102 research outputs found
Ferroelectric phase transitions induced by a strain gradient
Abstract
In perovskite oxide ferroelectrics, gradients of lattice strain are known to induce nanoscale topological structures, leading to novel or enhanced functionality. Here, we experimentally detect and theoretically analyze thickness distribution of structural properties in epitaxial Pb0.5 Sr0.5 TiO3 films grown on (001) SrTiO3 substrates. We show that the relaxation of substrate-imposed stress produces a strain gradient, which leads to the formation of distinct ferroelectric phases as a function of distance from the film-substrate interface within the same film. Charge carriers trapped at phase boundaries stabilize the induced phases and manifest themselves under electric field. Crosstalk between the phases, where polarization may rotate in one phase and invert in the other one, opens perspectives for advanced ferroelectric thin film devices
Cell adhesion and growth on ultrananocrystalline diamond and diamond-like carbon films after different surface modifications
Diamond and diamond-like carbon (DLC) films possess a set of excellent physical and chemical properties
which together with a high biocompatibility make them attractive candidates for a number of medical and
biotechnological applications. In the current work thin ultrananocrystalline diamond (UNCD) and DLC
films were comparatively investigated with respect to cell attachment and proliferation after different
surface modifications. The UNCD films were prepared by microwave plasma enhanced chemical vapor
deposition, the DLC films by pulsed laser deposition (PLD). The films were comprehensively characterized
with respect to their basic properties, e.g. crystallinity, morphology, chemical bonding nature, etc. Afterwards
the UNCD and DLC films were modified applying O2 or NH3/N2 plasmas and UV/O3 treatments to
alter their surface termination. The surface composition of as-grown and modified samples was studied
by X-ray photoelectron spectroscopy (XPS). Furthermore the films were characterized by contact angle
measurements with water, formamide, 1-decanol and diiodomethane; from the results obtained the surface
energy with its dispersive and polar components was calculated. The adhesion and proliferation of
MG63 osteosarcoma cells on the different UNCD and DLC samples were assessed by measurement of the
cell attachment efficiency and MTT assays. The determined cell densities were compared and correlated
with the surface properties of as-deposited and modified UNCD and DLC films.JRC.I.4-Nanobioscience
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