Hierarchical Lattice Models of Hydrogen Bond Networks in Water

We develop a graph-based model of the hydrogen bond network in water, with a view towards quantitatively modeling the molecular-level correlational structure of the network. The networks are formed are studied by the constructing the model on two infinite-dimensional lattices. Our models are built \emph{bottom up}, based on microscopic information coming from atomistic simulations, and we show that the predictions of the model are consistent with known results from ab-initio simulations of liquid water. We show that simple entropic models can predict the correlations and clustering of local-coordination defects around tetrahedral waters observed in the atomistic simulations. We also find that orientational correlations between bonds are longer ranged than density correlations, and determine the directional correlations within closed loops and show that the patterns of water wires within these structures are also consistent with previous atomistic simulations. Our models show the existence of density and compressibility anomalies, as seen in the real liquid, and the phase diagram of these models is consistent with the singularity-free scenario previously proposed by Sastry and co-workers (Sastry et al, PRE 53, 6144 (1996)).Comment: 17 pages, published versio

Hubble Space Telescope H-Band Imaging Survey of Massive Gas-Rich Mergers

We report the results from a deep HST NICMOS H-band imaging survey of a carefully selected sample of 33 luminous, late-stage galactic mergers at z < 0.3. Signs of a recent galactic interaction are seen in all of the objects in the HST sample, including all 7 IR-excess Palomar-Green (PG) QSOs in the sample. Unsuspected double nuclei are detected in 5 ULIRGs. A detailed two-dimensional analysis of the surface brightness distributions in these objects indicates that the great majority (81%) of the single-nucleus systems show a prominent early-type morphology. However, low-surface-brightness exponential disks are detected on large scale in at least 4 of these sources. The hosts of 'warm' AGN-like systems are of early type and have less pronounced merger-induced morphological anomalies than the hosts of cool systems with LINER or HII region-like nuclear optical spectral types. The host sizes and luminosities of the 7 PG~QSOs in our sample are statistically indistinguishable from those of the ULIRG hosts. In comparison, highly luminous quasars, such as those studied by Dunlop et al. (2003), have hosts which are larger and more luminous. The hosts of ULIRGs and PG QSOs lie close to the locations of intermediate-size (about 1 -- 2 L*) spheroids in the photometric projection of the fundamental plane of ellipticals, although there is a tendency in our sample for the ULIRGs with small hosts to be brighter than normal spheroids. Excess emission from a young stellar population in the ULIRG/QSO hosts may be at the origin of this difference. Our results provide support for a possible merger-driven evolutionary connection between cool ULIRGs, warm ULIRGs, and PG~QSOs although this sequence may break down at low luminosity. (abridged)Comment: Paper to be published in the Astrophysical Journal; revised based on comments from referee. A PDF file combining both text and figures is available at http://www.astro.umd.edu/~veilleux/pubs/nicmos.pd

Applications of polymer optical fibre grating sensors to condition monitoring of textiles

Fibre Bragg gratings (FBGs) in polymer optical fibres (POFs) have been used to measure the strain in a woven textile. FBGs in both POFs and silica optical fibres were attached to a woven textile specimen, and their performance characterised. It was demonstrated that the POF FBGs provide improved strain transfer coefficients and reduce local structural reinforcement compared to silica FBGs and therefore make a more suitable proposition for textile monitoring