Interface free energy or surface tension: definition and basic properties

Interface free energy is the contribution to the free energy of a system due to the presence of an interface separating two coexisting phases at equilibrium. It is also called surface tension. The content of the paper is 1) the definition of the interface free energy from first principles of statistical mechanics; 2) a detailed exposition of its basic properties. We consider lattice models with short range interactions, like the Ising model. A nice feature of lattice models is that the interface free energy is anisotropic so that some results are pertinent to the case of a crystal in equilibrium with its vapor. The results of section 2 hold in full generality.Comment: 20 pages, 2 figure

Interface Pinning and Finite-Size Effects in the 2D Ising Model

We apply new techniques developed in a previous paper to the study of some surface effects in the 2D Ising model. We examine in particular the pinning-depinning transition. The results are valid for all subcritical temperatures. By duality we obtained new finite size effects on the asymptotic behaviour of the two-point correlation function above the critical temperature. The key-point of the analysis is to obtain good concentration properties of the measure defined on the random lines giving the high-temperature representation of the two-point correlation function, as a consequence of the sharp triangle inequality: let tau(x) be the surface tension of an interface perpendicular to x; then for any x,y tau(x)+tau(y)-tau(x+y) >= 1/kappa(||x||+||y||-||x+y||), where kappa is the maximum curvature of the Wulff shape and ||x|| the Euclidean norm of x.Comment: 34 pages, Late

Non-Analyticity and the van der Waals Limit

We study the analyticity properties of the free energy f_\ga(m) of the Kac model at points of first order phase transition, in the van der Waals limit \ga\searrow 0. We show that there exists an inverse temperature $\beta_0$ and \ga_0>0 such that for all $\beta\geq \beta_0$ and for all \ga\in(0,\ga_0), f_\ga(m) has no analytic continuation along the path $m\searrow m^*$ ($m^*$ denotes spontaneous magnetization). The proof consists in studying high order derivatives of the pressure p_\ga(h), which is related to the free energy f_\ga(m) by a Legendre transform

The metaphysics of Machian frame-dragging

The paper investigates the kind of dependence relation that best portrays Machian frame-dragging in general relativity. The question is tricky because frame-dragging relates local inertial frames to distant distributions of matter in a time-independent way, thus establishing some sort of non-local link between the two. For this reason, a plain causal interpretation of frame-dragging faces huge challenges. The paper will shed light on the issue by using a generalized structural equation model analysis in terms of manipulationist counterfactuals recently applied in the context of metaphysical enquiry by Schaffer (2016) and Wilson (2017). The verdict of the analysis will be that frame-dragging is best understood in terms of a novel type of dependence relation that is half-way between causation and grounding

A point is normal for almost all maps βx+α mod 1 or generalized β-transformations

We consider the map Tα,β(x):=βx+αmod1, which admits a unique probability measure μα,β of maximal entropy. For x[0,1], we show that the orbit of x is μα,β-normal for almost all (α,β)[0,1)×(1,∞) (with respect to Lebesgue measure). Nevertheless, we construct analytic curves in [0,1)×(1,∞) along which the orbit of x=0 is μα,β-normal at no more than one point. These curves are disjoint and fill the set [0,1)×(1,∞). We also study the generalized β-transformations (in particular, the tent map). We show that the critical orbit x=1 is normal with respect to the measure of maximal entropy for almost all

General approach for studying first-order phase transitions at low temperatures

By combining different ideas, a general and efficient protocol to deal with discontinuous phase transitions at low temperatures is proposed. For small $T$'s, it is possible to derive a generic analytic expression for appropriate order parameters, whose coefficients are obtained from simple simulations. Once in such regimes simulations by standard algorithms are not reliable, an enhanced tempering method, the parallel tempering -- accurate for small and intermediate system sizes with rather low computational cost -- is used. Finally, from finite size analysis, one can obtain the thermodynamic limit. The procedure is illustrated for four distinct models, demonstrating its power, e.g., to locate coexistence lines and the phases density at the coexistence.Comment: 5 page