83 research outputs found
Technological activity in the european regions
This paper investigates technological activity in the European regions. The analysis is based on a statistical databank set up by CRENoS on regional patenting at the European Patent Office spanning from 1978 to 2001 and classified by ISIC sectors at the 2 digit level. We consider 175 regions of 17 countries in Europe, the 15 members of the European Union plus Switzerland and Norway. An analysis of the spatial distribution of innovation activities in Europe is performed. Some global and local indicators for spatial association are presented, signaling the presence of a general dependence process in the distribution of the phenomena under examination. The analysis is implemented for different manufacturing sectors to assess for the presence of significant differences in the their spatial features. Moreover, the extent and strength of spatial externalities are evaluated for some subperiods spanning from the early eighties to the late nineties
Stability of Cubic FAPbI from X-ray Diffraction, Anelastic, and Dielectric Measurements
Among the hybrid metal-organic perovskites for photovoltaic applications
FAPbI_3 (FAPI) has the best performance regarding efficiency and the worst
regarding stability, even though the reports on its stability are highly
contradictory. In particular, since at room temperature the cubic alpha phase,
black and with high photovoltaic efficiency, is metastable against the yellow
hexagonal delta phase, it is believed that alpha-FAPI spontaneously transform
into delta-FAPI within a relatively short time. We performed X-ray diffraction
and thermogravimetric measurements on loose powder of FAPI, and present the
first complete dielectric and anelastic spectra of compacted FAPI samples under
various conditions. We found that alpha-FAPI is perfectly stable for at least
100 days, the duration of the experiments, unless extrinsic factors induce its
degradation. In our tests, degradation was detected after exposure to humidity,
strongly accelerated by grain boundaries and the presence of delta phase, but
it was not noticeable on the loose powder kept in air under normal laboratory
illumination. These findings have strong implications on the strategies for
improving the stability of FAPI without diminishing its photovoltaic efficiency
through modifications of its composition
Characterization of DNA methylation as a function of biological complexity via dinucleotide inter-distances
We perform a statistical study of the distances between successive
occurrencies of a given dinucleotide in the DNA sequence for a number of
organisms of different complexity. Our analysis highlights peculiar features of
the dinucleotide CG distribution in mammalian DNA, pointing towards a
connection with the role of such dinucleotide in DNA methylation. While the CG
distributions of mammals exhibit exponential tails with comparable parameters,
the picture for the other organisms studied (e.g., fish, insects, bacteria and
viruses) is more heterogeneous, possibly because in these organisms DNA
methylation has different functional roles. Our analysis suggests that the
distribution of the distances between dinucleotides CG provides useful insights
in characterizing and classifying organisms in terms of methylation
functionalities.Comment: 13 pages, 5 figures. To be published in the Philosophical
Transactions A theme issue "DNA as information
Titanium and Ruthenium Phthalocyanines for NO2 Sensors: A Mini-Review
This review presents studies devoted to the description and comprehension of phenomena connected with the sensing behaviour towards NO2 of films of two phthalocyanines, titanium bis-phthalocyanine and ruthenium phthalocyanine. Spectroscopic, conductometric, and morphological features recorded during exposure to the gas are explained and the mechanisms of gas-molecule interaction are also elucidated. The review also shows how X-ray reflectivity can be a useful tool for monitoring morphological parameters such as thickness and roughness that are demonstrated to be sensitive variables for monitoring the exposure of thin films of sensor materials to NO2 gas
Effect of dietary supplementation of a mix of chestnut and quebracho tannins on intestinal morphology, bacterial load, Eimeria spp oocyst excretion and immune response after vaccination in rabbits
