Characterization of the spatio-temporal variation of atmospheric pollution. WRF-Chem simulations and analysis potential sources contribution on the Central Andes

The Central Andes are an area located in South America, between latitudes 30 ° and 40 ° south. It is important because it contains the largest metropolitan area in Chile, Santiago and the fourth largest city in Argentina, Mendoza. According to climate predictions, this region would be very affected by climate change, which would cause an alteration of the relationships between liquidand solid precipitation, albedo variations, changes in the seasonal distribution of Andean fluvial spills and overtaking in runoff peaks. Due to the possible socioeconomic impacts in the region, it is necessary to design and implement adaptation strategies for these anticipated changes. An accurate prediction requires a correct representation of atmospheric conditions, their development and evolution. Recent studies conducted by our research group show that thepresence of atmospheric aerosols would be related to the negative trend variations of albedo in the snow during the last 17 years, which leads to an increase in the thaw rate. Even so, there is a high degree of uncertainty about the identification and characterization of the sources of origin of the aerosols that contribute most to the darkening of the snow. In addition, the particulatematerial, depending on its size, quantity and chemical composition, could modify the constitution of the clouds, reducing the precipitation of rain or snow and increasing the formation of hail. The physics and dynamics of this type of events can be understood through the use of mesoscale models. In this work, inventories of regional anthropogenic emissions of own elaboration are incorporated to the simulations carried out with the WRF-Chem model to studythe relationships: aerosols-albedo and aerosols-precipitations. The objective is to recognize the retro-trajectories that indicate potential sources of contamination, and to improve the modeling with own measurements, made for the criteria pollutants: PM, BC, OC and dust.Fil: Pascual Flores, Romina María. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Tecnológica Nacional. Facultad Regional de Mendoza; ArgentinaFil: Bolaño Ortiz, Tomas Rafael. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Tecnológica Nacional. Facultad Regional de Mendoza; ArgentinaFil: Puliafito, Salvador Enrique. Universidad Tecnológica Nacional. Facultad Regional de Mendoza; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaSchool of Atmospheric Measurements in Latin America and the Caribbean: Atmospheric particles and Reactive GasesSan JuanPuerto RicoUniversity of Puerto Ric

Aerosols measurement as product of biomass burning on cryosphere in the Central Andes

The cryosphere on the Central Andes between Argentina and Chile is an important water reservoir; therefore, it is important to ensure the sustainability of this resource for the ecosystem and millions of people in this region. Then, the knowledge about hydrological cycle and the different phenomena that are affecting its radiative balance caused by absorbing aerosols of solar radiation, some of these aerosols can be generated by large burning of biomass, a practice that occurs during crop changes in the austral spring in South America. For this reason, it has been analyzed in several basins uses remote knowledge data for 17 years (2000 - 2016) and the analysis of variations on snow albedo, aerosol optical depth (ODA) and land surface temperature of several water basins of that region. The partial results indicate a negative tendency in the snow albedo decrease related to the AOD variations. The next step will be collect snow samples to measure levoglucosan, mannosan and galactosan to establish if there is on snow presence of aerosol from the biomass combustion and the type of biomass source.Fil: Bolaño Ortiz, Tomas Rafael. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Tecnológica Nacional. Facultad Regional de Mendoza; ArgentinaFil: Pascual Flores, Romina María. Universidad Tecnológica Nacional. Facultad Regional de Mendoza; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Ruggeri, María Florencia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales. Provincia de Mendoza. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales. Universidad Nacional de Cuyo. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales; ArgentinaFil: Lakkis, Susan Gabriela. Universidad Tecnológica Nacional. Facultad Regional Buenos Aires; Argentina. Pontificia Universidad Católica Argentina "Santa María de los Buenos Aires". Facultad de Ciencias Agrarias; ArgentinaFil: Puliafito, Salvador Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Tecnológica Nacional. Facultad Regional de Mendoza; ArgentinaSchool of Atmospheric Measurements in Latin America and the Caribbean: Atmospheric particles and Reactive GasesSan JuanPuerto RicoUniversity of Puerto Ric

Atmospheric methane emissions for Argentina: comparison with TROPOMI satellite measurements

