Elements in Tap Water - Part 2 - Quality Assurance of Analysis

Due to the inclusion of the quality of the water distribution system in the DWD this new directive prescribes new parametric values and the performance characteristics. The trueness, precision and limit of detection are defined as percentage of the parametric value. In the framework of our research on the effect of products on the quality of drinking water at the consumers¿ tap, we studied the quality of our data using certified reference water and four selected samples. Elements additional to the DWD, i.e. those evaluated by the WHO and those mentioned in national regulations concerning the acceptance of products that come in contact with drinking water, were included in our study. Analysis of the certified standard revealed that K, Pb and Se might only suffer from a small systematic error whereas As and Ca might suffer a bigger systematic error (P=0.05). The trueness of As is out of range compared to what is defined in the DWD. The trueness of Cu and Pb is at the edge. The precision of As and Se are on the edge. In general, the low concentrations in the samples compared to the parametric values in the DWD result in slightly or significantly lower precisions. The precision of Al, Ca, Fe, Mg and Zn for the samples is lower compared to that of the certified standard at a similar concentration level whereas U showed the opposite behaviour. The certified values and their precision for certified standards are normally obtained by single element analysis and do not consider performance during time. Considering the fact that our method analyses 28 elements and that this might introduce additional variations both in trueness and precision compared to single element analysis and the fact that the results were obtained during ten month, our method is fit for our purpose to study release from materials. For legal purposes or for detailed studies on specific elements a single element analysis may be more appropriate. This is especially true for arsenic.JRC.H.5-Rural, water and ecosystem resource

Elements in Tap Water. Part 3. Effect of Sample Volume and Stagnation Time on the Concentration of the Element.

Abstract not availableJRC.H-Institute for environment and sustainability (Ispra

Evaluation of EDXRF for the Determination of Elements in PM10 Filter

Energy Dispersive X-ray Fluorescence (EDXRF) was compared to Inductively Coupled Plasma Mass Spectrometer (ICP-MS) for the measurements of elements in particulate matter (PM10). Lead (Pb), arsenic (As), nickel (Ni) and cadmium (Cd)) and the ones included in the EMEP programme, namely copper, chromium and zinc were tested. Other elements such as magnesium, aluminium, silicon, sulphur, chloride, potassium, calcium, titanium, vanadium, iron, cobalt, manganese, bromide, strontium, molybdenum, tin and antimony, which are essential for source apportionment studies, were also tested. PM10 samples collected at different sites on several types of filter were analyzed using both EDXRF and ICP-MS. As the overall result of this study, EDXRF can be considered as an alternative method to ICP-MS for measurements of PM-bound elements, particularly on Teflon filters. The European legislative requirements of Pb could be met for whatever filters type. The European legislative requirements of Ni and As are likely be met, but, it is unknown for Cd. The EMEP requirements can be met for Cu and Zn, but not for Cr. EDXRF can also be used to measure elements for source apportionment purposesJRC.H.2-Climate change and air qualit

JRC-Ispra Atmosphere - Biosphere - Climate Integrated monitoring Station: 2016 report

A comprehensive set of essential atmospheric variables have been measured at the JRC-Ispra Atmosphere - Biosphere - Climate Integrated monitoring Station (ABC-IS) for several years to assess the impact of European policies and international conventions on air pollution and climate forcing. The variables we measure at the Atmospheric Observatory in Ispra include greenhouse gas concentrations (CO2, CH4, N2O, SF6), radon (222Rn) activity concentration, short-lived gaseous and particulate pollutant (CO, SO2, NO, NO2, O3, PM2.5 and its main ionic and carbonaceous constituents) concentrations, atmospheric particle micro-physical characteristics (number concentration and size distribution) and optical properties (light scattering and absorption in-situ, light scattering and extinction vertical profiles remotely), eutrophying and acidifying species (SO42-, NO3-, NH4+) wet deposition. Vegetation atmosphere exchanges (CO2, O3, H2O and heat) are measured at our Forest Flux Station of San Rossore, backed up by meteorological and pedological measurements. The ABC-IS 2016 report presents the data produced during the past year in the context of the previous years of measurements.JRC.C.5-Air and Climat

