943 research outputs found

    Boundary conditions for the paleoenvironment: Chemical and physical processes in the pre-solar nebula

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    Detailed study of the first interstellar hydrocarbon ring, cyclopropenylidene (C3H2), is continuing. The singly deuterated isotope of this molecule, C3HD, was observed in several cold interstellar clouds. The results of a large survey for C3H2 in galactic sources of various types will soon be completed. It appears that cyclopropenylidene is present in virtually all interstellar clouds of at least moderate density. In order to make the first determinations of the CO2/CO abundance ratio in interstellar sources, observations of protonated CO2 were pursued. The spectrum from 18.5 to 22 GHz for several interstellar clouds is being systematically measured. Particular attention is being given to the cold, dark clouds TMC-1 and L124N, which may be formation sites for solar mass stars. The phenomena of maser emission from molecules of methanol is being studied in certain interstellar clouds. A comparison of 1 millimeter continuum emission from dust with the column density of carbon monoxide as determined from the rare C(18)O isotope for 4 molecular clouds in the Galaxy is nearing completion. Papers published during the period of this report are listed

    Transforming the public sector:1998-2018

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    The purpose of this paper is to provide an evaluation of public sector research in the 1998–2018 period. Design/methodology/approach The paper uses the extant literature of this era to study the theorisation of, and the findings of, public sector research. Findings This is a vibrant field of a study in a wide range of study settings and with many interdisciplinary studies. The influence of new public management is pervasive over this period. There are numerous instances of innovations in study settings, in key findings and the approach taken by investigators. Research limitations/implications This is not a comprehensive review of all literature in this period. Practical implications This study also explored the relevance of academic research of this era to policymaking by governments. Originality/value This paper offers a distinctive critique of theorisation of public sector accounting research. It reveals the dominant theoretical reference points in use during this period and observes the increasing tendency for theoretical pluralism to investigate complex study settings

    Reframing Resolution - Managing Conflict and Resolving Individual Employment Disputes in the Contemporary Workplace

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    The resolution of individual workplace conflict has assumed an increasingly important place in policy debates over contemporary work and employment. This is in part due to the decline in collective industrial action and the parallel rise in the volume of employment tribunal applications. It reflects a growing concern over the implications of individual employment disputes for those involved but has perhaps been driven by concerns over the cost of litigation and the perceived burden that this places on employers. Against this backdrop, an ESRC-funded seminar series, entitled ‘Reframing Resolution – Managing Conflict and Resolving Individual Employment Disputes in the Contemporary Workplace’, was held between October 2012 and September 2013. This comprised six seminars held at: University of Strathclyde; University of Central Lancashire; Swansea University; Queen’s University Belfast; IRRU, University of Warwick and University of Westminster. The series brought leading academic researchers, practitioners and policy-makers together to explore new empirical and conceptual developments, examine innovative practice and provide insights into key questions of public policy

    Boundary conditions for the paleoenvironment: Chemical and physical processes in the pre-solar nebula

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    In observations with the NRAO 12m telescope at Kitt Peak, Arizona, Irvine, a new interstellar radical, CH2N, has been detected. This identification is important for the study of hydrogenation processes in the interstellar medium. In particular, although the abundance of hydrogen is some four orders of magnitude higher than that of other reactive elements in this environment, many organic molecules in quiescent clouds are very unsaturated. This is a consequence of activation barriers which cannot be overcome at the temperatures of cold clouds, even when such reactions are energetically allowed. The hydrogenation series based on the cyanide radical (HnCN) has had four members previously detected in the interstellar medium: CN (n equals O), HCN (n equals l), CH2CN (n equals 3), and CH3NH2 (n equals 5). The recent determination of the rotational spectrum of the CH2N radical through microwave spectroscopy in Japan has made possible a search for this species. In addition to its potential importance for interstellar chemistry, the CH2N radical has been proposed as a reaction intermediate for HCN production in the atmosphere of Jupiter, and as a possible species in the expanding envelopes of oxygen--rich evolved stars. We detected CH2N in the cold cloud TMC--1 where the abundance seems to be some three orders of magnitude lower than that of HCN. A tentative detection was made in the Galactic Center molecular cloud Sgr B2. To our knowledge, there are no predicted abundances of CH2N from models of interstellar chemistry