Among plant products, tannins exhibited a strong antioxidant activity and their employment was studied as food or feed addictive with positive effects. Nevertheless, their health-enhancing properties remain to be completely clarified, particularly in rabbits. The aim of the present study was to investigate the influence of a mix of chestnut and quebracho tannins as supplementation in rabbit diet on intestinal morphology, as well as bacterial loads and Eimeria spp coccidial oocyst excretion and humoral immune response after vaccination. Rabbits were fed four different diets: basal diet (negative control, group CN), basal diet with anticoccidial supplementation (positive control, group CP) and basal diet with tannins mix 0.3% (group T0.3) or 0.6% (group T0.6). Samples of intestine, liver, spleen thymus, mesenteric lymph nodes, kidney and heart were submitted to histopathologic investigations. Morphometric analyses were performed on portion of duodenum, jejunum and ileum. Intestinal contents were analyzed by flotation test for Eimeria spp. oocysts excretion and by microbiological assays for Clostridium perfringens and Escherichia coli. Rabbits belonging to the four experimental groups were vaccinated by means of a live attenuated myxomatosis virus and sera were collected individually at three time points to determine antibody response.The obtained results demonstratedthe absence of toxic effects of the tannin mix on examined organs, particularly on liver and kidney and any negative influence on the growth performance. A relevant anti-inflammatory effect on the intestinal tract, a reduction of Eimeria spp. oocysts excretion and a positive immunomodulatory and antibacterial effects were also observed. Diets supplemented with the tannins mix affected also the morphology of examined intestinal tracts, particularly duodenum and ileum
Dietary supplementation of quebracho and chestnut tannins mix in rabbit: effects on live performances, digestibility, carcase traits, antioxidant status, faecal microbial load and economic value
The effects of dietary supplementation of tannins mix (quebracho and chestnut) in rabbit diet were evaluated for productive performances, health parameters and digestibility in order to quantify their practical utilisation in the rearing system. One-hundred and twenty Martini group hybrid rabbits of 30 days old were fed four different diets for 60 days. The diets were formulated as: basal diet (negative control, C), basal diet supplemented by 0.3% of tannins mix (T0.3), basal diet supplemented by 0.6% of tannins mix (T0.6) and basal diet supplemented with coccidiostat (positive control, CC). Live performances did not show any significant differences, moreover, no significant differences were observed for all carcase traits except for gastrointestinal tract (p =.015, lowest values for T0.3 diet). Also, digestibility of the feed and faecal microbial load was not influenced by tannins addition. Slight differences between the diets were detected in catalase and glutathione peroxidase concentrations in plasma, as a common trend was revealed with higher values of C than the other diets. From an economical point of view, T0.3 diet showed to be more profitable than CC and T0.6. Tannins addition might be taken into account as potential feed additive in rabbit feeds, as it does not affect negatively the productive performances, digestibility and induce a slight increase of antioxidant status.Highlights On an economical point of view tannin diet showed to be more profitable than a diet added with coccidiostat. Addition of tannins in rabbits’ feed did not affect negatively productive performances and digestibility. Tannins represent a valuable feed additive in rabbit farming as a slightly increase of antioxidant status was induced
Chemical and radiological characterization of meals served by the COSEAS (USP-SP)
O presente estudo apresenta resultados de análise quÃmica de refeições (almoço) oferecidas pelo restaurante do COSEAS (USP), por cinco dias não consecutivos. Essas refeições foram coletadas em triplicata, da mesma forma como oferecida para os usuários, sendo, a seguir, liofilizadas para as análises posteriores. No total, 15 amostras foram coletadas. A análise quÃmica de composição centesimal foi realizada segundo as técnicas padronizadas pela AOAC. O conteúdo de alguns elementos minerais (Ca, Fe, K, Na, Se e Zn) foi determinado por análise por ativação neutrônica instrumental. A validação da metodologia foi feita por meio da análise dos materiais de referência. A partir dos dados de concentração, calcularam-se os valores de ingestão de cada nutriente correspondente a esta refeição (40% da ingestão diária total), que foram avaliadas segundo as novas recomendações de nutrientes (Dietary Reference Intakes - DRIs) do National Research Council (USA), considerando a população de mulheres no estágio de vida de 19 a 30 anos. Comparando-se os valores médios encontrados com os valores recomendados, concluiu-se que: para os macronutrientes e os micronutrientes, Fe, Se e Zn, as recomendações