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Time-resolved infrared studies of the dynamics of ligand binding to cytochrome c oxidase
Time-resolved infrared spectroscopy (TRIRS) has been employed to study the reactions of small molecules with the cytochrome a{sub 3}-Cu{sub B} site of cytochrome c oxidase (CcO). All phases of these reactions have been investigated, from ultrafast phenomena (hundreds of femtoseconds) to relatively slow processes (milliseconds). The ligation dynamics immediately following photodissociation have been studied using a TRIR technique with time resolution of less than 1 ps. The rate of photoinitiated transfer of CO from Fe{sub a3}{sup 2+} to Cu{sub B}{sup +} was measured directly by monitoring the development of the transient Cu{sub B}{sup +}-CO absorption. The development of a stationary Cu{sub B}{sup +}-CO spectrum which is constant until the CO dissociates from Cu{sub B}{sup +} occurs in less than 1 ps, indicating that the photoinitiated transfer of CO is remarkably fast. This unprecedented ligand transfer rate has profound implications with regard to the structure and dynamics of the cytochrome a{sub 3}-Cu{sub B} site, the functional architecture of the protein and coordination dynamics in general. The photodissociation and recombination of Cn{sup {minus}} has also been studied using a real-time TRIR technique. The CN{sup {minus}} recombination rate of 430 s{sup {minus}1} is consistent with a recombination pathway similar to the one they have previously proposed for CO. The authors suggest the rate determining step for CN{sup {minus}} recombination is the thermal dissociation of the Fe{sub a3}{sup 2+}-L bond. 25 refs., 7 figs
Search for the Proton Decay Mode proton to neutrino K+ in Soudan 2
We have searched for the proton decay mode proton to neutrino K+ using the
one-kiloton Soudan 2 high resolution calorimeter. Contained events obtained
from a 3.56 kiloton-year fiducial exposure through June 1997 are examined for
occurrence of a visible K+ track which decays at rest into mu+ nu or pi+ pi0.
We found one candidate event consistent with background, yielding a limit,
tau/B > 4.3 10^{31} years at 90% CL with no background subtraction.Comment: 13 pages, Latex, 3 tables and 3 figures, Accepted by Physics Letters
Extrapolating SMBH correlations down the mass scale: the case for IMBHs in globular clusters
Empirical evidence for both stellar mass black holes M_bh<10^2 M_sun) and
supermassive black holes (SMBHs, M_bh>10^5 M_sun) is well established.
Moreover, every galaxy with a bulge appears to host a SMBH, whose mass is
correlated with the bulge mass, and even more strongly with the central stellar
velocity dispersion sigma_c, the `M-sigma' relation. On the other hand,
evidence for "intermediate-mass" black holes (IMBHs, with masses in the range
1^2 - 10^5 M_sun) is relatively sparse, with only a few mass measurements
reported in globular clusters (GCs), dwarf galaxies and low-mass AGNs. We
explore the question of whether globular clusters extend the M-sigma
relationship for galaxies to lower black hole masses and find that available
data for globular clusters are consistent with the extrapolation of this
relationship. We use this extrapolated M-sigma relationship to predict the
putative black hole masses of those globular clusters where existence of
central IMBH was proposed. We discuss how globular clusters can be used as a
constraint on theories making specific predictions for the low-mass end of the
M-sigma relation.Comment: 14 pages, 3 figures, accepted for publication in Astrophysics and
Space Science; fixed typos and a quote in Sec.
The chemical enrichment of the ICM from hydrodynamical simulations
The study of the metal enrichment of the intra-cluster and inter-galactic
media (ICM and IGM) represents a direct means to reconstruct the past history
of star formation, the role of feedback processes and the gas-dynamical
processes which determine the evolution of the cosmic baryons. In this paper we
review the approaches that have been followed so far to model the enrichment of
the ICM in a cosmological context. While our presentation will be focused on
the role played by hydrodynamical simulations, we will also discuss other
approaches based on semi-analytical models of galaxy formation, also critically
discussing pros and cons of the different methods. We will first review the
concept of the model of chemical evolution to be implemented in any
chemo-dynamical description. We will emphasise how the predictions of this
model critically depend on the choice of the stellar initial mass function, on
the stellar life-times and on the stellar yields. We will then overview the
comparisons presented so far between X-ray observations of the ICM enrichment
and model predictions. We will show how the most recent chemo-dynamical models
are able to capture the basic features of the observed metal content of the ICM
and its evolution. We will conclude by highlighting the open questions in this
study and the direction of improvements for cosmological chemo-dynamical models
of the next generation.Comment: 25 pages, 11 figures, accepted for publication in Space Science
Reviews, special issue "Clusters of galaxies: beyond the thermal view",
Editor J.S. Kaastra, Chapter 18; work done by an international team at the
International Space Science Institute (ISSI), Bern, organised by J.S.
Kaastra, A.M. Bykov, S. Schindler & J.A.M. Bleeke
Access to Print in Low‐Income and Middle‐Income Communities: An Ecological Study of Four Neighborhoods
Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/88026/1/RRQ.36.1.1.pd
Measurement of beauty production in deep inelastic scattering at HERA
The beauty production cross section for deep inelastic scattering events with
at least one hard jet in the Breit frame together with a muon has been
measured, for photon virtualities Q^2 > 2 GeV^2, with the ZEUS detector at HERA
using integrated luminosity of 72 pb^-1. The total visible cross section is
sigma_b-bbar (ep -> e jet mu X) = 40.9 +- 5.7 (stat.) +6.0 -4.4 (syst.) pb. The
next-to-leading order QCD prediction lies about 2.5 standard deviations below
the data. The differential cross sections are in general consistent with the
NLO QCD predictions; however at low values of Q^2, Bjorken x, and muon
transverse momentum, and high values of jet transverse energy and muon
pseudorapidity, the prediction is about two standard deviations below the data.Comment: 18 pages, 4 figure
D* Production in Deep Inelastic Scattering at HERA
This paper presents measurements of D^{*\pm} production in deep inelastic
scattering from collisions between 27.5 GeV positrons and 820 GeV protons. The
data have been taken with the ZEUS detector at HERA. The decay channel
(+ c.c.) has been used in the study. The
cross section for inclusive D^{*\pm} production with
and is 5.3 \pms 1.0 \pms 0.8 nb in the kinematic region
{ GeV and }. Differential cross
sections as functions of p_T(D^{*\pm}), and are
compared with next-to-leading order QCD calculations based on the photon-gluon
fusion production mechanism. After an extrapolation of the cross section to the
full kinematic region in p_T(D^{*\pm}) and (D^{*\pm}), the charm
contribution to the proton structure function is
determined for Bjorken between 2 10 and 5 10.Comment: 17 pages including 4 figure
The Influence of Dormitory Architecture On Resident Behavior
Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/66943/2/10.1177_001391657300500402.pd
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