Reconciling aerosol light extinction measurements from spaceborne lidar observations and in situ measurements in the Arctic

© Author(s) 2014. This work is distributed under the Creative Commons Attribution 3.0 License.In this study we investigate to what degree it is possible to reconcile continuously recorded particle light extinction coefficients derived from dry in situ measurements at Zeppelin station (78.92° N, 11.85° E; 475 m above sea level), Ny-Ålesund, Svalbard, that are recalculated to ambient relative humidity, as well as simultaneous ambient observations with the Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) aboard the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) satellite. To our knowledge, this represents the first study that compares spaceborne lidar measurements to optical aerosol properties from short-term in situ observations (averaged over 5 h) on a case-by-case basis. Finding suitable comparison cases requires an elaborate screening and matching of the CALIOP data with respect to the location of Zeppelin station as well as the selection of temporal and spatial averaging intervals for both the ground-based and spaceborne observations. Reliable reconciliation of these data cannot be achieved with the closest-approach method, which is often used in matching CALIOP observations to those taken at ground sites. This is due to the transport pathways of the air parcels that were sampled. The use of trajectories allowed us to establish a connection between spaceborne and ground-based observations for 57 individual overpasses out of a total of 2018 that occurred in our region of interest around Svalbard (0 to 25° E, 75 to 82° N) in the considered year of 2008. Matches could only be established during winter and spring, since the low aerosol load during summer in connection with the strong solar background and the high occurrence rate of clouds strongly influences the performance and reliability of CALIOP observations. Extinction coefficients in the range of 2 to 130 Mmg-1 at 532 nm were found for successful matches with a difference of a factor of 1.47 (median value for a range from 0.26 to 11.2) between the findings of in situ and spaceborne observations (the latter being generally larger than the former). The remaining difference is likely to be due to the natural variability in aerosol concentration and ambient relative humidity, an insufficient representation of aerosol particle growth, or a misclassification of aerosol type (i.e., choice of lidar ratio) in the CALIPSO retrieval.Peer reviewe

Proteomic analysis of endothelial cold-adaptation

<p>Abstract</p> <p>Background</p> <p>Understanding how human cells in tissue culture adapt to hypothermia may aid in developing new clinical procedures for improved ischemic and hypothermic protection. Human coronary artery endothelial cells grown to confluence at 37°C and then transferred to 25°C become resistant over time to oxidative stress and injury induced by 0°C storage and rewarming. This protection correlates with an increase in intracellular glutathione at 25°C. To help understand the molecular basis of endothelial cold-adaptation, isolated proteins from cold-adapted (25°C/72 h) and pre-adapted cells were analyzed by quantitative proteomic methods and differentially expressed proteins were categorized using the DAVID Bioinformatics Resource.</p> <p>Results</p> <p>Cells adapted to 25°C expressed changes in the abundance of 219 unique proteins representing a broad range of categories such as translation, glycolysis, biosynthetic (anabolic) processes, NAD, cytoskeletal organization, RNA processing, oxidoreductase activity, response-to-stress and cell redox homeostasis. The number of proteins that decreased significantly with cold-adaptation exceeded the number that increased by 2:1. Almost half of the decreases were associated with protein metabolic processes and a third were related to anabolic processes including protein, DNA and fatty acid synthesis. Changes consistent with the suppression of cytoskeletal dynamics provided further evidence that cold-adapted cells are in an energy conserving state. Among the specific changes were increases in the abundance and activity of redox proteins glutathione S-transferase, thioredoxin and thioredoxin reductase, which correlated with a decrease in oxidative stress, an increase in protein glutathionylation, and a recovery of reduced protein thiols during rewarming from 0°C. Increases in S-adenosylhomocysteine hydrolase and nicotinamide phosphoribosyltransferase implicate a central role for the methionine-cysteine transulfuration pathway in increasing glutathione levels and the NAD salvage pathway in increasing the reducing capacity of cold-adapted cells.</p> <p>Conclusions</p> <p>Endothelial adaptation to mild-moderate hypothermia down-regulates anabolic processes and increases the reducing capacity of cells to enhance their resistance to oxidation and injury associated with 0°C storage and rewarming. Inducing these characteristics in a clinical setting could potentially limit the damaging effects of energy insufficiency due to ischemia and prevent the disruption of integrated metabolism at low temperatures.</p

Seasonal variation of aerosol water uptake and its impact on the direct radiative effect at Ny-Ålesund, Svalbard

