A direct time series comparison between the La Jolla and Belfast radiocarbon records

For many years it has been widely assumed that the variations in the level of atmospheric carbon-14 were due to statistical fluctuations arising from experimental error. This is understandable since the signal/noise ratio is very low and the time sequences representing the variations are strongly stochastic. Interlaboratory comparisons show that baseline variations in the absolute value of the carbon-14 concentration do exist. However, assuming linearity, the delta 14C values are independent of these. The importance of assessing the quantitive reality of the delta 14C values is based upon their expression of the interplanetary cosmic ray source function, because in the range of 100 to 1000 year periods, there appears to be no evidence that the Earth's magnetic field is the source modulating function. Therefore the modulation is either due to changes in the solar atmosphere propagated out into the solar wind, or extra-heliospheric pressure effects, but these appear to be unlikely for the periods noted here. The recent availability of the new high quality Belfast time sequence of delta 14C now permits a simple mutual assessment of the several sequences which are available. Since the La Jolla record has been a standard for many years , these two were chosen for a simple comparison. Although differences exist, the close agreement between these two sequences, one carried out on White mountain Bristlecone pines, and the other done using Irish peat bog wood, is striking. This correlation between the two strongly reinforces the statistical view that the delta 14C record is that of real interplanetary modulation of the cosmic ray source leading to the generation of atmospheric 14C

A closer look at nitrification in pelagic sediments

Nutrient profiles in Southwest Pacific interstitial solutions suggest that in environments of oxic pelagic sedimentation microbially mediated nitrification is recognizable as a two-step process. During the first step partially oxidized nitrogenous intermediaries accumulate in distinctive ammonia and nitrite maxima along with nitrate. During the second step nitrification continues and all intermediate species are fully oxidized to nitrate. Both steps occur within a zone that corresponds in thickness to the biologically active surface layer. Similarly, experimental nitrogen regeneration from decomposition of plankton in seawater (VON BRAND and RAKESTRAW, 1941: VON BRAND et al., 1942) suggests that each step corresponds to a distinct reaction in the microbially mediated transformation of N-org → NH3 → NO2 → NO3. The resolution of distinct reaction zones in pore water nutrient profiles possibly depends on the nature and mode of supply of the organic matter undergoing nitrification or reflects the spatial succession downcore of microbial populations capable of deamination, ammonium oxidation and nitrite oxidation, respectively. Finally, stoichiometric ratios of nutrients in the free water column - here demonstrated on published data from Saanich Inlet - reflect the same two steps of nitrification as delineated by the dissolved pore water species. Future pore water studies should include dissolved oxygen measurements as well as accurate ∑CO2, PO4 and nitrogenous species profiles, to verify and better quantify these separate steps in nitrification mechanism of oxic pelagic sediments

In situ measurement of fluid flow from cold seeps at active continental margins

In situ measurement of fluid flow rates from active margins is an important parameter in evaluating dissolved mass fluxes and global geochemical balances as well as tectonic dewatering during developments of accretionary prisms. We have constructed and deployed various devices that allow for the direct measurement of this parameter. An open bottom barrel with an exhaust port at the top and equipped with a mechanical flowmeter was initially used to measure flow rates in the Cascadia accretionary margin during an Alvin dive program in 1988. Sequentially activated water bottles inside the barrel sampled the increase of venting methane in the enclosed body of water. Subsequently, a thermistor flowmeter was developed to measure flow velocities from cold seeps. It can be used to measure velocities between 0.01 and 50 cm s−1, with a response time of 200 ms. It was deployed again by the submersible Alvin in visits to the Cascadia margin seeps (1990) and in conjunction with sequentially activated water bottles inside the barrel. We report the values for the flow rates based on the thermistor flowmeter and estimated from methane flux calculations. These results are then compared with the first measurement at Cascadia margin employing the mechanical flowmeter. The similarity between water flow and methane expulsion rates over more than one order of magnitude at these sites suggests that the mass fluxes obtained by our in situ devices may be reasonably realistic values for accretionary margins. These values also indicate an enormous variability in the rates of fluid expulsion within the same accretionary prism. Finally, during a cruise to the active margin off Peru, another version of the same instrument was deployed via a TV-controlled frame within an acoustic transponder net from a surface ship, the R.V. Sonne. The venting rates obtained with the thermistor flowmeter used in this configuration yielded a value of 4411 m−2 day−1 at an active seep on the Peru slope. The ability for deployment of deep-sea instruments capable of measuring fluid flow rates and dissolved mass fluxes from conventional research vessels will allow easier access to these seep sites and a more widespread collection of the data needed to evaluate geochemical processes resulting from venting at cold seeps on a global basis. Comparison of the in situ flow rates from steady-state compactive dewatering models differ by more than 4 orders of magnitude. This implies that only a small area of the margin is venting and that there must be recharge zones associated with venting at convergent margin

A [4Fe-4S]-Fe(CO)(CN)-L-cysteine intermediate is the first organometallic precursor in [FeFe] hydrogenase H-cluster bioassembly.

