Observation of Spin-glass-like Behavior in SrRuO3 Epitaxial Thin Films

We report the observation of spin-glass-like behavior and strong magnetic anisotropy in extremely smooth (~1-3 \AA) roughness) epitaxial (110) and (010) SrRuO3 thin films. The easy axis of magnetization is always perpendicular to the plane of the film (unidirectional) irrespective of crystallographic orientation. An attempt has been made to understand the nature and origin of spin-glass behavior, which fits well with Heisenberg model.Comment: 5 pages, 5 Figure

Variation in fish catches from the continental shelf between Quilon and Gulf of Mannar and its relation to oceanographic conditions during the southwest monsoon period

The present paper is based on the fishing results of FORV Sagar Sampada during July-August, 1987 along the southwest coast of India. The fish fauna of the Quilon Bank and Wadge Bank has a dominant nemipterid element and the Gulf of Mannar area has a dominant population of barracudas. Nemipterids constituted 88.2 and 64.4% of the total trawl catch from the Quilon Bank and Wadge Bank respectively

Reversible, repeatable and low phase transition behaviour of spin coated nanostructured vanadium oxide thin films with superior mechanical properties

Smooth, uniform and crystalline vanadium oxide thin films were deposited on quartz by spin coating technique with four different rpm i.e., 1000, 2000, 3000 and 4000 and subsequently post annealed at 350, 450 and 550 °C in vacuum. Transmission electron microscopy (TEM), Field emission scanning electron microscopy (FESEM) and X-ray diffraction (XRD) techniques were utilized for microstructural characterizations and phase analysis, respectively, for vanadium oxide powder and deposited film. Nanorods were observed to be grown after vacuum annealing. X-ray photoelectron spectroscopy (XPS) technique was utilized to study the elemental oxidation state of deposited vanadium oxide films. Thermo-optical and electrical properties such as solar transmittance (τs), reflectance (ρs), absorptance (αs), infrared (IR) emittance (εir) and sheet resistance (Rs) of different thin films were evaluated. Based on the optical characteristics the optimized condition of the film processing was identified to be spin coated at 3000 rpm. Subsequently, the nanoindentation technique was utilized to measure hardness and Young's modulus of the optimized film. The measured nanomechanical properties were found to be superior to those reported for sputtered vanadium oxide films. Finally, temperature dependent phase transition characteristics of optimized vanadium oxide films were studied by differential scanning calorimetry (DSC) technique. Reversible and repeatable phase transition was found to occur in the range of 44–48 °C which was significantly lower than the phase transition temperature (i.e., 68 °C) of bulk VO2

Phase transition and enhanced magneto-dielectric response in BiFeO3-DyMnO3 multiferroics

This work is partially supported by DST fast track Project No. SR/FTP/PS-16/2009. Dhiren K. Pradhan acknowledges IFN (NSF Grant No. EPS—01002410) for fellowship. The work at UPR was supported by National Science Foundation (NSF DMR 1410869) and Institute for Functional Nanomaterials (IFN).We report systematic studies on crystal structure and magneto-dielectric properties of (1 − x) BiFeO3-x DyMnO3 (0.0 ≤ x ≤ 0.2) nanoceramics synthesized by auto-combustion method. Rietveld refinement of X-ray diffraction data indicates a structural transition from R3c to R3c + Pn21a at x = 0.1. Field emission scanning electron micrographs display a decrease in grain size with increase in x. The presence of dielectric anomalies around antiferromagnetic transition temperature implies the magnetoelectric coupling. Dielectric measurements showed decrease in magnetic ordering temperature with increasing x in agreement with differential scanning calorimetry results. A significant increase in magnetization has been found with increasing DyMnO3 substitution. Magneto-impedance spectroscopy reveals a significant change (∼18%) in dielectricpermittivity at H = 2 T for x = 0.2.Peer reviewe

