943 research outputs found

    Strengthening America's Best Idea: An Independent Review of the National Park Service's Natural Resource Stewardship and Science Directorate

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    NRSS requested that an independent panel of the National Academy conduct a review of its effectiveness in five core functions, its relationships with key internal stakeholders, and its performance measurement system. Among other things, the National Park Service's Natural Resource Stewardship and Science Directorate (NRSS) is responsible for providing usable natural and social science information throughout the National Park Service (NPS). NRSS leadership requested this review of the directorate's performance on five core functions, its relationships with key internal NPS stakeholders, and its performance measurement system.Main FindingsThe panel determined that NRSS is a highly regarded organization that provides independent, credible scientific expertise and technical information. The panel also found that NRSS and NPS have additional opportunities to advance natural resource stewardship throughout the Service. If implemented, the panel's eight major recommendations will: (1) help the Service respond to the parks' environmental challenges while raising public awareness about the condition of these special places; (2) strengthen NRSS as an organization; (3) promote scientifically based decision-making at the national, regional, and park levels; and (4) improve the existing performance measurement system

    Gated nonlinear transport in organic polymer field effect transistors

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    We measure hole transport in poly(3-hexylthiophene) field effect transistors with channel lengths from 3 μ\mum down to 200 nm, from room temperature down to 10 K. Near room temperature effective mobilities inferred from linear regime transconductance are strongly dependent on temperature, gate voltage, and source-drain voltage. As TT is reduced below 200 K and at high source-drain bias, we find transport becomes highly nonlinear and is very strongly modulated by the gate. We consider whether this nonlinear transport is contact limited or a bulk process by examining the length dependence of linear conduction to extract contact and channel contributions to the source-drain resistance. The results indicate that these devices are bulk-limited at room temperature, and remain so as the temperature is lowered. The nonlinear conduction is consistent with a model of Poole-Frenkel-like hopping mechanism in the space-charge limited current regime. Further analysis within this model reveals consistency with a strongly energy dependent density of (localized) valence band states, and a crossover from thermally activated to nonthermal hopping below 30 K.Comment: 22 pages, 7 figures, accepted to J. Appl. Phy

    Extensions of Effective Medium Theory of Transport in Disordered Systems

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    Effective medium theory of transport in disordered systems, whose basis is the replacement of spatial disorder by temporal memory, is extended in several practical directions. Restricting attention to a 1-dimensional system with bond disorder for specificity, a transformation procedure is developed to deduce, from given distribution functions characterizing the system disorder, explicit expressions for the memory functions. It is shown how to use the memory functions in the Lapace domain forms in which they first appear, and in the time domain forms which are obtained via numerical inversion algorithms, to address time evolution of the system beyond the asymptotic domain of large times normally treated. An analytic but approximate procedure is provided to obtain the memories, in addition to the inversion algorithm. Good agreement of effective medium theory predictions with numerically computed exact results is found for all time ranges for the distributions used except near the percolation limit as expected. The use of ensemble averages is studied for normal as well as correlation observables. The effect of size on effective mediumtheory is explored and it is shown that, even in the asymptotic limit, finite size corrections develop to the well known harmonic mean prescription for finding the effective rate. A percolation threshold is shown to arise even in 1-d for finite (but not infinite) systems at a concentration of broken bonds related to the system size. Spatially long range transfer rates are shown to emerge naturally as a consequence of the replacement of spatial disorder by temporal memories, in spite of the fact that the original rates possess nearest neighbor character. Pausing time distributions in continuous time random walks corresponding to the effective medium memories are calculated.Comment: 15 pages, 11 figure

    Effects of disorder in location and size of fence barriers on molecular motion in cell membranes