Biosynthesis of the [FeFe] hydrogenase active site (the 'H-cluster') requires the interplay of multiple proteins and small molecules. Among them, the radical S-adenosylmethionine enzyme HydG, a tyrosine lyase, has been proposed to generate a complex that contains an Fe(CO)2(CN) moiety that is eventually incorporated into the H-cluster. Here we describe the characterization of an intermediate in the HydG reaction: a [4Fe-4S][(Cys)Fe(CO)(CN)] species, 'Complex A', in which a CO, a CN- and a cysteine (Cys) molecule bind to the unique 'dangler' Fe site of the auxiliary [5Fe-4S] cluster of HydG. The identification of this intermediate-the first organometallic precursor to the H-cluster-validates the previously hypothesized HydG reaction cycle and provides a basis for elucidating the biosynthetic origin of other moieties of the H-cluster

Stratigraphy and Sedimentation Rates from Oxygen Isotope Composition, Organic Carbon Content, and Grain-Size Distribution at the Peru Upwelling Region: Holes 680B and 686B

A high-resolution chronostratigraphy was established for Holes 680B and 686B, drilled during Ocean Drilling Program (ODP) Leg 112 off Peru. The stratigraphy is largely based on oxygen isotopes of benthic foraminifers and supplemented by data for organic-carbon content and sediment texture. At both drill sites, during isotope Stage 1, the sedimentation rate was more than twice that of the older stages, which partly reflects lack of compaction in the youngest sediments. In Hole 680B, located at the center of a modern coastal upwelling cell in a water depth of 252.5 m, the mean sedimentation rate is 6.6 cm/k.y. in isotope Stages 1 through 15. Hole 686B lies at the fringe of another active upwelling cell off Capo Nazca in a water depth of 447 m. A prominent hiatus is evident between 105 and 120 m below seafloor (bsf). The mean sedimentation rate is 17.1 cm/k.y. above the hiatus (isotope Stages 1 through 15) and about 100 cm/k.y. below

Probing the Edge of the Solar System: Formation of an Unstable Jet-Sheet

The Voyager spacecraft is now approaching the edge of the solar system. Near the boundary between the solar system and the interstellar medium we find that an unstable ``jet-sheet'' forms. The jet-sheet oscillates up and down due to a velocity shear instability. This result is due to a novel application of a state-of-art 3D Magnetohydrodynamic (MHD) code with a highly refined grid. We assume as a first approximation that the solar magnetic and rotation axes are aligned. The effect of a tilt of the magnetic axis with respect to the rotation axis remains to be seen. We include in the model self-consistently magnetic field effects in the interaction between the solar and interstellar winds. Previous studies of this interaction had poorer spatial resolution and did not include the solar magnetic field. This instability can affect the entry of energetic particles into the solar system and the intermixing of solar and interstellar material. The same effect found here is predicted for the interaction of rotating magnetized stars possessing supersonic winds and moving with respect to the interstellar medium, such as O stars.Comment: 9 pages, 4 figures, accepted for publication in ApJ

Stationary field-aligned MHD flows at astropauses and in astrotails. Principles of a counterflow configuration between a stellar wind and its interstellar medium wind

A stellar wind passing through the reverse shock is deflected into the astrospheric tail and leaves the stellar system either as a sub-Alfvenic or as a super-Alfvenic tail flow. An example is our own heliosphere and its heliotail. We present an analytical method of calculating stationary, incompressible, and field-aligned plasma flows in the astrotail of a star. We present a recipe for constructing an astrosphere with the help of only a few parameters, like the inner Alfven Mach number and the outer Alfven Mach number, the magnetic field strength within and outside the stellar wind cavity, and the distribution of singular points of the magnetic field within these flows. Within the framework of a one-fluid approximation, it is possible to obtain solutions of the MHD equations for stationary flows from corresponding static MHD equilibria, by using noncanonical mappings of the canonical variables. The canonical variables are the Euler potentials of the magnetic field of magnetohydrostatic equilibria. Thus we start from static equilibria determined by the distribution of magnetic neutral points, and assume that the Alfven Mach number for the corresponding stationary equilibria is finite. The topological structure determines the geometrical structure of the interstellar gas - stellar wind interface. Additional boundary conditions like the outer magnetic field and the jump of the magnetic field across the astropause allow determination of the noncanonical transformations. This delivers the strength of the magnetic field at every point in the astrotail region beyond the reverse shock. The mathematical technique for describing such a scenario is applied to astrospheres in general, but is also relevant for the heliosphere. It shows the restrictions of the outer and the inner magnetic field strength in comparison with the corresponding Alfven Mach numbers in the case of subalfvenic flows.Comment: 19 pages, 17 figures, accepted for publication in A&

Tectonic history of the northern Peru convergent margin during the past 400 ka

The late Pleistocene tectonic history of the northern Peru convergent margin can be retraced using data collected during deep-sea dives of the submersible Nautile combined with a recent Hydrosweep survey conducted off Peru at lat 5°-6°S by the R/V Sonne. During the past 400 ka, a broad rollover fold formed in the middle slope area, in association with a major seaward-dipping detachment fault. A catastrophic debris avalanche occurred as the result of oversteepening of the landward flank of the rollover fold. The gravity failure of the slope, previously recognized by SeaBeam mapping, occurred at 13.8 ±2.7 ka and produced a destructive tsunami