Optimal control of a leaking qubit

Physical implementations of quantum bits can contain coherent transitions to energetically close non-qubit states. In particular, for anharmonic oscillator systems such as the superconducting phase qubit and the transmon a two-level approximation is insufficient. We apply optimal control theory to the envelope of a resonant Rabi pulse in a qubit in the presence of a single, weakly off-resonant leakage level. The gate error of a spin flip operation reduces by orders of magnitude compared to simple pulse shapes. Near-perfect gates can be achieved for any pulse duration longer than an intrinsic limit given by the nonlinearity. The pulses can be understood as composite sequences that refocus the leakage transition. We also discuss ways to improve the pulse shapes.Comment: 4 pages, 2 figure

Optimal control of a qubit coupled to a non-Markovian environment

A central challenge for implementing quantum computing in the solid state is decoupling the qubits from the intrinsic noise of the material. We investigate the implementation of quantum gates for a paradigmatic, non-Markovian model: A single qubit coupled to a two-level system that is exposed to a heat bath. We systematically search for optimal pulses using a generalization of the novel open systems Gradient Ascent Pulse Engineering (GRAPE) algorithm. We show and explain that next to the known optimal bias point of this model, there are optimal shapes which refocus unwanted terms in the Hamiltonian. We study the limitations of controls set by the decoherence properties. This can lead to a significant improvement of quantum operations in hostile environments.Comment: 5 pages, 3 figures, improved pulse shape

Non-Markovian Quantum Jumps in Excitonic Energy Transfer

We utilize the novel non-Markovian quantum jump (NMQJ) approach to stochastically simulate exciton dynamics derived from a time-convolutionless master equation. For relevant parameters and time scales, the time-dependent, oscillatory decoherence rates can have negative regions, a signature of non-Markovian behavior and of the revival of coherences. This can lead to non-Markovian population beatings for a dimer system at room temperature. We show that strong exciton-phonon coupling to low frequency modes can considerably modify transport properties. We observe increased exciton transport, which can be seen as an extension of recent environment-assisted quantum transport (ENAQT) concepts to the non-Markovian regime. Within the NMQJ method, the Fenna-Matthew-Olson protein is investigated as a prototype for larger photosynthetic complexes.Comment: 9 pages, 4 figures, submitted to Journal of Chemical Physic

Symmetry-enhanced supertransfer of delocalized quantum states

Coherent hopping of excitation rely on quantum coherence over physically extended states. In this work, we consider simple models to examine the effect of symmetries of delocalized multi-excitation states on the dynamical timescales, including hopping rates, radiative decay, and environmental interactions. While the decoherence (pure dephasing) rate of an extended state over N sites is comparable to that of a non-extended state, superradiance leads to a factor of N enhancement in decay and absorption rates. In addition to superradiance, we illustrate how the multi-excitonic states exhibit `supertransfer' in the far-field regime: hopping from a symmetrized state over N sites to a symmetrized state over M sites at a rate proportional to MN. We argue that such symmetries could play an operational role in physical systems based on the competition between symmetry-enhanced interactions and localized inhomogeneities and environmental interactions that destroy symmetry. As an example, we propose that supertransfer and coherent hopping play a role in recent observations of anomolously long diffusion lengths in nano-engineered assembly of light-harvesting complexes.Comment: 6 page

Stochastic exclusion processes versus coherent transport

Stochastic exclusion processes play an integral role in the physics of non-equilibrium statistical mechanics. These models are Markovian processes, described by a classical master equation. In this paper a quantum mechanical version of a stochastic hopping process in one dimension is formulated in terms of a quantum master equation. This allows the investigation of coherent and stochastic evolution in the same formal framework. The focus lies on the non-equilibrium steady state. Two stochastic model systems are considered, the totally asymmetric exclusion process and the fully symmetric exclusion process. The steady state transport properties of these models is compared to the case with additional coherent evolution, generated by the $XX$-Hamiltonian

Bichromatic Driving of a Solid State Cavity QED System

The bichromatic driving of a solid state cavity quantum electrodynamics system is used to probe cavity dressed state transitions and observe coherent interaction between the system and the light field. We theoretically demonstrate the higher order cavity-dressed states, supersplitting, and AC stark shift in a solid state system comprised of a quantum dot strongly coupled to a photonic crystal cavity for on- and far off-resonant cases. For the off-resonant case, phonons mediate off-resonant coupling between the quantum dot and the photonic resonator, a phenomenon unique to solid state cavity quantum electrodynamics.Comment: 8 pages 6 figure

An efficient method to calculate excitation energy transfer in light harvesting systems. Application to the FMO complex

A master equation, derived from the non-Markovian quantum state diffusion (NMQSD), is used to calculate excitation energy transfer in the photosynthetic Fenna-Matthews-Olson (FMO) pigment-protein complex at various temperatures. This approach allows us to treat spectral densities that contain explicitly the coupling to internal vibrational modes of the chromophores. Moreover, the method is very efficient, with the result that the transfer dynamics can be calculated within about one minute on a standard PC, making systematic investigations w.r.t. parameter variations tractable. After demonstrating that our approach is able to reproduce the results of the numerically exact hierarchical equations of motion (HEOM) approach, we show how the inclusion of vibrational modes influences the transfer

Optimal number of pigments in photosynthetic complexes

We study excitation energy transfer in a simple model of photosynthetic complex. The model, described by Lindblad equation, consists of pigments interacting via dipole-dipole interaction. Overlapping of pigments induces an on-site energy disorder, providing a mechanism for blocking the excitation transfer. Based on the average efficiency as well as robustness of random configurations of pigments, we calculate the optimal number of pigments that should be enclosed in a pigment-protein complex of a given size. The results suggest that a large fraction of pigment configurations are efficient as well as robust if the number of pigments is properly chosen. We compare optimal results of the model to the structure of pigment-protein complexes as found in nature, finding good agreement.Comment: 20 pages, 7 figures; v2.: new appendix, published versio