Characterization of Carbon-Contaminated B4C-Coated Optics after Chemically Selective Cleaning with Low-Pressure RF Plasma

Boron carbide (B4C) is one of the few materials that is expected to be mostly resilient with respect to the extremely high brilliance of the photon beam generated by free electron lasers (FELs) and is thus of considerable interest for optical applications in this field. However, as in the case of many other optics operated at modern light source facilities, B4C-coated optics are subject to ubiquitous carbon contaminations. These contaminations represent a serious issue for the operation of high performance FEL beamlines due to severe reduction of photon flux, beam coherence, creation of destructive interference, and scattering losses. A variety of B4C cleaning technologies were developed at different laboratories with varying success. We present a study regarding the low-pressure RF plasma cleaning of carbon contaminated B4C test samples via inductively coupled O2/Ar, H2/Ar, and pure O2 RF plasma produced following previous studies using the same IBSS GV10x downstream plasma source. Results regarding the chemistry, morphology as well as other aspects of the B4C optical coating before and after the plasma cleaning are reported. We conclude from these comparative plasma processes that pure O2 feedstock plasma only exhibits the required chemical selectivity for maintaining the integrity of the B4C optical coating.Comment: 27 pages, 15 figure

Scope and limitation of the copper free thermal Huisgen cross-linking reaction to stabilize the chromophores orientation in electro-optic polymers

New methacrylate copolymers incorporating two complementary thermally cross-linkable groups (azide or ethynyl) for implementation in electro-optic devices were synthesized and their nonlinear optical properties were investigated. These copolymers were prepared from a monomer containing Disperse Red 1 (DR1) as active NLO chromophore which is end substituted either by an azide or ethynyl group connected via a rigid (phenyl) or flexible spacer (alkyl chain). The second monomer is either a trimethylsilyl-propargyl methacrylate, or an azidopropyl methacrylate or a trimethylsilyl-phenyl methacrylate. The determination of the reactivity ratios showed that the monomer containing the DR1 chromophore is more reactive than trimethylsilyl-propargyl methacrylate. The cross-linking temperatures of these polymers range from 150 °C to 187 °C depending on the rigidity of the spacers connecting the cross-linkable units. These polymers displayed relatively high macroscopic electro-optic stability, enhanced upon cross-linking by more than 40 °C relative to non-cross-linked polymers. The results underscore the importance of the flexibility of the spacers to achieve the stable bulk electro-optic response. While rigidity is favorable to maintain the orientation of the chromophores, the optimal polymer is the one containing a flexible and a rigid spacer, since the mobility of the reactive groups is a key parameter which guarantees a high cross-linking conversion within the polymer. This study demonstrates the versatility of this new cross-linking process because we showed that the reactive groups (azide or trimethylsilylacetylated groups) can be interconverted (on the chromophore or as polymer side chain) with no change on the overall electro-optic activity and its thermal stability. Furthermore, preliminary kinetic study indicates that the Huisgen reaction rate can be controlled by the substituent on the ethynyl group opening the possibility to tune the cross-linking temperature by the careful choice of this substituent

Monitoramento da campilobacteriose genital bovina no Pantanal Sul-Matogrossense: 1996 a 2004.

bitstream/CPAP/56260/1/CT74.pdfFormato eletrônic

Universal dynamical decoherence control of noisy single-and multi-qubit systems

In this article we develop, step by step, the framework for universal dynamical control of two-level systems (TLS) or qubits experiencing amplitude- or phase-noise (AN or PN) due to coupling to a thermal bath. A comprehensive arsenal of modulation schemes is introduced and applied to either AN or PN, resulting in completely analogous formulae for the decoherence rates, thus underscoring the unified nature of this universal formalism. We then address the extension of this formalism to multipartite decoherence control, where symmetries are exploited to overcome decoherence.Comment: 28 pages, 4 figure

Dynamical control of quantum state transfer within hybrid open systems

We analyze quantum state-transfer optimization within hybrid open systems, from a "noisy" (write-in) qubit to its "quiet" counterpart (storage qubit). Intriguing interplay is revealed between our ability to avoid bath-induced errors that profoundly depend on the bath-memory time and the limitations imposed by leakage out of the operational subspace. Counterintuitively, under no circumstances is the fastest transfer optimal (for a given transfer energy)

Experimental peripheral arterial disease: new insights into muscle glucose uptake, macrophage, and T-cell polarization during early and late stages.

