14,282 research outputs found
Distribution of inorganic and organic nutrients in the South Pacific Ocean – evidence for long-term accumulation of organic matter in nitrogen-depleted waters
International audienceThe BIOSOPE cruise of the RV Atalante was devoted to study the biogeochemical properties in the South Pacific between the Marquesas Islands (141° W–8° S) and the Chilean upwelling (73° W–34° S). The 8000 km cruise had the opportunity to encounter different trophic situations, and especially strong oligotrophic conditions in the Central South Pacific Gyre (SPG, between 123° W and 101° W). In this isolated region, nitrate was undetectable between surface and 160–180 m, while regenerated nitrogen (nitrite and ammonium) only revealed some traces (-1), even in the subsurface maximum. Integrated nitrate over the photic layer, which reached 165 m, was close to zero. In spite of this severe nitrogen-depletion, phosphate was always present at significant concentrations (˜0.1 µmoles l-1), while silicate maintained at low but classical oceanic levels (˜1 µmoles l-1). In contrast, the Marquesas region (MAR) at west and Chilean upwelling (UPW) at east were characterized by large nutrient contents one hundred to one thousand fold higher than in the SPG. Distribution of surface chlorophyll concentration reflected this gradient of nitrate availability. The lowest value (0.023 nmoles l-1) was measured in the centre of the SPG, where integrated chlorophyll over the photic layer was very weak (˜10 mg m-2), since a great part (up to 50%) of the deep chlorophyll maximum (DCM) was located below the 1% light. But, because of the relative high concentration encountered in the DCM (0.2 µg l-1), chlorophyll a content over the photic layer varied much less (by a factor 2 to 5) than the nitrate content. In contrast to chlorophyll a, integrated content of particulate organic matter (POM) remained more or less constant along the investigated area (500 mmoles m-2, 60 mmoles m-2 and 3.5 mmoles m-2 for particulate organic carbon, particulate organic nitrogen and particulate organic phosphorus, respectively), except in the upwelling where values were two fold higher. Extensive comparison has shown that glass fiber GF/F filters efficiency collected particulate chlorophyll, while a significant fraction of POM (up to 50%) passed trough this filter and was retained by 0.2 µm Teflon membrane. The most striking feature was the large accumulation of dissolved organic matter (DOM) in the SPG relative to surrounding waters, especially dissolved organic carbon (DOC) where concentrations were at levels rarely measured in oceanic waters (>100 µmoles l-1). Due to this large pool of DOM over the whole photic layer of the SPG, integrated values followed an opposite geographical pattern than this of inorganic nutrients with a large accumulation within the centre of the SPG. While suspended particulate matter in the mixed layer had C/N ratio largely conform to Redfield stoichiometry (C/N˜6.6), marked deviations were observed in this excess DOM (C/N˜16 to 23). The existence of C-rich dissolved organic matter is recognized as a feature typical of oligotrophic waters, requiring the over consumption of carbon. Thus, in spite of strong nitrate-depletion leading to low chlorophyll biomass, the closed ecosystem of the SPG can produce a large amount of carbon. The implications of this finding are discussed, the conclusion being that, due to the lack of seasonal vertical mixing and weak lateral advection, the dissolved organic carbon biologically produced can be accumulated and stored in the photic layer for a very long period
The Effects of Gravitational Back-Reaction on Cosmological Perturbations
Because of the non-linearity of the Einstein equations, the cosmological
fluctuations which are generated during inflation on a wide range of
wavelengths do not evolve independently. In particular, to second order in
perturbation theory, the first order fluctuations back-react both on the
background geometry and on the perturbations themselves. I this paper, the
gravitational back-reaction of long wavelength (super-Hubble) scalar metric
fluctuations on the perturbations themselves is investigated for a large class
of inflationary models. Specifically, the equations describing the evolution of
long wavelength cosmological metric and matter perturbations in an inflationary
universe are solved to second order in both the amplitude of the perturbations
and in the slow roll expansion parameter. Assuming that the linear fluctuations
have random phases, we show that the fractional correction to the power
spectrum due to the leading infrared back-reaction terms does not change the
shape of the spectrum. The amplitude of the effect is suppressed by the product
of the inflationary slow-roll parameter and the amplitude of the linear power
spectrum. The non-gaussianity of the spectrum induced by back-reaction is
commented upon.Comment: 9 page
Seasonal Variability of Saturn's Tropospheric Temperatures, Winds and Para-H from Cassini Far-IR Spectroscopy
Far-IR 16-1000 m spectra of Saturn's hydrogen-helium continuum measured
by Cassini's Composite Infrared Spectrometer (CIRS) are inverted to construct a
near-continuous record of upper tropospheric (70-700 mbar) temperatures and
para-H fraction as a function of latitude, pressure and time for a third of
a Saturnian year (2004-2014, from northern winter to northern spring). The
thermal field reveals evidence of reversing summertime asymmetries superimposed
onto the belt/zone structure. The temperature structure that is almost
symmetric about the equator by 2014, with seasonal lag times that increase with
depth and are qualitatively consistent with radiative climate models. Localised
heating of the tropospheric hazes (100-250 mbar) create a distinct perturbation
to the temperature profile that shifts in magnitude and location, declining in
the autumn hemisphere and growing in the spring. Changes in the para-H
() distribution are subtle, with a 0.02-0.03 rise over the spring
hemisphere (200-500 mbar) perturbed by (i) low- air advected by both the
springtime storm of 2010 and equatorial upwelling; and (ii) subsidence of
high- air at northern high latitudes, responsible for a developing
north-south asymmetry in . Conversely, the shifting asymmetry in the
para-H disequilibrium primarily reflects the changing temperature structure
(and the equilibrium distribution of ), rather than actual changes in
induced by chemical conversion or transport. CIRS results interpolated to
the same point in the seasonal cycle as re-analysed Voyager-1 observations show
qualitative consistency, with the exception of the tropical tropopause near the