JRC – Ispra: Atmosphere – Biosphere – Climate Integrated monitoring Station: 2015 Report

A comprehensive set of essential atmospheric variables have been measured at the JRC-Ispra Atmosphere -Biosphere - Climate Integrated monitoring Station (ABC-IS) for several years to detect the impact of European policies and international conventions on air pollution and climate forcing. The variables we measure include greenhouse gas concentrations (CO2, CH4, N2O, SF6), radon (222Rn)activity concentration, short-lived gaseous and particulate pollutants (CO, SO2, NO, NO2, O3, PM2.5 and its main ionic and carbonaceous constituents), atmospheric particle micro-physical characteristics (number concentration and size distribution) and optical properties (light scattering and absorption in-situ, light scattering and extinction vertical profiles remotely), eutrophying and acidifying species (SO42-, NO3-, NH4+) wet deposition, and vegetation atmosphere exchanges (CO2, O3, H2O and heat), backed up by meteorological and pedological measurements. All the measurements performed at ABC-IS are made under international projects and programs like InGOS (Integrated non-CO2 Greenhouse gas Observation System), ACTRIS (the EU research Infra-Structure for the observation of Aerosols, Clouds and TRace gases), EMEP (co-operative Program for Monitoring and Evaluation of the long range transmission of air pollutants in Europe) and GAW (Global Atmosphere Watch), which implies the use of standard methods and scales, and the participation in quality assurance activities. The JRC has a leading role in ACTRIS and EMEP regarding the quality assurance for carbonaceous aerosol measurements. All the data obtained at ABC-IS are submitted to international open data bases (www.europe-fluxdata.eu, fluxnet.ornl.gov, www.ingos-infrastructure.eu, ebas.nilu.no,) and can be freely downloaded from these web sites. The data we produce are used in European wide assessments, for model inputs and validation, and for calibrating satellite airborne sensors. The ABC-IS 2015 report presents the data produced during the past year in the context of the previous years of measurements.JRC.C.5-Air and Climat

Intercomparison Exercise for Heavy Metals in PM10

The Joint Research Centre (JRC) has carried out an Intercomparison Exercise (IE) for the determination of heavy metals in particulate matter (PM10). The IE focussed on Lead (Pb), Arsenic (As), Nickel (Ni) and Cadmium (Cd), the heavy metals regulated by the 1st and 4th Daughter Directives for Air Pollution. Copper (Cu), Chromium (Cr) and Zinc (Zn), the elements included in the EMEP programme together with Aluminium (Al), Cobalt (Co), Iron (Fe), Manganese (Mn) and Vanadium (V) were also tested. Fourteen Laboratories, generally members of the Network of Air Quality Reference Laboratories (AQUILA), participated in the IE. The participants mainly used microwave digestion with nitric acid and hydrogen peroxide and Inductively Coupled Plasma Mass Spectrometry (ICP-MS) or Graphite Furnace Atomic Absorption Spectrometry (GF-AAS) for analysis as recommended in the reference method (EN 14902). However, a few participants used other methods: Energy Dispersive X-ray Fluorescence (EDXRF), Atomic Emission Spectrometry (ICP-AES) and Voltammetry for analysis and vaporisation on hot plate before microwave digestion, Soxhlet extraction, high pressure or cold Hydrogen Fluoride methods for digestion. Each participant received 5 samples to be analysed: a liquid sample prepared by dilution of a Certified Reference Material (CRM), a solution of a dust CRM sample digested by the JRC13F, a sub-sample of a dust CRM that each participating laboratory had to digest and analyse, a solution prepared by JRC after digestion of an exposed filter and a pair of filters (one blank filter and one exposed filter) to be digested and analysed by each participant. For 89 % of all types of samples, the DQOs of the 1st and 4th European Directives (uncertainty of 25 % for Pb and 40 % for As, Cd and Ni) were met. All together, this is a very good score. The best results were obtained for the liquid CRM, dust CRM digested by JRC, dust CRM and filter digested by JRC with 92, 90, 96 and 93 % of DQOs being met, respectively. It was found that the DQOs were not met if the difference of acidity between test samples and participant calibration standards was high. Conversely, only 76 % of DQOs were met for the filter to be digested by each participant with (about 85 % for Cd and Ni, 73/64 % for Pb and As, the most difficult element to determine). The worst results were associated with special events: explosion in microwave oven during digestion for two participants, a wrong dilution factor used by one participant and a huge contamination in the blank filter for another participant. Among the two explosions, one of them was probably the effect of a lack of temperature control in the digestion vessel. For the other explosion, the microwave digestion and the digestion program advised by EN 14902 is to be questioned. Moreover, satisfactory results were obtained using Soxhlet extraction, high pressure method and cold Hydrogen Fluoride digestion methods which are not presented in EN 14902. The DQOs of As and Cd could not be met with EDXRF whose limit of detection was too high for these two elements and for Cd using Voltammetry which suffered a strong interference for this element. Regarding the methods of analysis, apart the points mentioned just before about EDXRF and Voltammetry, good results were observed using ICP-OES for Cd, Ni and Pb. A few discrepancies were also registered for GF-AAS and ICP-MS but they were created by the special events or acidity problem mentioned before. This shows that even though GF-AAS and ICP-MS are found suitable, the implementation by each participant may be responsible for important mistakes.JRC.H.4-Transport and air qualit

