Low-Symmetry Rhombohedral GeTe Thermoelectrics

High-symmetry thermoelectric materials usually have the advantage of very high band degeneracy, while low-symmetry thermoelectrics have the advantage of very low lattice thermal conductivity. If the symmetry breaking of band degeneracy is small, both effects may be realized simultaneously. Here we demonstrate this principle in rhombohedral GeTe alloys, having a slightly reduced symmetry from its cubic structure, to realize a record figure of merit (zT ∼ 2.4) at 600 K. This is enabled by the control of rhombohedral distortion in crystal structure for engineering the split low-symmetry bands to be converged and the resultant compositional complexity for simultaneously reducing the lattice thermal conductivity. Device ZT as high as 1.3 in the rhombohedral phase and 1.5 over the entire working temperature range of GeTe alloys make this material the most efficient thermoelectric to date. This work paves the way for exploring low-symmetry materials as efficient thermoelectrics. Thermoelectric materials enable a heat flow to be directly converted to a flow of charge carriers for generating electricity. The crystal structure symmetry is one of the most fundamental parameters determining the properties of a crystalline material including thermoelectrics. The common belief currently held is that high-symmetry materials are usually good for thermoelectrics, leading to great efforts having historically been focused on GeTe alloys in a high-symmetry cubic structure. Here we show a slight reduction of crystal structure symmetry of GeTe alloys from cubic to rhombohedral, enabling a rearrangement in electronic bands for more transporting channels of charge carriers and many imperfections for more blocking centers of heat-energy carriers (phonons). This leads to the discovery of rhombohedral GeTe alloys as the most efficient thermoelectric materials to date, opening new possibilities for low-symmetry thermoelectric materials. Cubic GeTe thermoelectrics have been historically focused on, while this work utilizes a slight symmetry-breaking strategy to converge the split valence bands, to reduce the lattice thermal conductivity and therefore realize a record thermoelectric performance, all enabled in GeTe in a rhombohedral structure. This not only promotes GeTe alloys as excellent materials for thermoelectric power generation below 800 K, but also expands low-symmetry materials as efficient thermoelectrics

The Expression and Roles of Nde1 and Ndel1 in the Adult Mammalian Central Nervous System

Open Access funded by Wellcome Trust Under a Creative Commons license Acknowledgments We thank Prof Angelo Sementilli, Department of Pathology, Universidade Metropolitana de Santos, SP, Brazil, for the human sample collection. This study is funded by Scottish Universities Life Sciences Alliance (HR07019 to S. Shen and C.D. McCaig), Medical Research Scotland (384 FRG to B. Lang, United Kingdom), Tenovus Scotland (G12/25 to B. Lang), Sino-UK Higher Education Research Partnership for PhD Studies (C.D. McCaig and Y.Q. Ding) and Wellcome Trust (WT081633MA-NCE to P.J.A. McCaffery, United Kingdom).Peer reviewedPublisher PD

Polypyrrole and polyaniline nanocomposites with high photothermal conversion efficiency

The simple and scalable synthesis of poly[2-(methacryloyloxy)ethyl phosphorylcholine] (PMPC)-coated conducting polymer (CP) nanocomposites is described. These functional nanocomposites exhibit tunable absorption in the near-infrared region with relatively high photothermal efficiencies. More importantly, their potential for bio-imaging and therapeutic treatment is proven by cellular uptake and cytotoxicity studies

Neutrino masses, leptogenesis and dark matter in hybrid seesaw

We suggest a hybrid seesaw model where relatively ``light''right-handed neutrinos give no contribution to the neutrino mass matrix due to a special symmetry. This allows their Yukawa couplings to the standard model particles to be relatively strong, so that the standard model Higgs boson can decay dominantly to a left and a right-handed neutrino, leaving another stable right-handed neutrino as cold dark matter. In our model neutrino masses arise via the type-II seesaw mechanism, the Higgs triplet scalars being also responsible for the generation of the matter-antimatter asymmetry via the leptogenesis mechanism.Comment: 4 page

A unified approach to combinatorial key predistribution schemes for sensor networks

There have been numerous recent proposals for key predistribution schemes for wireless sensor networks based on various types of combinatorial structures such as designs and codes. Many of these schemes have very similar properties and are analysed in a similar manner. We seek to provide a unified framework to study these kinds of schemes. To do so, we define a new, general class of designs, termed “partially balanced t-designs”, that is sufficiently general that it encompasses almost all of the designs that have been proposed for combinatorial key predistribution schemes. However, this new class of designs still has sufficient structure that we are able to derive general formulas for the metrics of the resulting key predistribution schemes. These metrics can be evaluated for a particular scheme simply by substituting appropriate parameters of the underlying combinatorial structure into our general formulas. We also compare various classes of schemes based on different designs, and point out that some existing proposed schemes are in fact identical, even though their descriptions may seem different. We believe that our general framework should facilitate the analysis of proposals for combinatorial key predistribution schemes and their comparison with existing schemes, and also allow researchers to easily evaluate which scheme or schemes present the best combination of performance metrics for a given application scenario