Band structure and optical properties of opal photonic crystals

A theoretical approach for the interpretation of reflectance spectra of opal photonic crystals with fcc structure and (111) surface orientation is presented. It is based on the calculation of photonic bands and density of states corresponding to a specified angle of incidence in air. The results yield a clear distinction between diffraction in the direction of light propagation by (111) family planes (leading to the formation of a stop band) and diffraction in other directions by higher-order planes (corresponding to the excitation of photonic modes in the crystal). Reflectance measurements on artificial opals made of self-assembled polystyrene spheres are analyzed according to the theoretical scheme and give evidence of diffraction by higher-order crystalline planes in the photonic structure.Comment: to appear in PR

Role of covalency in the ground state properties of perovskite ruthenates: A first principle study using local spin density approximations

We investigate the electronic structure of SrRuO3 and CaRuO3 using full potential linearized augmented plane wave method within the local spin density approximations. The ferromagnetic ground state in SrRuO3 could exactly be described in these calculations and the calculated spin magnetic moment is found to be close to the experimentally observed values. Interestingly, the spin polarized calculations for CaRuO3 exhibit large spin moment as observed in the experiments but the magnetic ground state has higher energy than that in the non-magnetic solution. Various calculations for different structural configurations indicate that Ca-O covalency plays the key role in determining the electronic structure and thereby the magnetic ground state in this system.Comment: 8 figure

Nod2 Deficiency in mice is Associated with Microbiota Variation Favouring the Expansion of mucosal CD4+ LAP+ Regulatory Cells

Nucleotide-binding Oligomerization Domain-2 (NOD2) mutations are associated with an increased risk to develop Crohn's Disease. In previous studies, we have shown that Nod2-/- mice manifest increased proportion of Lamina Propria (LP) CD4+ LAP+ Foxp3- regulatory cells, when compared with Nod2+/+ mice, while CD4+ Foxp3 + regulatory cells were not affected. Here, we investigated the Nod2 gut microbiota, by 16S rRNA pyrosequencing, at steady state and after TNBS-colitis induction in mice reared separately or in cohousing, correlating the microbial profiles with LP regulatory T cells proportion and tissue cytokines content. We found that enrichment of Rikenella and Alistipes (Rikenellaceae) in Nod2-/- mice at 8 weeks of age reared separately was associated with increased proportion of CD4+ LAP+ Foxp3- cells and less severe TNBS-colitis. In co-housed mice the acquisition of Rickenellaceae by Nod2+/+ mice was associated with increased CD4+ LAP+ Foxp3- proportion and less severe colitis. Severe colitis was associated with enrichment of gram-negative pathobionts (Escherichia and Enterococcus), while less severe colitis with protective bacteria (Barnesiella, Odoribacter and Clostridium IV). Environmental factors acting on genetic background with different outcomes according to their impact on microbiota, predispose in different ways to inflammation. These results open a new scenario for therapeutic attempt to re-establish eubiosis in Inflammatory Bowel Disease patients with NOD2 polymorphisms

TiOCl, an orbital-ordered system?

We present first principles density functional calculations and downfolding studies of the electronic and magnetic properties of the layered quantum spin system TiOCl. We discuss explicitely the nature of the exchange pathes and attempt to clarify the concept of orbital ordering in this material. An analysis of the electronic structure of slightly distorted structures according to the phononic modes allowed in this material suggests that this system is subject to large orbital fluctuations driven by the electron-phonon coupling. Based on these results, we propose a microscopic explanation of the behavior of TiOCl near the phase transition to a spin-gapped system.Comment: Some figures are compressed, for higher quality please contact the author

Impact of aging on the sintering behavior of bioactive-glass powder

Bioactive glasses (BGs) have been successfully used for several years as bone graft substitutes to fill defects and augment bone structures in orthopedic and dental procedures. Despite recent advances in the fabrication of reliable 3D scaffolds based on BG, the reproducibility of fabrication has only been marginally addressed and remains a challenge for their application. Recent studies have shown that BGs can react with moisture and atmospheric CO2 to form carbonates, affecting the properties and structure of the final product. In this study, factors that can affect the sintering behavior of BG powders were identified and investigated. A statistical analysis was then performed to optimize the BG sintering process, which revealed the possibility of obtaining BG scaffolds with reproducible density by acting on controllable factors such as aging and drying. In practice, this can be achieved by controlling the atmosphere during processing, handling, and storage of the material

Origin of Jahn-Teller distortion and orbital-order in LaMnO3

The origin of the cooperative Jahn-Teller distortion and orbital-order in LaMnO3 is central to the physics of the manganites. The question is complicated by the simultaneous presence of tetragonal and GdFeO3-type distortions and the strong Hund's rule coupling between e_g and t_2g electrons. To clarify the situation we calculate the transition temperature for the Kugel-Khomskii superexchange mechanism by using the local density approximation+dynamical mean-field method, and disentangle the effects of super-exchange from those of lattice distortions. We find that super-exchange alone would yield T_KK=650 K. The tetragonal and GdFeO3-type distortions, however, reduce T_KK to 550 K. Thus electron-phonon coupling is essential to explain the persistence of local Jahn-Teller distortions to at least 1150 K and to reproduce the occupied orbital deduced from neutron scattering.Comment: 4 pages, 3 figures; published version (minor changes

Magnetic Field Effect on the Pseudogap Temperature within Precursor Superconductivity

We determine the magnetic field dependence of the pseudogap closing temperature T* within a precursor superconductivity scenario. Detailed calculations with an anisotropic attractive Hubbard model account for a recently determined experimental relation in BSCCO between the pseudogap closing field and the pseudogap temperature at zero field, as well as for the weak initial dependence of T* at low fields. Our results indicate that the available experimental data are fully compatible with a superconducting origin of the pseudogap in cuprate superconductors.Comment: 4 pages, 3 figure

Charge Kondo effect toward a non-Fermi-liquid fixed point in the orbitally degenerate exchange model

We show that a Kondo-type model with an orbital degeneracy has a new non-Fermi-liquid fixed point. Near the fixed point the spin degrees of freedom are completely quenched, and the residual charge degrees of freedom lead to the multi-channel Kondo effect. Anomalous behavior appears in electric and thermal properties, but the magnetic susceptibility should show the local Fermi-liquid behavior. The non-Fermi-liquid fixed point becomes unstable against perturbations breaking the particle-hole symmetry. We derive these results using the third-order scaling for a spherically symmetric model with a fictitious spin. In contrast to the Coqblin-Schrieffer model, the present model respects different time-reversal properties of multipole operators.Comment: 4 pages, 2 eps figures, to appear in J. Phys. Soc. Jpn. 68 No.