JRC – Ispra Atmosphere – Biosphere – Climate Integrated monitoring Station: 2014 Report

The Institute for Environment and Sustainability provides long-term observations of the atmosphere within international programs and research projects. These observations are performed from the research infrastructure named ABC-IS: Atmosphere – Biosphere – Climate Integrated monitoring Station. Most measurements are performed at the JRC-Ispra site, but observations are also carried out from two other platforms: the forest station in San Rossore, and a ship cruising in the Western Mediterranean sea. This document reports about the measurement programs, the equipment which is deployed, the data quality assessment, and the results obtained for each site. Our observations are presented, compared to each other, as well as to historical data obtained over close to 30 years at the Ispra site.JRC.H.2-Air and Climat

JRC – Ispra Atmosphere – Biosphere – Climate Integrated monitoring Station 2013 report

The Institute for Environment and Sustainability provides long-term observations of the atmosphere within international programs and research projects. These observations are performed from the research infrastructure named ABC-IS: Atmosphere – Biosphere – Climate Integrated monitoring Station. Most measurements are performed at the JRC-Ispra site, but observations are also carried out from two other platforms: the forest station in San Rossore, and a ship cruising in the Western Mediterranean sea. This document reports about the measurement programs, the equipment which is deployed, the data quality assessment, and the results obtained for each site. Our observations are presented, compared to each other, as well as to historical data obtained over more than 25 years at the Ispra site.JRC.H.2-Air and Climat

JRC-Ispra Atmosphere-Biosphere-Climate Integrated monitoring Station 2012 report

The Institute for Environment and Sustainability provide long-term observations of the atmosphere within international programs and research projects. These observations are performed from the research infrastructure named ABC-IS: Atmosphere – Biosphere – Climate Integrated monitoring station. Most measurements are performed at the JRC-Ispra site. Observations are also carried out from two other platforms: the forest station in San Rossore, and a ship cruising in the Western Mediterranean sea. This document reports about measurement programs, the equipment which is deployed, the data quality assessment, and the results obtained for each site. Our observations are presented, compared to each other, as well as to historical data obtained over more than 25 years at the Ispra siteJRC.H.2-Air and Climat

JRC – Ispra Atmosphere – Biosphere – Climate Integrated monitoring Station : 2011 report

The Institute for Environment and Sustainability provide long-term observations of the atmosphere within international programs and research projects. These observations are performed from the research infrastructure named ABC-IS: Atmosphere-Biosphere-Climate Integrated monitoring station. Most measurements are performed at the JRC-Ispra site. Observations are also carried out from two other platforms: the forest station in San Rossore, and a ship cruising in the Western Mediterranean sea. This document reports about measurement programs, the equipment which is deployed, and the data quality assessment for each site. Our observations are presented, compared to each other, as well as to historical data obtained over the past 25 years at the Ispra site.JRC.H.2-Air and Climat