Methane emissions have very important effect on global radiative forcing. Therefore, reducing these emissions has been proposed as an effective short-term strategy to mitigate global warming, in parallel with reductions in long-lived carbon dioxide (CO2) for long- term temperature stabilizations. In this context, Argentina emits 3645 Gg of CH4 mainly from livestock production, biomass burning and natural gas production. Since 2018, TROPOMI instruments provide global coverage on methane column-average mole fraction of dry air (XCH4), and height profiles of methane concentrations. We compare two available methane inventory: a national (a high resolution of own ellaboration: GEAA) and an international (EDGAR) emissions database with TROPOMI measurements. By performing inverse satellite retrieval we evaluate the ability of remote sensing information to detect possible hotspot methane emissions and compare these results with the two inventories. From these analyzes, we observe that the latitudinal averages of the continental sector increase at a rate of 10 ppb/degree, from south to north, while the maritime sector remains constant. From a temporary perspective, the average monthly concentration amplitude range varies 40 to 50 ppb, with minimum values in March and maximum values in September.Fil: Puliafito, Salvador Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza; Argentina. Universidad Tecnológica Nacional. Facultad Regional de Mendoza; ArgentinaFil: Berná Peña, Lucas Luciano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza; Argentina. Universidad Tecnológica Nacional. Facultad Regional de Mendoza; ArgentinaFil: Lopez Noreña, Ana Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza; Argentina. Universidad Tecnológica Nacional. Facultad Regional de Mendoza; ArgentinaFil: Pascual Flores, Romina María. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza; Argentina. Universidad Tecnológica Nacional. Facultad Regional de Mendoza; ArgentinaFil: Bolaño Ortiz, Tomas Rafael. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza; Argentina. Universidad Tecnológica Nacional. Facultad Regional de Mendoza; ArgentinaIEEE Latin American GRSS & ISPRS Remote Sensing ConferenceSantiagoChileInternational Society for Photogrametry and Remote SensingInstitute of Electrical and Electronics Engineer

Identifying patterns and sources of anthropogenic trace metals in the Argentine Central Andes by using snow samples and an atmospheric dispersion model

This study presents the first local measurements of metals in snow from the Argentine Central Andes. Cu, Pb and Zn were selected as specific tracers of anthropogenic local emission sources in the study area. Snow samples were collected during winter (2014, 2015 and 2016) at two sites with different characteristics: Punta de Vacas and Vallecitos. The samples were analyzed by ICP-MS, and the average concentrations found were 1.4 μg L-1 (Cu), 2.2 μg L-1 (Pb) and 14.2 μg L-1 (Zn) in the snow samples from Vallecitos, and 5.3 μg L-1 (Cu), 2.6 μg L-1 (Pb) and 24.0 μg L-1 (Zn) in the snow samples from Punta de Vacas. These data and the snowfall amount in each sampling site were statistically analyzed. Results suggested that the levels of metals in the snow are influenced not only by the atmospheric concentrations, but also by the amount of precipitated snow. Additionally, an atmospheric dispersion model, CALPUFF, was applied in the study area to determine the origin of the studied metals and to understand the spatial distribution pattern of the concentrations found. Results showed that the metal atmospheric loads in the study area originated from local sources, especially vehicular traffic and mining. This work represents an important contribution to the knowledge and preservation of the local Andean cryosphere, and it could be used as an input to develop protection policies in the area through the combination of different and complementary tools for the evaluation of air quality.Fil: Ruggeri, María Florencia. Universidad Tecnica Federico Santa Maria.; Chile. Universidad Tecnológica Nacional; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales. Provincia de Mendoza. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales. Universidad Nacional de Cuyo. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales; ArgentinaFil: Castesana, Paula Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza; Argentina. Universidad Nacional de San Martín; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); ArgentinaFil: Bolaño Ortiz, Tomas Rafael. Universidad Tecnológica Nacional. Facultad Regional de Mendoza; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza; ArgentinaFil: Puliafito, Salvador Enrique. Universidad Tecnológica Nacional. Facultad Regional de Mendoza; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza; ArgentinaFil: Pascual Flores, Romina María. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza; Argentina. Universidad Tecnológica Nacional. Facultad Regional de Mendoza; ArgentinaFil: Altamirano, Jorgelina Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales. Provincia de Mendoza. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales. Universidad Nacional de Cuyo. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales; ArgentinaFil: Allende, David Gabriel. Universidad Tecnológica Nacional. Facultad Regional de Mendoza; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza; Argentin

A techno-economic and life cycle assessment for the production of green methanol from CO2: catalyst and process bottlenecks

