Thermal stability of the cu-ceo2 interface on silica and alumina, and its relation with activity in the oxidation reaction of co and the decomposition of n2o

Indexación: Scopus; Scielo.The effect of the support on the formation of the Cu-CeO2 interface and its thermal stability after calcination at 500, 700 and 900 °C is studied. The supports used are SiO2, because of its inert character, and Al2O3, because it can interact with the Cu and Ce species on the surface. The catalysts were characterized by BET, XRD, UV-vis DRS, and TPR with H2. The catalytic activity in the CO oxidation reactions with O2 at low temperature and the decomposition of N2O were selected to visualize the effect of temperature on the concentration of Cu-CeO2 interfacial sites. The results show that at a calcination temperature of 500 °C the formation of the Cu-CeO2 interface is favored over the SiO2 support. However, the stability of the Cu-CeO2 interface on SiO2 is much lower than on Al2O3, causing a substantial decrease of the interfacial sites calcining at 700 °C, and segregation of the Cu and Ce species on the surface of the silica, with complete loss of the catalytic activity in both reactions when calcining at 900 °C. In contrast, on alumina the Cu-CeO2 interface is more stable and presents a significant catalytic activity in both reactions, even when calcining at 900 °C. The characterization results show that the sintering process of Cu species and CeO2 particles is less on the alumina support due to the greater interaction of the Cu and Ce with this support. © 2018 Sociedad Chilena de Quimica.all rights reserved.https://scielo.conicyt.cl/scielo.php?script=sci_arttext&pid=S0717-97072018000304102&lng=en&nrm=iso&tlng=e

Evaluación Bidimensional y Tridimensional de la Vía Aérea Superior

Indexación: Scopus; Scielo.The aim of this study was to validate and correlate the two-dimensional (2D) with the three-dimensional (3D) measures of the upper airway assessment. Lateral cephalograms and cone beam CT of 100 adult subjects were used to perform a 2D and 3D assessment of the upper airway. Spearman correlation coefficient was used to determine whether there was correlation between variables. Additionally, specificity, sensitivity, negative predictive value and positive predictive value was calculated for the 2D assessment of the upper airway. Correlation between all two and three dimensional variables was found. In the nasopharynx and oropharynx, a weak correlation (r <0.51) was found; in the oropharynx a moderate one (0.50 <r <0.76). The validity tests of the 2D assessment resulted in a 73% sensitivity, 45% specificity, 93% negative predictive value and 14% positive predictive value for the nasopharynx; 100% sensitivity, 51% specificity, 100% negative predictive value and 6% positive predictive value in the oropharynx and 100% sensitivity, 71% specificity, 100% negative predictive value and 13% positive predictive value in the hypopharynx. There is a weak correlation between the 2D and 3D assessment of the upper airway. However, the lateral cephalogram has a high sensitivity and high negative predictive value, therefore, an additional complementary examination would not be necessary if the 2D assessment of the upper airway throws a normal result.http://ref.scielo.org/mpkrn

Activity of alumina supported fe catalysts for N2O decomposition: Effects of the iron content and thermal treatment

Indexación: Scopus.The activity of Fe2O3/Al2O3 catalysts prepared by impregnation of Al2O3 with different amounts of Fe and calcination temperatures (650 and 900 °C) in the direct N2O decomposition reaction was studied. High calcination temperature was introduced to study the effect of "aging", which are the conditions prevailing in the process-gas option for N2O abatement. The catalysts were characterized by BET, XRD, UV-DRS, and H2-TPR. The incorporation of Fe promotes the alumina phase transition (g-Al2O3 to a-Al2O3) when the catalysts are calcined at 900 °C, which is accompanied by a decrease in the specifc area. The activity of the catalysts and the specifc surface area depend on Fe loading and calcination temperature. It was found that highly dispersed Fe species are more active than bulk type Fe2O3 particles. We conclude that Fe2O3/Al2O3 catalysts prepared by impregnation method are active in the decomposition of N2O, to be used at low or high reaction temperatures (tail-gas or process-gas treatments, respectively), as part of nitric acid production plant. © 2018 Sociedad Chilena de Quimica. All rights reserved.https://scielo.conicyt.cl/pdf/jcchems/v62n4/0717-9324-jcchems-62-04-3752.pd

Menopausia, el inicio del envejecimiento de las mujeres chilenas. Un estudio cualitativo