© Author(s) 2014. This work is distributed under the Creative Commons Attribution 3.0 LicenseIn this study we investigated the impact of water uptake by aerosol particles in ambient atmosphere on their optical properties and their direct radiative effect (ADRE, W m-2) in the Arctic at Ny-Ålesund, Svalbard, during 2008. To achieve this, we combined three models, a hygroscopic growth model, a Mie model and a radiative transfer model, with an extensive set of observational data. We found that the seasonal variation of dry aerosol scattering coefficients showed minimum values during the summer season and the beginning of fall (July-August-September), when small particles (< 100 nm in diameter) dominate the aerosol number size distribution. The maximum scattering by dry particles was observed during the Arctic haze period (March-April-May) when the average size of the particles was larger. Considering the hygroscopic growth of aerosol particles in the ambient atmosphere had a significant impact on the aerosol scattering coefficients: the aerosol scattering coefficients were enhanced by on average a factor of 4.30 ± 2.26 (mean ± standard deviation), with lower values during the haze period (March-April-May) as compared to summer and fall. Hygroscopic growth of aerosol particles was found to cause 1.6 to 3.7 times more negative ADRE at the surface, with the smallest effect during the haze period (March-April-May) and the highest during late summer and beginning of fall (July-August-September).Peer reviewe

Measured and predicted aerosol light scattering enhancement factors at the high alpine site Jungfraujoch

Ambient relative humidity (RH) determines the water content of atmospheric aerosol particles and thus has an important influence on the amount of visible light scattered by particles. The RH dependence of the particle light scattering coefficient (&amp;sigma;&lt;sub&gt;sp&lt;/sub&gt;) is therefore an important variable for climate forcing calculations. We used a humidification system for a nephelometer which allows for the measurement of &amp;sigma;&lt;sub&gt;sp&lt;/sub&gt; at a defined RH in the range of 20–95%. In this paper we present measurements of light scattering enhancement factors &lt;i&gt;f&lt;/i&gt;(RH)=&amp;sigma;&lt;sub&gt;sp&lt;/sub&gt;(RH)/&amp;sigma;&lt;sub&gt;sp&lt;/sub&gt;(dry) from a 1-month campaign (May 2008) at the high alpine site Jungfraujoch (3580 m a.s.l.), Switzerland. Measurements at the Jungfraujoch are representative for the lower free troposphere above Central Europe. For this aerosol type hardly any information about the &lt;i&gt;f&lt;/i&gt;(RH) is available so far. At this site, &lt;i&gt;f&lt;/i&gt;(RH=85%) varied between 1.2 and 3.3. Measured &lt;i&gt;f&lt;/i&gt;(RH) agreed well with &lt;i&gt;f&lt;/i&gt;(RH) calculated with Mie theory using measurements of the size distribution, chemical composition and hygroscopic diameter growth factors as input. Good &lt;i&gt;f&lt;/i&gt;(RH) predictions at RH&amp;lt;85% were also obtained with a simplified model, which uses the Ångström exponent of &amp;sigma;&lt;sub&gt;sp&lt;/sub&gt;(dry) as input. RH influences further intensive optical aerosol properties. The backscatter fraction decreased by about 30% from 0.128 to 0.089, and the single scattering albedo increased on average by 0.05 at 85% RH compared to dry conditions. These changes in &amp;sigma;&lt;sub&gt;sp&lt;/sub&gt;, backscatter fraction and single scattering albedo have a distinct impact on the radiative forcing of the Jungfraujoch aerosol

Evaluating the capabilities and uncertainties of droplet measurements for the fog droplet spectrometer (FM-100)

Droplet size spectra measurements are crucial to obtain a quantitative microphysical description of clouds and fog. However, cloud droplet size measurements are subject to various uncertainties. This work focuses on the error analysis of two key measurement uncertainties arising during cloud droplet size measurements with a conventional droplet size spectrometer (FM-100): first, we addressed the precision with which droplets can be sized with the FM-100 on the basis of the Mie theory. We deduced error assumptions and proposed a new method on how to correct measured size distributions for these errors by redistributing the measured droplet size distribution using a stochastic approach. Second, based on a literature study, we summarized corrections for particle losses during sampling with the FM-100. We applied both corrections to cloud droplet size spectra measured at the high alpine site Jungfraujoch for a temperature range from 0 °C to 11 °C. We showed that Mie scattering led to spikes in the droplet size distributions using the default sizing procedure, while the new stochastic approach reproduced the ambient size distribution adequately. A detailed analysis of the FM-100 sampling efficiency revealed that particle losses were typically below 10% for droplet diameters up to 10 μm. For larger droplets, particle losses can increase up to 90% for the largest droplets of 50 μm at ambient wind speeds below 4.4 m s&lt;sup&gt;−1&lt;/sup&gt; and even to &gt;90% for larger angles between the instrument orientation and the wind vector (sampling angle) at higher wind speeds. Comparisons of the FM-100 to other reference instruments revealed that the total liquid water content (LWC) measured by the FM-100 was more sensitive to particle losses than to re-sizing based on Mie scattering, while the total number concentration was only marginally influenced by particle losses. Consequently, for further LWC measurements with the FM-100 we strongly recommend to consider (1) the error arising due to Mie scattering, and (2) the particle losses, especially for larger droplets depending on the set-up and wind conditions

