Copper(I)-Phosphinite Complexes in Click Cycloadditions: Three-Component Reactions and Preparation of 5-Iodotriazoles

© 2016 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.The remarkable activity displayed by copper(I)–phosphinite complexes of general formula [CuBr(L)] in two challenging cycloadditions is reported: a) the one-pot azidonation/cycloaddition of boronic acids, NaN3, and terminal alkynes; b) the cycloaddition of azides and iodoalkynes. These air-stable catalysts led to very good results in both cases and the expected triazoles could be isolated in pure form under ‘Click-suitable’ conditions

The Earth Mantle-Core Effect in Matter-Induced Asymmetries for Atmospheric Neutrino Oscillations

Earth medium effects in the three-neutrino oscillations of atmospheric neutrinos are observable under appropriate conditions. This paper generalizes the study of the medium effects and the possibility of their observation in the atmospheric neutrino oscillations from the case of neutrinos traversing only the Earth mantle, where the density is essentially constant, to the case of atmospheric neutrinos crossing also the Earth core. In the latter case new resonance-like effects become apparent. We calculate the CPT-odd asymmetry for the survival probability of muon neutrinos and the observable muon-charge asymmetry, taking into account the different atmospheric neutrino fluxes, and show the dependence of these asymmetries on the sign of $\Delta m^{2}_{3 1}$ and on the magnitude of the mixing angle $\theta_{13}$. A magnetized detector with a sufficiently good neutrino momentum resolution is required for the observation of the muon-charge asymmetry generated by the Earth mantle-core effect.Comment: 14 pages, 5 figure

Multifractal properties of elementary cellular automata in a discrete wavelet approach of MF-DFA

In 2005, Nagler and Claussen (Phys. Rev. E 71 (2005) 067103) investigated the time series of the elementary cellular automata (ECA) for possible (multi)fractal behavior. They eliminated the polynomial background at^b through the direct fitting of the polynomial coefficients a and b. We here reconsider their work eliminating the polynomial trend by means of the multifractal-based detrended fluctuation analysis (MF-DFA) in which the wavelet multiresolution property is employed to filter out the trend in a more speedy way than the direct polynomial fitting and also with respect to the wavelet transform modulus maxima (WTMM) procedure. In the algorithm, the discrete fast wavelet transform is used to calculate the trend as a local feature that enters the so-called details signal. We illustrate our result for three representative ECA rules: 90, 105, and 150. We confirm their multifractal behavior and provide our results for the scaling parametersComment: 8 pages, 5 figures, 21 reference

Multifractal properties of elementary cellular automata in a discrete wavelet approach of MF-DFA

In 2005, Nagler and Claussen (Phys. Rev. E 71 (2005) 067103) investigated the time series of the elementary cellular automata (ECA) for possible (multi)fractal behavior. They eliminated the polynomial background at^b through the direct fitting of the polynomial coefficients a and b. We here reconsider their work eliminating the polynomial trend by means of the multifractal-based detrended fluctuation analysis (MF-DFA) in which the wavelet multiresolution property is employed to filter out the trend in a more speedy way than the direct polynomial fitting and also with respect to the wavelet transform modulus maxima (WTMM) procedure. In the algorithm, the discrete fast wavelet transform is used to calculate the trend as a local feature that enters the so-called details signal. We illustrate our result for three representative ECA rules: 90, 105, and 150. We confirm their multifractal behavior and provide our results for the scaling parametersComment: 8 pages, 5 figures, 21 reference

Homoclinic Orbits around Spinning Black Holes I: Exact Solution for the Kerr Separatrix

Under the dissipative effects of gravitational radiation, black hole binaries will transition from an inspiral to a plunge. The separatrix between bound and plunging orbits features prominently in the transition. For equatorial Kerr orbits, we show that the separatrix is a homoclinic orbit in one-to-one correspondence with an energetically-bound, unstable circular orbit. After providing a definition of homoclinic orbits, we exploit their correspondence with circular orbits and derive exact solutions for them. This paper focuses on homoclinic behavior in physical space, while in a companion paper we paint the complementary phase space portrait. The exact results for the Kerr separatrix could be useful for analytic or numerical studies of the transition from inspiral to plunge.Comment: 21 pages, some figure