3,930 research outputs found
Bounding film drainage in common thin films
A review of thin film drainage models is presented in which the predictions of thinning
velocities and drainage times are compared to reported values on foam and emulsion films
found in the literature. Free standing films with tangentially immobile interfaces and suppressed electrostatic repulsion are considered, such as those studied in capillary cells.
The experimental thinning velocities and drainage times of foams and emulsions are shown to be bounded by predictions from the Reynolds and the theoretical MTsR equations. The semi-empirical MTsR and the surface wave equations were the most consistently accurate with all of the films considered. These results are used in an
accompanying paper to develop scaling laws that bound the critical film thickness of foam and emulsion films
Quantum Criticality of an Ising-like Spin-1/2 Antiferromagnetic Chain in Transverse Magnetic Field
We report on magnetization, sound velocity, and magnetocaloric-effect
measurements of the Ising-like spin-1/2 antiferromagnetic chain system
BaCoVO as a function of temperature down to 1.3 K and applied
transverse magnetic field up to 60 T. While across the N\'{e}el temperature of
K anomalies in magnetization and sound velocity confirm the
antiferromagnetic ordering transition, at the lowest temperature the
field-dependent measurements reveal a sharp softening of sound velocity
and a clear minimum of temperature at T,
indicating the suppression of the antiferromagnetic order. At higher fields,
the curve shows a broad minimum at T, accompanied by a
broad minimum in the sound velocity and a saturation-like magnetization. These
features signal a quantum phase transition which is further characterized by
the divergent behavior of the Gr\"{u}neisen parameter . By contrast, around the critical field, the
Gr\"{u}neisen parameter converges as temperature decreases, pointing to a
quantum critical point of the one-dimensional transverse-field Ising model.Comment: Phys. Rev. Lett., to appea
Distinct magnetic regimes through site-selective atom substitution in the frustrated quantum antiferromagnet CsCuClBr
We report on a systematic study of the magnetic properties on single crystals
of the solid solution CsCuClBr (0 x 4), which
include the two known end-member compounds CsCuCl and CsCuBr,
classified as quasi-two-dimensional quantum antiferromagnets with different
degrees of magnetic frustration. By comparative measurements of the magnetic
susceptibility () on as many as eighteen different Br concentrations,
we found that the inplane and out-of-plane magnetic correlations, probed by the
position and height of a maximum in the magnetic susceptibility, respectively,
do not show a smooth variation with x. Instead three distinct concentration
regimes can be identified, which are separated by critical concentrations
x = 1 and x = 2. This unusual magnetic behavior can be explained
by considering the structural peculiarities of the materials, especially the
distorted Cu-halide tetrahedra, which support a site-selective replacement of
Cl- by Br- ions. Consequently, the critical concentrations x (x)
mark particularly interesting systems, where one (two) halidesublattice
positions are fully occupied.Comment: 15 pages, 4 figure
Improved genome editing in human cell lines using the CRISPR method
The Cas9/CRISPR system has become a popular choice for genome editing. In this system, binding of a single guide (sg) RNA to a cognate genomic sequence enables the Cas9 nuclease to induce a double-strand break at that locus. This break is next repaired by an error-prone mechanism, leading to mutation and gene disruption. In this study we describe a range of refinements of the method, including stable cell lines expressing Cas9, and a PCR based protocol for the generation of the sgRNA. We also describe a simple methodology that allows both elimination of Cas9 from cells after gene disruption and re-introduction of the disrupted gene. This advance enables easy assessment of the off target effects associated with gene disruption, as well as phenotype-based structure-function analysis. In our study, we used the Fan1 DNA repair gene as control in these experiments. Cas9/CRISPR-mediated Fan1 disruption occurred at frequencies of around 29%, and resulted in the anticipated spectrum of genotoxin hypersensitivity, which was rescued by re-introduction of Fan1
Direct observation of the evolving metal–support interaction of individual cobalt nanoparticles at the titania and silica interface
Understanding the metal–support interaction (MSI) is crucial to comprehend how the catalyst support affects performance and whether this interaction can be exploited in order to design new catalysts with enhanced properties. Spatially resolved soft X-ray absorption spectroscopy (XAS) in combination with Atomic Force Microscopy (AFM) and Scanning Helium Ion-Milling Microscopy (SHIM) has been applied to visualise and characterise the behaviour of individual cobalt nanoparticles (CoNPs) supported on two-dimensional substrates (SiOxSi(100) (x < 2) and rutile TiO2(110)) after undergoing reduction–oxidation–reduction (ROR). The behaviour of the Co species is observed to be strongly dependent on the type of support. For SiOxSi a weaker MSI between Co and the support allows a complete reduction of CoNPs although they migrate and agglomerate. In contrast, a stronger MSI of CoNPs on TiO2 leads to only a partial reduction under H2 at 773 K (as observed from Co L3-edge XAS data) due to enhanced TiO2 binding of surface-exposed cobalt. SHIM data revealed that the interaction of the CoNPs is so strong on TiO2, that they are seen to spread at and below the surface and even to migrate up to ∼40 nm away. These results allow us to better understand deactivation phenomena and additionally demonstrate a new understanding concerning the nature of the MSI for Co/TiO2 and suggest that there is scope for careful control of the post-synthetic thermal treatment for the tuning of this interaction and ultimately the catalytic performance
A Crucial Test for Color-Octet Production Mechanism in Z^0 Decays
The direct production rates of -wave charmonia in the decays of is
evaluated. The color-octet production processes are shown to have distinctively large branching ratios, the same order
of magnitude as that of prodution, as compared with other -wave
charmonium production mechanisms. This may suggest a crucial channel to test
the color-octet mechanism as well as to observe the -wave charmonium states
in decays. In addition, a signal for the charmonium as strong as
or with large transverse momentum at the Tevatron should
also be observed.Comment: 14 pages in LaTex (3 figures in PS-file
Critical Phenomena at the Antiferromagnetic Phase Transition of Azurite
We report on high-resolution acoustic, specific-heat and thermal expansion
measurements in the vicinity of the antiferromagnetic phase transition at T_N =
1.88 K on a high-quality single crystal of the natural mineral azurite. A
detailed investigation of the critical contribution to the various quantities
at T_N is presented. The set of critical exponents and amplitude ratios of the
singular contributions above and below the transition indicate that the system
can be reasonably well described by a three-dimensional Heisenberg
antiferromagnet.Comment: 9 pages, 3 figures, proceedings of ICM 2012, JKP
Gluon fragmentation to ^3D_J quarkonia
We present a calculation of the leading order QCD fragmentation functions for
gluons to split into spin-triplet D-wave quarkonia. We apply them to evaluate
the gluon fragmentation contributions to inclusive ^3D_J quarkonium production
at large transverse momentum processes like the Tevatron and find that the
D-wave quarkonia, especially the charmonium 2^{--} state, could be observed
through color-octet mechanism with present luminosity. Since there are
distinctively large gaps between the contributions of two different (i.e,
color-singlet and color-octet) quarkonium production mechanisms, our results
may stand as a unique test to NRQCD color-octet quarkonium production
mechanism.Comment: 15 pages in LaTex (2 figures in PS-file
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