Hydrogen-induced ferromagnetism in ZnO single crystals investigated by Magnetotransport

We investigated the electrical and magnetic properties of low-energy hydrogen-implanted ZnO single crystals with hydrogen concentrations up to 3 at.% in the first 20 nm surface layer between 10 K and 300 K. All samples showed clear ferromagnetic hysteresis loops at 300 K with a saturation magnetization up to 4 emu/g. The measured anomalous Hall effect agrees with the hysteresis loops measured by superconducting quantum interferometer device magnetometry. All the H-treated ZnO crystals exhibited a negative magnetoresistance up to the room temperature. The relative magnitude of the anisotropic magnetoresistance reaches 0.4 % at 250 K and 2 % at 10 K, exhibiting an anomalous, non-monotonous behavior and a change of sign below 100 K. All the experimental data indicate that hydrogen atoms alone in a few percent range trigger a magnetic order in a ZnO crystalline state. Hydrogen implantation turns out to be a simpler and effective method to generate a magnetic order in ZnO, which provides interesting possibilities for future applications due to the strong reduction of the electrical resistance

Effects of relative humidity on aerosol light scattering in the Arctic

Aerosol particles experience hygroscopic growth in the ambient atmosphere. Their optical properties – especially the aerosol light scattering – are therefore strongly dependent on the ambient relative humidity (RH). In-situ light scattering measurements of long-term observations are usually performed under dry conditions (RH&amp;gt;30–40%). The knowledge of this RH effect is of eminent importance for climate forcing calculations or for the comparison of remote sensing with in-situ measurements. This study combines measurements and model calculations to describe the RH effect on aerosol light scattering for the first time for aerosol particles present in summer and fall in the high Arctic. For this purpose, a field campaign was carried out from July to October 2008 at the Zeppelin station in Ny-Ålesund, Svalbard. The aerosol light scattering coefficient &amp;sigma;&lt;sub&gt;sp&lt;/sub&gt;(&amp;lambda;) was measured at three distinct wavelengths (λ=450, 550, and 700 nm) at dry and at various, predefined RH conditions between 20% and 95% with a recently developed humidified nephelometer (WetNeph) and with a second nephelometer measuring at dry conditions with an average RH&amp;lt;10% (DryNeph). In addition, the aerosol size distribution and the aerosol absorption coefficient were measured. The scattering enhancement factor &lt;i&gt;f&lt;/i&gt;(RH, &amp;lambda;) is the key parameter to describe the RH effect on &amp;sigma;&lt;sub&gt;sp&lt;/sub&gt;(&amp;lambda;) and is defined as the RH dependent &amp;sigma;&lt;sub&gt;sp&lt;/sub&gt;(RH, &amp;lambda;) divided by the corresponding dry &amp;sigma;&lt;sub&gt;sp&lt;/sub&gt;(RH&lt;sub&gt;dry&lt;/sub&gt;, &amp;lambda;). During our campaign the average &lt;i&gt;f&lt;/i&gt;(RH=85%, λ=550 nm) was 3.24&amp;plusmn;0.63 (mean &amp;plusmn; standard deviation), and no clear wavelength dependence of &lt;i&gt;f&lt;/i&gt;(RH, &amp;lambda;) was observed. This means that the ambient scattering coefficients at RH=85% were on average about three times higher than the dry measured in-situ scattering coefficients. The RH dependency of the recorded &lt;i&gt;f&lt;/i&gt;(RH, &amp;lambda;) can be well described by an empirical one-parameter equation. We used a simplified method to retrieve an apparent hygroscopic growth factor &lt;i&gt;g&lt;/i&gt;(RH), defined as the aerosol particle diameter at a certain RH divided by the dry diameter, using the WetNeph, the DryNeph, the aerosol size distribution measurements and Mie theory. With this approach we found, on average, &lt;i&gt;g&lt;/i&gt;(RH=85%) values to be 1.61&amp;plusmn;0.12 (mean&amp;plusmn;standard deviation). No clear seasonal shift of &lt;i&gt;f&lt;/i&gt;(RH, &amp;lambda;) was observed during the 3-month period, while aerosol properties (size and chemical composition) clearly changed with time. While the beginning of the campaign was mainly characterized by smaller and less hygroscopic particles, the end was dominated by larger and more hygroscopic particles. This suggests that compensating effects of hygroscopicity and size determined the temporal stability of &lt;i&gt;f&lt;/i&gt;(RH, &amp;lambda;). During sea salt influenced periods, distinct deliquescence transitions were observed. At the end we present a method on how to transfer the dry in-situ measured aerosol scattering coefficients to ambient values for the aerosol measured during summer and fall at this location