equatorial zones and belts, where downward propagation of a cool temperature
anomaly associated with Saturn's stratospheric oscillation could potentially
perturb tropopause temperatures, para-H and winds. [ABRIDGED]Comment: Preprint accepted for publication in Icarus, 29 pages, 18 figure
Choice Dilemmas and Risk Management Education
Differences in attitudes toward risk may result in individuals making different, yet correct, decisions. This article illustrates how choice dilemmas, hypothetical life decision situations, can be used in Extension workshops to help individuals identify their own willingness to assume risk and demonstrate differences among individuals. The agriculturally adapted choice dilemmas also illustrate fundamental risk-return trade-offs and the diversity of risks faced by producers. The willingness to assume risk scale is useful in assisting producers to understand their own risk attitudes and provides a means of incorporating risk attitudes into risk management education programs
RISK PERCEPTIONS AND MANAGEMENT RESPONSES: PRODUCER-GENERATED HYPOTHESES FOR RISK MODELING
Farm level risk analyses have used price and yield variability almost exclusively to represent risk. Results from a survey of 149 agricultural producers in 12 states indicate that producers consider a broader range of sources of variability in their operations. Significant differences exist among categories with respect to the importance of the sources of variability in crop and livestock production. Producers also used a variety of management responses to variability. There were significant difference among categories in the importance given to particular responses and their use of them. These results have implications for research, extension, and policy programs.Risk and Uncertainty,
Numerical simulation of ion transport membrane reactors: Oxygen permeation and transport and fuel conversion
Ion transport membrane (ITM) based reactors have been suggested as a novel technology for several applications including fuel reforming and oxy-fuel combustion, which integrates air separation and fuel conversion while reducing complexity and the associated energy penalty. To utilize this technology more effectively, it is necessary to develop a better understanding of the fundamental processes of oxygen transport and fuel conversion in the immediate vicinity of the membrane. In this paper, a numerical model that spatially resolves the gas flow, transport and reactions is presented. The model incorporates detailed gas phase chemistry and transport. The model is used to express the oxygen permeation flux in terms of the oxygen concentrations at the membrane surface given data on the bulk concentration, which is necessary for cases when mass transfer limitations on the permeate side are important and for reactive flow modeling. The simulation results show the dependence of oxygen transport and fuel conversion on the geometry and flow parameters including the membrane temperature, feed and sweep gas flow, oxygen concentration in the feed and fuel concentration in the sweep gas.King Fahd University of Petroleum and MineralsKing Abdullah University of Science and Technology (KAUST) (grant number KSU-I1-010-01
Entangled-Photon Imaging of a Pure Phase Object
We demonstrate experimentally and theoretically that a coherent image of a
pure phase object may be obtained by use of a spatially incoherent illumination
beam. This is accomplished by employing a two-beam source of entangled photons
generated by spontaneous parametric down-conversion. Though each of the beams
is, in and of itself, spatially incoherent, the pair of beams exhibits
higher-order inter-beam coherence. One of the beams probes the phase object
while the other is scanned. The image is recorded by measuring the photon
coincidence rate using a photon-counting detector in each beam. Using a
reflection configuration, we successfully imaged a phase object implemented by
a MEMS micro-mirror array. The experimental results are in accord with
theoretical predictions.Comment: 11 pages, 3 figures, submittedto Phys. Rev. Let
Eigenvector Centrality Distribution for Characterization of Protein Allosteric Pathways
Determining the principal energy pathways for allosteric communication in
biomolecules, that occur as a result of thermal motion, remains challenging due
to the intrinsic complexity of the systems involved. Graph theory provides an
approach for making sense of such complexity, where allosteric proteins can be
represented as networks of amino acids. In this work, we establish the
eigenvector centrality metric in terms of the mutual information, as a mean of
elucidating the allosteric mechanism that regulates the enzymatic activity of
proteins. Moreover, we propose a strategy to characterize the range of the
physical interactions that underlie the allosteric process. In particular, the
well known enzyme, imidazol glycerol phosphate synthase (IGPS), is utilized to
test the proposed methodology. The eigenvector centrality measurement
successfully describes the allosteric pathways of IGPS, and allows to pinpoint
key amino acids in terms of their relevance in the momentum transfer process.
The resulting insight can be utilized for refining the control of IGPS
activity, widening the scope for its engineering. Furthermore, we propose a new
centrality metric quantifying the relevance of the surroundings of each
residue. In addition, the proposed technique is validated against experimental
solution NMR measurements yielding fully consistent results. Overall, the
methodologies proposed in the present work constitute a powerful and cost
effective strategy to gain insight on the allosteric mechanism of proteins
Clustering and Synchronization of Oscillator Networks
Using a recently described technique for manipulating the clustering
coefficient of a network without changing its degree distribution, we examine
the effect of clustering on the synchronization of phase oscillators on
networks with Poisson and scale-free degree distributions. For both types of
network, increased clustering hinders global synchronization as the network
splits into dynamical clusters that oscillate at different frequencies.
Surprisingly, in scale-free networks, clustering promotes the synchronization
of the most connected nodes (hubs) even though it inhibits global
synchronization. As a result, scale-free networks show an additional, advanced
transition instead of a single synchronization threshold. This cluster-enhanced
synchronization of hubs may be relevant to the brain with its scale-free and
highly clustered structure.Comment: Submitted to Phys. Rev.
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