    Boundary Conditions for the Paleoenvironment: Chemical and Physical Processes in the Pre-Solar Nebula

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    The basic theme of this program is the study of molecular complexity and evolution in interstellar clouds and in primitive solar system objects. Research has included the detection and study of a number of new interstellar molecules and investigation of reaction pathways for astrochemistry from a comparison of theory and observed molecular abundances. The latter includes studies of cold, dark clouds in which ion-molecule chemistry should predominate, searches for the effects of interchange of material between the gas and solid phases in interstellar clouds, unbiased spectral surveys of particular sources, and systematic investigation of the interlinked chemistry and physics of dense interstellar clouds. In addition, the study of comets has allowed a comparison between the chemistry of such minimally thermally processed objects and that of interstellar clouds, shedding light on the evolution of the biogenic elements during the process of solar system formation

    Verification of a Distributed Ledger Protocol for Distributed Autonomous Systems Using Monterey Phoenix

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    Autonomous multi-vehicle systems are becoming increasingly relevant in military operations and have demonstrated potential applicability in civilian environments as well. A problem emerges, however, when logging data within these systems. In particular, potential loss of individual vehicles and inherently lossy and noisy communications environments can result in the loss of important mission data. This paper describes a novel distributed ledger protocol that can be used to ensure that the data in such a system survives and documents verification of the behavioral correctness of this protocol using informal verification methods and tools provided by the Monterey Phoenix project

    Solar Geoengineering in the Polar Regions: A Review

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    Solar geoengineering refers to proposals, including stratospheric aerosol injection (SAI), to slow or reverse climate change by reflecting away incoming sunlight. The rapid changes ongoing in the Arctic and Antarctic, and the risk of exceeding tipping points in the cryosphere within decades, make limiting such changes a plausible objective of solar geoengineering. Here, we review the impacts of SAI on polar climate and cryosphere, including the dependence of these impacts on the latitude(s) of injection, and make recommendations for future research directions. SAI would cool the polar regions and reduce many changes in polar climate under future warming scenarios. Some under-cooling of the polar regions relative to the global mean is expected under SAI without high latitude injection, due to latitudinal variation in insolation and CO2 forcing, the forcing dependence of the polar lapse rate feedback, and altered atmospheric dynamics. There are also potential limitations in the effectiveness of SAI to arrest changes in winter-time polar climate and to prevent sea-level rise from the Antarctic ice sheet. Finally, we also review the prospects for three other solar geoengineering proposals targeting the poles: marine cloud brightening, cirrus cloud thinning, and sea-ice albedo modification. Sea-ice albedo modification appears unlikely to be viable on pan-Arctic or Antarctic scales. Whether marine cloud brightening or cirrus cloud thinning would be effective in the polar regions remains uncertain. Solar geoengineering is an increasingly prominent proposal and a robust understanding of its consequences in the polar regions is needed to inform climate policy in the coming decades

    Why practice philosophy as a way of life?

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    This essay explains why there are good reasons to practice philosophy as a way of life. The argument begins with the assumption that we should live well but that our understanding of how to live well can be mistaken. Philosophical reason and reflection can help correct these mistakes. Nonetheless, the evidence suggests that philosophical reasoning often fails to change our dispositions and behavior. Drawing on the work of Pierre Hadot, the essay claims that spiritual exercises and communal engagement mitigate the factors that prevent us from living in accord- ance with our conceptions of the good life. So, many of us have reasons to engage in philosophical reasoning along with behavioral, cognitive, and social strategies to alter our behavior and attitudes so that they’re in line with our philosophical commitments. In these respects, many of us should practice philosophy as a way of life

    The reactions of aromatic amines with 1,2-quinones

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