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    The effect of disorder in the energetic heights and in the physical locations of fence barriers encountered by transmembrane molecules such as proteins and lipids in their motion in cell membranes is studied theoretically. The investigation takes as its starting point a recent analysis of a periodic system with constant distances between barriers and constant values of barrier heights, and employs effective medium theory to treat the disorder. The calculations make possible, in principle, the extraction of confinement parameters such as mean compartment sizes and mean intercompartmental transition rates from experimentally reported published observations. The analysis should be helpful both as an unusual application of effective medium theory and as an investigation of observed molecular movements in cell membranes.Comment: 9 pages, 5 figure

    Molecular simulation studies in the supercritical region

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    In our work, we employed molecular dynamics and Monte Carlo (MC) simulations to investigate the supercritical phase of carbon dioxide near its critical point. Three systems have been studied. The pure carbon dioxide, mixture methane + carbon dioxide at infinite dilution of supercritical carbon dioxide and water + carbon dioxide at infinite dilution of supercritical carbon dioxide. The usage of molecular simulation methods in supercritical region gave us a distinct advantage of knowing the microstructure of the systems in a qualitative and quantitative way. The Kirkwood-Buff theory, which predicts the influence of the solvent on the solute, enabled us to predict thermodynamic properties of supercritical phase and compare them with experimental values. We have examined the density effect on structure of the pure carbon dioxide and its solutions along its critical isotherm 4 K above its critical point. We focused our research and we present results for two basic sections, A. Equilibrium and transport properties, namely Volumetric properties; Average configurational energy; Isothermal compressibility; Diffusivity; and the Isochoric heat capacity B. Solution structures at infinite solutions, namely Radial distribution function; and Coordination number We discuss the outcomes based on the density inhomogeneities of the solvent and critical fluctuations, which are maximised at the critical point. We found that the addition of methane to supercritical carbon dioxide increases the volume of the solution and a cavitation is formed around it. On the hand, the addition of water gives a cluster around it in local structure and decrease the volume of solution. We report results also of the diffusion coefficients for the pure carbon dioxide and the mixtures in this study, which it shows an anomalous decrease close to the critical point of the pure carbon dioxide. It is a general conclusion for all the properties we have studied that the density dependence along the isotherm is maximised at densities close to the critical one. Further, the usage of both molecular dynamics and Monte Carlo in supercritical regions validates the extension of the techniques in the supercritical region and reveals their limitations

    Traversal Times for Random Walks on Small-World Networks

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    We study the mean traversal time for a class of random walks on Newman-Watts small-world networks, in which steps around the edge of the network occur with a transition rate F that is different from the rate f for steps across small-world connections. When f >> F, the mean time to traverse the network exhibits a transition associated with percolation of the random graph (i.e., small-world) part of the network, and a collapse of the data onto a universal curve. This transition was not observed in earlier studies in which equal transition rates were assumed for all allowed steps. We develop a simple self-consistent effective medium theory and show that it gives a quantitatively correct description of the traversal time in all parameter regimes except the immediate neighborhood of the transition, as is characteristic of most effective medium theories.Comment: 9 pages, 5 figure

    Understanding and utilization of Thematic Mapper and other remotely sensed data for vegetation monitoring

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    The TM Tasseled Cap transformation, which provides both a 50% reduction in data volume with little or no loss of important information and spectral features with direct physical association, is presented and discussed. Using both simulated and actual TM data, some important characteristics of vegetation and soils in this feature space are described, as are the effects of solar elevation angle and atmospheric haze. A preliminary spectral haze diagnostic feature, based on only simulated data, is also examined. The characteristics of the TM thermal band are discussed, as is a demonstration of the use of TM data in energy balance studies. Some characteristics of AVHRR data are described, as are the sensitivities to scene content of several LANDSAT-MSS preprocessing techniques