foram atingidas; para Ca e K foram deficientes; e para Na excedeu o valor recomendado. Os radionuclÃdeos 40K, 60Co, 137Cs e 131I foram determinados, nas amostras de dieta, por espectrometria gama; 90Sr por cintilação em meio lÃquido; e 210Po, 234U, 232Th, 238U, 235U, 228Th, 230Th e 232Th por espectrometria alfa. Verificou-se, a partir dos resultados obtidos, que todos os radionuclÃdeos analisados se encontram muito abaixo dos limites estabelecidos pela FAO.This study presents the results obtained for the chemical and radiological analyses of lunch meals served in the cafeteria at the University of São Paulo-USP (COSEAS restaurant) in Brazil, on 5 non-consecutive days. On each of the five days, the meals were collected in triplicate and then freeze-dried for analysis totalizing 15 samples. The determination of the proximate composition complied with the AOAC standardized methodologies. The content of Ca, Fe, K, Na, Se, and Zn was determined by instrumental neutron activation analysis and the method validation was performed by certified reference materials analyses. Based on the concentration data, the daily intake of each mineral was calculated (corresponding to 40% of the total daily intake) and compared to the new recommendations set by the National Research Council (USA) considering the 19-30 year-old women range group. Comparing the average values obtained in this study with the recommended values, it was possible to verify that for macronutrients and the micronutrients Fe, Se, and Zn the recommendations were followed; for Ca and K they were deficient and exceeded the recommendation value for Na. The radionuclides 40K, 60Co, 137Cs, and 131I were determined by gamma spectrometry; 90Sr by liquid cintilation and 210Po, 234U, 232Th, 238U, 235U, 228Th, 230Th, and 232Th by alfa spectrometry. All radionuclides are present in concentrations below the limits set by the Food and Agriculture Organization (FAO)
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Nonlinear Optical Characterization of CsPbBr3 Nanocrystals as a Novel Material for the Integration into Electro-Optic Modulators
The present work is concerned with the investigation of the nonlinear optical response of green emissive CsPbBr3 nanocrystals, in the form of colloidal dispersions in toluene, synthesized via a room-temperature ligand-assisted supersaturation recrystallization (LASR) method. After carrying out a preliminary characterization via X-Ray Diffraction (XRD) and Absorption and Photoluminescence (PL) Spectroscopies, the optical nonlinearity of the as-obtained colloids is probed by means of a single-beam Z-scan setup. Results show that the material in question, within the sensitivity of the experimental apparatus, exhibits a nonlinear refractive index n2 that is the order of 10-15 cm2/W. Moreover, a three-photon absorption mechanism (3PA) is postulated, according to the fitting of the recorded Z-scan traces and the fundamental absorption threshold, which turns out to be off resonance with twice the energy of the laser radiation. A figure of merit is, then, calculated as an indicator of the quality of the CsPbBr3 nanocrystals as a candidate material for photonic devices, for instance, Kerr-like electro-optic modulators (EOMs)
Determination of Natural Radionuclides (Ra-226, Po-210, Ra-228 and K-40) and Cs-137 in Fish Consumed in the City of São Paulo
The aim of the study was to determine the activity concentration of the natural radionuclides (226Ra, 210Po, 228Ra and 40K) and artificial radionuclide 137Cs in the muscle of the marine fish species most consumed in the city of São Paulo and to evaluate the annual effective dose due to the consumption of the fish. Samples were collected in the supermarket chain Extra and Carrefour and in the distribution center CEAGESP. Six fish species were selected among the most available and consumed in São Paulo city: anchovy, tuna, dogfish, croaker, hake and sardine. After the sample preparation procedures, the determination of 226Ra, 228Ra, 40K and 137Cs was carried out by gamma spectrometry and the determination of 210Po by alpha spectrometry. The results obtained for all the species studied are below the limits adopted by the Brazilian Standards for 137Cs and, therefore, their consumption offers no risk due to the ingestion of this radionuclide. The concentration obtained for the radionuclides 226Ra, 210Po, 228Ra and 137Cs in the fish samples analized are low and of the same order of magnitude as data from literature. The results obtained for the doses, for all the species studied, showed that their consumption offers no risk of exposure due to the ingestion of the analyzed radionuclides
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