Indexación: Scopus.Objective. To develop the meaning of menopause of a group of post-menopausal women and their relationship with aging. Methods. Qualitative descriptive study on 15 Chilean women that completed a taped face-to-face in depth interview that were interpreted according to Krippendorff. Results. A qualitative content analysis revealed the presence of two themes: (a) Cessation of women's reproductive stage and (b) a life transition to aging. Conclusion. Women perceived their menopause as the beginning of aging focusing on the end of fertility and the social connotation that this new role implies. Feeling old 10 years before the customary beginning of old age is an important starting point to be incorporated in women's health education.http://ref.scielo.org/x7bfh

Stabilization arising from PGEM : a review and further developments

The aim of this paper is twofold. First, we review the recent Petrov-Galerkin enriched method (PGEM) to stabilize numerical solutions of BVP's in primal and mixed forms. Then, we extend such enrichment technique to a mixed singularly perturbed problem, namely, the generalized Stokes problem, and focus on a stabilized finite element method arising in a natural way after performing static condensation. The resulting stabilized method is shown to lead to optimal convergences, and afterward, it is numerically validated

Determination of Frequency and Distribution of Hessian Fly (Diptera: Cecidomyiidae) Biotypes in the Northeastern Soft Wheat Region

Fifteen collections of Hessian flies from the northern soft winter wheat region of the United States were used to determine the composition and frequency of biotypes. The wheat cultivars \u27Seneca\u27 (H7Hs), \u27Monon\u27 (H3), \u27Knox 62\u27 (~, H7Hg), and \u27Abe\u27 (Hs) were used as differentials. Biotypes J and L replaced biotype B as the prevalent biotype in Indiana, since wheat cultivars having the Hs and the H6 genes have been grown. Biotype GP, the least virulent of any Hessian fly biotypes, was still present in New York indicating that wheat cuItivars with no genes for resistance are still being grown there. The genetic variability of Hessian fly biotypes that enables them to overcome the resistance in wheat cultivars is discussed

An efficient buds culture method for the regeneration via somatic embryogenesis of table grapes 'Red Globe' and 'Flame Seedless'

Research Note

Discovery of 6.035GHz Hydroxyl Maser Flares in IRAS18566+0408

We report the discovery of 6.035GHz hydroxyl (OH) maser flares toward the massive star forming region IRAS18566+0408 (G37.55+0.20), which is the only region known to show periodic formaldehyde (4.8 GHz H2CO) and methanol (6.7 GHz CH3OH) maser flares. The observations were conducted between October 2008 and January 2010 with the 305m Arecibo Telescope in Puerto Rico. We detected two flare events, one in March 2009, and one in September to November 2009. The OH maser flares are not simultaneous with the H2CO flares, but may be correlated with CH3OH flares from a component at corresponding velocities. A possible correlated variability of OH and CH3OH masers in IRAS18566+0408 is consistent with a common excitation mechanism (IR pumping) as predicted by theory.Comment: Accepted for publication in the Astrophysical Journa

High Resolution Observations of the Massive Protostar in IRAS18566+0408

We report 3 mm continuum, CH3CN(5-4) and 13CS(2-1) line observations with CARMA, in conjunction with 6 and 1.3 cm continuum VLA data, and 12 and 25 micron broadband data from the Subaru Telescope toward the massive proto-star IRAS18566+0408. The VLA data resolve the ionized jet into 4 components aligned in the E-W direction. Radio components A, C, and D have flat cm SEDs indicative of optically thin emission from ionized gas, and component B has a spectral index alpha = 1.0, and a decreasing size with frequency proportional to frequency to the -0.5 power. Emission from the CARMA 3 mm continuum, and from the 13CS(2-1), and CH3CN(5-4) spectral lines is compact (i.e. < 6700 AU), and peaks near the position of VLA cm source, component B. Analysis of these lines indicates hot, and dense molecular gas, typical for HMCs. Our Subaru telescope observations detect a single compact source, coincident with radio component B, demonstrating that most of the energy in IRAS18566+0408 originates from a region of size < 2400 AU. We also present UKIRT near-infrared archival data for IRAS18566+0408 which show extended K-band emission along the jet direction. We detect an E-W velocity shift of about 10 km/sec over the HMC in the CH3CN lines possibly tracing the interface of the ionized jet with the surrounding core gas. Our data demonstrate the presence of an ionized jet at the base of the molecular outflow, and support the hypothesis that massive protostars with O-type luminosity form with a mechanism similar to lower mass stars