and analysis assessment through skill scores

This paper describes the first evaluation of the quality of the forecast and analyses produced at the basin scale by the Mediterranean ocean Forecasting System (MFS) (http://gnoo.bo.ingv.it/mfs). The system produces short-term ocean forecasts for the following ten days. Analyses are produced weekly using a daily assimilation cycle. The analyses are compared with independent data from buoys, where available, and with the assimilated data before the data are inserted. In this work we have considered 53 ten days forecasts produced from 16 August 2005 to 15 August 2006. The forecast skill is evaluated by means of root mean square error (rmse) differences, bias and anomaly correlations at different depths for temperature and salinity, computing differences between forecast and analysis, analysis and persistence and forecast and persistence. The Skill Score (SS) is defined as the ratio of the rmse of the difference between analysis and forecast and the rmse of the difference between analysis and persistence. The SS shows that at 5 and 30m the forecast is always better than the persistence, but at 300m it can be worse than persistence for the first days of the forecast. This result may be related to flow adjustments introduced by the data assimilation scheme. The monthly variability of SS shows that when the system variability is high, the values of SS are higher, therefore the forecast has higher skill than persistence. We give evidence that the error growth in the surface layers is controlled by the atmospheric forcing inaccuracies, while at depth the forecast error can be interpreted as due to the data insertion procedure. The data, both in situ and satellite, are not homogeneously distributed in the basin; therefore, the quality of the analyses may be different in different areas of the basin

Ordered vacancy network induced by the growth of epitaxial graphene on Pt(111)

We have studied large areas of (v3×v3)R30° graphene commensurate with a Pt(111) substrate. A combination of experimental techniques with ab initio density functional theory indicates that this structure is related to a reconstruction at the Pt surface, consisting of an ordered vacancy network formed in the outermost Pt layer and a graphene layer covalently bound to the Pt substrate. The formation of this reconstruction is enhanced if low temperatures and polycyclic aromatic hydrocarbons are used as molecular precursors for epitaxial growth of the graphene layers

Essential Constants for Spatially Homogeneous Ricci-flat manifolds of dimension 4+1

The present work considers (4+1)-dimensional spatially homogeneous vacuum cosmological models. Exact solutions -- some already existing in the literature, and others believed to be new -- are exhibited. Some of them are the most general for the corresponding Lie group with which each homogeneous slice is endowed, and some others are quite general. The characterization ``general'' is given based on the counting of the essential constants, the line-element of each model must contain; indeed, this is the basic contribution of the work. We give two different ways of calculating the number of essential constants for the simply transitive spatially homogeneous (4+1)-dimensional models. The first uses the initial value theorem; the second uses, through Peano's theorem, the so-called time-dependent automorphism inducing diffeomorphismsComment: 26 Pages, 2 Tables, latex2

A relocatable ocean model in support of environmental emergencies

During the Costa Concordia emergency case, regional, subregional, and relocatable ocean models have been used together with the oil spill model, MEDSLIK-II, to provide ocean currents forecasts, possible oil spill scenarios, and drifters trajectories simulations. The models results together with the evaluation of their performances are presented in this paper. In particular, we focused this work on the implementation of the Interactive Relocatable Nested Ocean Model (IRENOM), based on the Harvard Ocean Prediction System (HOPS), for the Costa Concordia emergency and on its validation using drifters released in the area of the accident. It is shown that thanks to the capability of improving easily and quickly its configuration, the IRENOM results are of greater accuracy than the results achieved using regional or subregional model products. The model topography, and to the initialization procedures, and the horizontal resolution are the key model settings to be configured. Furthermore, the IRENOM currents and the MEDSLIK-II simulated trajectories showed to be sensitive to the spatial resolution of the meteorological fields used, providing higher prediction skills with higher resolution wind forcing.MEDESS4MS Project; TESSA Project; MyOcean2 Projectinfo:eu-repo/semantics/publishedVersio