The success of catalytic schemes for the large-scale valorization of CO2 does not only depend on the development of active, selective and stable catalytic materials but also on the overall process design. Here we present a multidisciplinary study (from catalyst to plant and techno-economic/lifecycle analysis) for the production of green methanol from renewable H2 and CO2. We combine an in-depth kinetic analysis of one of the most promising recently reported methanol-synthesis catalysts (InCo) with a thorough process simulation and techno-economic assessment. We then perform a life cycle assessment of the simulated process to gauge the real environmental impact of green methanol production from CO2. Our results indicate that up to 1.75 ton of CO2 can be abated per ton of produced methanol only if renewable energy is used to run the process, while the sensitivity analysis suggest that either rock-bottom H2 prices (1.5 $kg−1) or severe CO2 taxation (300$ per ton) are needed for a profitable methanol plant. Besides, we herein highlight and analyze some critical bottlenecks of the process. Especial attention has been paid to the contribution of H2 to the overall plant costs, CH4 trace formation, and purity and costs of raw gases. In addition to providing important information for policy makers and industrialists, directions for catalyst (and therefore process) improvements are outlined.The authors gratefully acknowledge financial support from the King Abdullah University of Science and Technology (KAUST). T. Cordero-Lanzac and A.T. Aguayo acknowledge the financial support received from the Spanish Ministry of Science and Innovation with some ERDF funds (CTQ2016-77812-R) and the Basque Government (IT1218-19). T. Cordero-Lanzac also acknowledges the Spanish Ministry of Education, Culture and Sport for the award of his FPU grant (FPU15-01666). A. Navajas and L.M. Gandía gratefully acknowledge the financial support from Spanish Ministerio de Ciencia, Innovación y Universidades, and the European Regional Development Fund (ERDF/FEDER) (grant RTI2018-096294-B-C31). L.M. Gandía also thanks Banco de Santander and Universidad Pública de Navarra for their financial support under ‘’Programa de Intensificación de la Investigación 2018’ initiative

Spread of COVID-19, Meteorological Conditions and Air Quality in the City of Buenos Aires, Argentina: Two Facets Observed during Its Pandemic Lockdown

This work studied the spread of COVID-19, the meteorological conditions and the air quality in a megacity from two viewpoints: (1) the correlation between meteorological and air quality (PM10 and NO2) variables with infections and deaths due COVID-19, and (2) the improvement in air quality. Both analyses were performed for the pandemic lockdown due to COVID-19 in the City of Buenos Aires (CABA), the capital and the largest city in Argentina. Daily data from temperature, rainfall, average relative humidity, wind speed, PM10, NO2, new cases and deaths due COVID-19 were analyzed. Our findings showed a significant correlation of meteorological and air quality variables with COVID-19 cases. The highest temperature correlation occurred before the confirmation day of new cases. PM10 presented the highest correlation within 13 to 15 days lag, while NO2 within 3 to 6 days lag. Also, reductions in PM10 and NO2 were observed. This study shows that exposure to air pollution was significantly correlated with an increased risk of becoming infected and dying due to COVID-19. Thus, these results show that the NO2 and PM10 levels in CABA can serve as one of the indicators to assess vulnerability to COVID-19. In addition, decision-makers can use this information to adopt strategies to restrict human mobility during the COVID-19 pandemic and future outbreaks of similar diseases in CABA.Fil: Bolaño Ortiz, Tomas Rafael. Universidad Tecnológica Nacional. Facultad Regional de Mendoza; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Pascual Flores, Romina María. Universidad Tecnológica Nacional. Facultad Regional Buenos Aires; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Puliafito, Salvador Enrique. Universidad Tecnológica Nacional. Facultad Regional de Mendoza; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Camargo Caicedo, Yiniva. Universidad del Magdalena; ColombiaFil: Berná Peña, Lucas Luciano. Universidad Tecnológica Nacional. Facultad Regional de Mendoza; Argentina. Ministerio de Ciencia. Tecnología e Innovación Productiva. Agencia Nacional de Promoción Científica y Tecnológica; ArgentinaFil: Ruggeri, María Florencia. Universidad Tecnica Federico Santa Maria; Chile. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Lopez Noreña, Ana Isabel. Universidad Tecnológica Nacional. Facultad Regional de Mendoza; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Tames, María Florencia. Universidad Tecnológica Nacional. Facultad Regional de Mendoza; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Cereceda Balic, Francisco. Universidad Tecnica Federico Santa Maria; Chil

12-month safety and efficacy of everolimus with reduced exposure cyclosporine in de novo renal transplant recipients

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/74645/1/j.1432-2277.2006.00414.x.pd