Phase transition close to room temperature in BiFeO3 thin films

BiFeO3 (BFO) multiferroic oxide has a complex phase diagram that can be mapped by appropriately substrate-induced strain in epitaxial films. By using Raman spectroscopy, we conclusively show that films of the so-called supertetragonal T-BFO phase, stabilized under compressive strain, displays a reversible temperature-induced phase transition at about 100\circ, thus close to room temperature.Comment: accepted in J. Phys.: Condens. Matter (Fast Track Communication

Autonomous mowing and turf-type bermudagrass as innovations for an environment-friendly floor management of a vineyard in coastal tuscany

The establishment of permanent cover crops is becoming a common practice in vineyard floor management. Turfgrass science may provide species and techniques with a high potential for improving the sustainability of vineyard floor management. Based on this assumption, an experiment was carried out during 2018 and 2019 at the Donna Olimpia Vineyard, Bolgheri, Italy. The trial aimed at comparing an innovative floor management system based on a turf-type cultivar of bermudagrass mown with an autonomous mower with a conventional floor management system. Ground cover percentage, energy consumption, CO2 emissions, grapevine water status, leaf nitrogen content, fruit yield and must composition have been assessed in order to perform the comparison. The innovative vineyard floor management produced an almost complete ground cover (98%) at the end of the second growing season, with the resident species reduced to a small percentage (4%). Resident species growing under-trellis were efficiently controlled without herbicide applications. A lower primary energy consumption and a reduction in CO2 emissions were observed for the innovative management system compared to the conventional management system. Grapevine water status, leaf chlorophyll content, soil–plant analyses development (SPAD), fruit yields and must composition were similar between the different soil management systems. Based on results obtained in this trial, turf-type bermudagrass and innovative mowing machines may contribute to enhance the sustainability of vineyard floor management

Magnetoelectric ordering of BiFeO3 from the perspective of crystal chemistry

In this paper we examine the role of crystal chemistry factors in creating conditions for formation of magnetoelectric ordering in BiFeO3. It is generally accepted that the main reason of the ferroelectric distortion in BiFeO3 is concerned with a stereochemical activity of the Bi lone pair. However, the lone pair is stereochemically active in the paraelectric orthorhombic beta-phase as well. We demonstrate that a crucial role in emerging of phase transitions of the metal-insulator, paraelectric-ferroelectric and magnetic disorder-order types belongs to the change of the degree of the lone pair stereochemical activity - its consecutive increase with the temperature decrease. Using the structural data, we calculated the sign and strength of magnetic couplings in BiFeO3 in the range from 945 C down to 25 C and found the couplings, which undergo the antiferromagnetic-ferromagnetic transition with the temperature decrease and give rise to the antiferromagnetic ordering and its delay in regard to temperature, as compared to the ferroelectric ordering. We discuss the reasons of emerging of the spatially modulated spin structure and its suppression by doping with La3+.Comment: 18 pages, 5 figures, 3 table

Effect of Solid Die Equi-Channel Pressing Angle on beta-Mg17Al12 Phase Morphology and Mechanical Behavior of AZ80 Mg alloy

The effects of die channel angle (I broken vertical bar) in hot (similar to 623 K) equi-channel angular pressing (ECAP) on microstructure, and tensile and compressive flow properties of AZ80 Mg alloy were investigated. Two solid ECAP dies, having I broken vertical bar of (1) dual 60A degrees and 120A degrees in a single die and (2) 90A degrees in another die, were designed for this purpose. Grain refinement with more than 40% reduction in average grain size along with submicron size second-phase beta-precipitates was achieved after single-pass ECAP. A great variation in beta-Mg17Al12 phase morphology with increasing flow stresses in tension and compression are found with decreasing value of angle I broken vertical bar. There found an increasing effect on strain to failure with decrease in porosity and second-phase precipitate modification. However, there appears flow asymmetry between tension and compression with the latter exhibiting greater flow stress and strain to failure