    Static Pairwise Annihilation in Complex Networks

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    We study static annihilation on complex networks, in which pairs of connected particles annihilate at a constant rate during time. Through a mean-field formalism, we compute the temporal evolution of the distribution of surviving sites with an arbitrary number of connections. This general formalism, which is exact for disordered networks, is applied to Kronecker, Erd\"os-R\'enyi (i.e. Poisson) and scale-free networks. We compare our theoretical results with extensive numerical simulations obtaining excellent agreement. Although the mean-field approach applies in an exact way neither to ordered lattices nor to small-world networks, it qualitatively describes the annihilation dynamics in such structures. Our results indicate that the higher the connectivity of a given network element, the faster it annihilates. This fact has dramatic consequences in scale-free networks, for which, once the ``hubs'' have been annihilated, the network disintegrates and only isolated sites are left.Comment: 7 Figures, 10 page

    The role of the lateral prefrontal cortex and anterior cingulate in stimulus–response association reversals

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    Many complex tasks require us to flexibly switch between behavioral rules, associations, and strategies. The prefrontal cerebral cortex is thought to be critical to the performance of such behaviors, although the relative contribution of different components of this structure and associated subcortical regions are not fully understood. We used functional magnetic resonance imaging to measure brain activity during a simple task which required repeated reversals of a rule linking a colored cue and a left/right motor response. Each trial comprised three discrete events separated by variable delay periods. A colored cue instructed which response was to be executed, followed by a go signal which told the subject to execute the response and a feedback instruction which indicated whether to ‘‘hold’’ or ‘‘f lip’’ the rule linking the colored cue and response. The design allowed us to determine which brain regions were recruited by the specific demands of preparing a rule contingent motor response, executing such a response, evaluating the significance of the feedback, and reconfiguring stimulus–response (SR) associations. The results indicate that an increase in neural activity occurs within the anterior cingulate gyrus under conditions in which SR associations are labile. In contrast, lateral frontal regions are activated by unlikely/unexpected perceptual events regardless of their significance for behavior. A network of subcortical structures, including the mediodorsal nucleus of the thalamus and striatum were the only regions showing activity that was exclusively correlated with the neurocognitive demands of reversing SR associations. We conclude that lateral frontal regions act to evaluate the behavioral significance of perceptual events, whereas medial frontal–thalamic circuits are involved in monitoring and reconfiguring SR associations when necessary

    Are adults just big kids? Can the newer paediatric weight estimation systems be used in adults?

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    Background. The weight of a patient is an important variable that impacts on their medical care. Although some drugs are prescribed on a so-called ‘adult dose’ basis, we know that adults come in all shapes and sizes – a ‘one-dose-fits-all’ approach is not necessarily appropriate. As a measured weight may not always be available, an alternative method of accurately estimating weight is required.Objectives. To assess and compare the accuracy of weight estimations in adults by patient self-estimation, the Mercy method, Buckley method, Broca index and PAWPER XL-MAC (paediatric advanced weight prediction in the emergency room eXtra length/eXtra large mid-arm circumference) method.Methods. This was a prospective, cross-sectional study conducted at a tertiary academic hospital in a metropolitan area of Johannesburg, South Africa. Anthropometric variables of height, abdominal circumference, thigh circumference, mid-arm circumference and humeral length were measured. These variables were then applied to the various weight estimation methods and compared with the patient’s actual weight.Results. There were 188 adult patients included in the study. None of the methodologies evaluated in this study achieved the recommended >70% of weight estimations within 10% of the patient’s actual weight (PW10). The Mercy method was the closest to achieving greater than the recommended 95% for weight estimation falling within 20% of the patient’s actual weight (PW20). The PW20 for the Mercy method was 91.5%. The PAWPER XL-MAC and patient self-estimate methods achieved a PW20 of 85.1% and 86.1%, respectively. The Broca and Buckley methods performed poorly overall.Conclusions. None of the evaluated weight estimation methodologies was accurate enough for use in adult weight estimation. The Mercy and PAWPER XL-MAC methodologies both showed significant promise for use in adult weight estimation, but need further refinement. Although patient self-estimates were similarly accurate to those found in previous studies, they were not an accurate option; self-estimations would remain the first choice if the patient was able to provide such an estimation. The Broca index and Buckley method cannot be recommended owing to their poor performance
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