Effect of hygroscopic growth on the aerosol light-scattering coefficient: A review of measurements, techniques and error sources

Knowledge of the scattering enhancement factor, f(RH), is important for an accurate description of direct aerosol radiative forcing. This factor is defined as the ratio between the scattering coefficient at enhanced relative humidity, RH, to a reference (dry) scattering coefficient. Here, we review the different experimental designs used to measure the scattering coefficient at dry and humidified conditions as well as the procedures followed to analyze the measurements. Several empirical parameterizations for the relationship between f(RH) and RH have been proposed in the literature. These parameterizations have been reviewed and tested using experimental data representative of different hygroscopic growth behavior and a new parameterization is presented. The potential sources of error in f(RH) are discussed. A Monte Carlo method is used to investigate the overall measurement uncertainty, which is found to be around 20 e40% for moderately hygroscopic aerosols. The main factors contributing to this uncertainty are the uncertainty in RH measurement, the dry reference state and the nephelometer uncertainty. A literature survey of nephelometry-based f(RH) measurements is presented as a function of aerosol type. In general, the highest f(RH) values were measured in clean marine environments, with pollution having a major influence on f(RH). Dust aerosol tended to have the lowest reported hygroscopicity of any of the aerosol types studied. Major open questions and suggestions for future research priorities are outlined.This work was supported by the Andalusia Regional Government through projects P10-RNM-6299 and P12-RNM-2409; by the Spanish Ministry of Economy and Competitiveness and FEDER through project CGL2013_45410-R; and by European Union’s Horizon 2020 research and innovation programme under grant agreement No 654109, ACTRIS-2. G. Titos was partially funded by Programa del Plan Propio de Investigación “Contrato Puente” of the University of Granada. We thank the Stockholm International Meteorological Institute (IMI) for travel support of G. Titos

Deeply Virtual Compton Scattering

We study in QCD the physics of deeply-virtual Compton scattering (DVCS)---the virtual Compton process in the large s and small t kinematic region. We show that DVCS can probe a new type of off-forward parton distributions. We derive an Altarelli-Parisi type of evolution equations for these distributions. We also derive their sum rules in terms of nucleon form-factors of the twist-two quark and gluon operators. In particular, we find that the second sum rule is related to fractions of the nucleon spin carried separately by quarks and gluons. We estimate the cross section for DVCS and compare it with the accompanying Bethe-Heitler process at CEBAF and HERMES kinematics.Comment: 20 pages, 2 figures, replaced with the version to appear in Phys. Rev.

Late summer transition from a free-tropospheric to boundary layer source of Aitken mode aerosol in the high Arctic

In the Arctic, the aerosol budget plays a particular role in determining the behaviour of clouds, which are important for the surface energy balance and thus for the region’s climate. A key question is the extent to which cloud condensation nuclei in the high Arctic summertime boundary layer are controlled by local emission and formation processes as opposed to transport from outside. Each of these sources is likely to respond differently to future changes in ice cover. Here we use a global model and observations from ship and aircraft field campaigns to understand the source of high Arctic aerosol in late summer. We find that particles formed remotely, i.e. at lower latitudes, outside the Arctic, are the dominant source of boundary layer Aitken mode particles during the sea ice melt period up to the end of August. Particles from such remote sources, entrained into the boundary layer from the free troposphere, account for nucleation and Aitken mode particle concentrations that are otherwise underestimated by the model. This source from outside the high Arctic declines as photochemical rates decrease towards the end of summer, and is largely replaced by local new particle formation driven by iodic acid emitted from the surface and associated with freeze-up. Such a local source is consistent with strong fluctuations in nucleation mode concentrations that occur in September. Our results suggest a high-Arctic aerosol regime shift in late summer, and only after this shift do cloud condensation nuclei become sensitive to local aerosol processes