Peripheral arterial disease (PAD) is a common disease with increasing prevalence, presenting with impaired walking ability affecting patient's quality of life. PAD epidemiology is known, however, mechanisms underlying functional muscle impairment remain unclear. Using a mouse PAD model, aim of this study was to assess muscle adaptive responses during early (1 week) and late (5 weeks) disease stages. Unilateral hindlimb ischemia was induced in ApoE(-/-) mice by iliac artery ligation. Ischemic limb perfusion and oxygenation (Laser Doppler imaging, transcutaneous oxygen pressure assessments) significantly decreased during early and late stage compared to pre-ischemia, however, values were significantly higher during late versus early phase. Number of arterioles and arteriogenesis-linked gene expression increased at later stage. Walking ability, evaluated by forced and voluntary walking tests, remained significantly decreased both at early and late phase without any significant improvement. Muscle glucose uptake ([18F]fluorodeoxyglucose positron emission tomography) significantly increased during early ischemia decreasing at later stage. Gene expression analysis showed significant shift in muscle M1/M2 macrophages and Th1/Th2 T cells balance toward pro-inflammatory phenotype during early ischemia; later, inflammatory state returned to neutrality. Muscular M1/M2 shift inhibition by a statin prevented impaired walking ability in early ischemia. High-energy phosphate metabolism remained unchanged (31-Phosphorus magnetic resonance spectroscopy). Results show that rapid transient muscular inflammation contributes to impaired walking capacity while increased glucose uptake may be a compensatory mechanisms preserving immediate limb viability during early ischemia in a mouse PAD model. With time, increased ischemic limb perfusion and oxygenation assure muscle viability although not sufficiently to improve walking impairment. Subsequent decreased muscle glucose uptake may partly contribute to chronic walking impairment. Early inflammation inhibition and/or late muscle glucose impairment prevention are promising strategies for PAD management

RF plasma cleaning of optical surfaces: A study of cleaning rates on different carbon allotropes as a function of RF powers and distances

An extended study on an advanced method for the cleaning of carbon contaminations on large optical surfaces using a remote inductively coupled low pressure RF plasma source (GV10x downstream asher) is reported in this work. Technical as well as scientific features of this scaled up cleaning process are analyzed, such as the cleaning efficiency for different carbon allotropes (amorphous and diamond-like carbon) as a function of feedstock gas composition, RF power (ranging from 30 to 300W), and source-object distances (415 to 840 mm). The underlying physical phenomena for these functional dependences are discussed.Comment: 16 pages, 9 figure

Mapeamento de unidades de paisagem em nível de fazenda, Pantanal da Nhecolândia.

bitstream/CPAP-2009-09/56882/1/BP83.pd

Simpler and more efficient strategy to stabilize the chromophore orientation in electro-optic polymers with copper-free thermal Huisgen reaction

A new strategy is proposed to stabilize the electro-optic (EO) activity of second-order materials using copper-free thermal Huisgen 1,3-dipolar cross-linking reaction. It consists in freezing the chromophores orientation after the poling process by a cross-linking reaction based on the 1,3-dipolar cycloaddition between an azide and an alkyne. To reach this goal, the synthesis of new methacrylate type polymers bearing a derivative of Disperse Red 1 chromophore was performed. The polymeric structure is bearing a cross-linkable function on its backbone and the complementary reactive function is brought by a small molecule called “doping agent” (DA), containing several complementary cross-linking groups, evenly distributed in the polymer film. Materials have been prepared and exhibit large second-order nonlinear optical coefficients (d33) up to 60 pm/V at the fundamental wavelength of 1064 nm. Moreover, the thermal stability of the orientation of the chromophores could reach 150 °C upon cross-linking with such materials, which is higher than previously described cross-linkable EO polymers based on this reaction. Furthermore, this new strategy widens the possibilities offered by copper-free thermal Huisgen 1,3-dipolar cycloaddition as cross-linking reaction for EO polymers